摘要:
A pressure-sensitive adhesive comprising organic fillers, obtainable by a process in which a thermal crosslinker is added in the melt to a polyacrylate copolymer (“polyacrylate”) based on acrylic esters and/or methacrylic esters, at least a fraction of which contains primary hydroxyl groups, at least one organic filler has been or is added to the polyacrylate, the polyacrylate provided with the crosslinker and the filler is conveyed to a coating unit, where it is applied to a web-form coat of a further material and, following application, is homogeneously crosslinked, a process as outlined above, and adhesive tapes furnished with the pressure-sensitive adhesive.
摘要:
A method of producing an adhesive tape having at least one carrier layer and two outer adhesive layers, wherein the carrier layer is from 300 μm to 5000 μm thick and is composed of a photoinitiator-free homogeneously thermally crosslinked polymer based on acrylate and/or methacrylate, in which at least one trimerized isocyanate crosslinker is added in the melt to a polyacrylate copolymer having primary hydroxyl groups and based on acrylic esters and/or methacrylic ester, a layer of the polyacrylate together with the crosslinker is conveyed to a coating unit, where pressure-sensitive adhesive layers are laminated onto both sides of the not-yet fully-crosslinked polyacrylate layer, and the crosslinking of the polyacrylate leads to a homogeneously crosslinked carrier layer.
摘要:
The invention describes a double-sided, carrierless self-adhesive tape which can be used in particular for achieving very durable adhesive bonding of a variety of articles. This double-sided, carrierless self-adhesive tape is composed of a homogeneously crosslinked pressure-sensitive acrylate hotmelt composition of single-layer construction, which may have been lined with release materials such as siliconized release papers or release films. The double-sided, carrierless pressure-sensitive adhesive tape is characterized in that it is composed of a photoinitiator-free, thermally homogeneously crosslinked acrylate hotmelt which is crosslinked predominantly by way of urethane units. It is notable in particular for the fact that it is homogeneously chemically crosslinked through the layer and, in contrast to acrylate layers crosslinked by radiation (UV/EBC), does not exhibit any profile of crosslinking through the layer. It can be used in particular as an adhesive transfer tape for the permanent attachment of articles to a variety of substrates.
摘要:
A process for producing an adhesive tape with single- or double-sided crosslinked pressure-sensitive acrylate hotmelt adhesive layer, wherein a crosslinker is added in the melt to a polyacrylate copolymer (“polyacrylate”) based on acrylic and/or methacrylic esters, the polyacrylate with crosslinker is conveyed to a coating unit, where it is applied to a web-form layer and following application is homogeneously crosslinked, where the crosslinker is a thermal crosslinker and some of the acrylic and/or methacrylic esters contain primary hydroxyl groups and addition takes place preferably in an extruder.
摘要:
A process for preparing a polyacrylate-based shaped article, a polyacrylate being polymerized by a conventional method, wherein the polyacrylate comprises copolymerized comonomers having thermally crosslinkable groups and comonomers having attached photoinitiators, and the polyacrylate is crosslinked thermally in a first step and by irradiation with UV light in a second step.
摘要:
The invention describes a double-sided pressure-sensitive adhesive tape of the kind which can be used in particular for achieving very durable bonds at high temperatures. These adhesive tapes, especially adhesive assembly tapes for the permanent fixing of articles to substrates, are preferably of multilayer construction. The inventive double-sided pressure-sensitive adhesive tapes are characterized in that the viscoelastic carrier layer is composed of a photoinitiator-free, thermally homogeneously crosslinked acrylate hotmelt. They are further characterized in that these homogeneously thermally crosslinked acrylate hotmelts have crosslinking sites by way of urethane units. This viscoelastic carrier layer is covered on both sides in each case by adhesive layers, preferably pressure-sensitive adhesive layers. These layers are connected by chemical reaction to the viscoelastic carrier layer. The operation for producing the adhesive tapes constitutes the corona pretreatment of the adhesive layers following their coating onto release material, the two-dimensional application and shaping of the acrylate hotmelt for thermal crosslinking, a thermal crosslinker having been added to the hotmelt prior to coating, the lamination of the layers together, and the afterreaction on the product in bale form, preferably without introduction of additional heat for crosslinking. This method ensures particularly effective anchoring even of different materials, which is particularly positive for the technical adhesive properties of the adhesive assembly tape.
摘要:
A process for preparing a polyacrylate-based shaped article, a polyacrylate being polymerized by a conventional method, wherein the polyacrylate comprises copolymerized comonomers having thermally crosslinkable groups and comonomers having attached photoinitiators, and the polyacrylate is crosslinked thermally in a first step and by irradiation with UV light in a second step.
摘要:
A process for producing an adhesive tape with single- or double-sided crosslinked pressure-sensitive acrylate hotmelt adhesive layer, wherein a crosslinker is added in the melt to a polyacrylate copolymer (“polyacrylate”) based on acrylic and/or methacrylic esters, the polyacrylate with crosslinker is conveyed to a coating unit, where it is applied to a web-form layer and following application is homogeneously crosslinked, where the crosslinker is a thermal crosslinker and some of the acrylic and/or methacrylic esters contain primary hydroxyl groups and addition takes place preferably in an extruder.
摘要:
A UV-crosslinkable polyacrylate pressure-sensitive adhesive composition having a polyacrylate having photoinitiator units incorporated therein by polymerization and being produced by a free-radical solvent-free polymerization process.