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公开(公告)号：US4298695A
公开(公告)日：1981-11-03
申请号：US120243
申请日：1980-02-11
IPC分类号： B01J23/745 , B01J29/46 , C07C9/14 , C10G2/00 , C07C1/00
CPC分类号： B01J23/745 , B01J29/46 , C10G2/334 , B01J2229/26 , B01J2229/42 , C07C2521/04 , C07C2521/08 , C07C2521/12 , C07C2529/46 , Y10S208/95
摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from finely divided iron powder or iron oxide. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
摘要翻译： 公开了一种方法，用于使用由细碎铁粉或氧化铁制备的新型催化剂，以90％塔顶转化合成气至沸点范围小于400°F的液体烃产物。 该新方法包括使合成气与含铁的单一颗粒催化剂接触，二氧化硅与氧化铝之比至少为12的结晶酸性硅铝酸盐沸石，孔径大于约5埃单位，约束指数约为1 到12，和矩阵。 催化剂不含助催化剂。
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公开(公告)号：US4354963A
公开(公告)日：1982-10-19
申请号：US257301
申请日：1981-04-24
IPC分类号： B01J23/745 , B01J29/46 , B01J29/76 , B01J29/30
CPC分类号： B01J29/46 , B01J23/745 , B01J2229/26 , B01J2229/42
摘要： A single particle catalyst composition prepared by forming a homogeneous mixture containing iron, a hydrogel matrix and a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 angstrom units, and a contraint index of about 1 to 12.
摘要翻译： 通过形成含有铁，水凝胶基质和二氧化硅与氧化铝之比至少为12，孔径大于约5埃单位的结晶酸性硅铝酸盐沸石的均匀混合物制备的单一颗粒催化剂组合物，以及相对指数 约1至12。
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公开(公告)号：US4312790A
公开(公告)日：1982-01-26
申请号：US140343
申请日：1980-04-14
IPC分类号： B01J29/67 , B01J29/44 , B01J29/74 , C07B61/00 , C07C1/00 , C07C5/27 , C07C15/08 , C07C67/00 , B01J29/32
CPC分类号： B01J29/44 , C07C5/2724 , B01J2229/26 , B01J2229/42 , Y02P20/52
摘要： A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
摘要翻译： 一种制备芳族化合物加工催化剂的方法，其包括将贵金属与有效类型的沸石的成员或成员结合，其结合发生在沸石结晶之后，但在最终催化剂颗粒形成之前，即挤出成颗粒。 所述有用类别的沸石的特征在于二氧化硅与氧化铝的摩尔比为至少12，约束指数在约1至12的范围内。
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公开(公告)号：USRE31919E
公开(公告)日：1985-06-18
申请号：US526257
申请日：1983-08-25
CPC分类号： B01J29/44 , B01J2229/26 , B01J2229/42
摘要： A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
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公开(公告)号：US4255349A
公开(公告)日：1981-03-10
申请号：US970307
申请日：1978-12-18
CPC分类号： C07C1/0445 , B01J29/40 , B01J29/46 , B01J2229/26 , B01J2229/42 , C07C2529/46
摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
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公开(公告)号：US4385195A
公开(公告)日：1983-05-24
申请号：US296601
申请日：1981-08-26
CPC分类号： B01J29/44 , C07C5/2724 , B01J2229/26 , B01J2229/42
摘要： A method of preparing aromatics processing catalysts which comprises incorporating a noble metal with a member or members of a useful class of zeolites, with such incorporation occurring after zeolite crystallization, but prior to final catalyst particle formation, i.e. extrusion into particles. Said useful class of zeolites is characterized by a silica to alumina mole ratio of at least 12 and a Constraint Index in the approximate range of 1 to 12.
摘要翻译： 一种制备芳族化合物加工催化剂的方法，其包括将贵金属与有效类型的沸石的成员或成员结合，其结合发生在沸石结晶之后，但在最终催化剂颗粒形成之前，即挤出成颗粒。 所述有用类别的沸石的特征在于二氧化硅与氧化铝的摩尔比为至少12，约束指数在约1至12的范围内。
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公开(公告)号：US4293446A
公开(公告)日：1981-10-06
申请号：US129551
申请日：1980-03-12
CPC分类号： B01J29/46 , B01J2229/26 , B01J2229/42 , C07C2529/46
摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling range of less than 400.degree. F. at a 90% overhead utilizing a novel catalyst prepared from a water-insoluble organic iron compound. The novel method involves contacting synthesis gas with a single particle catalyst containing iron, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a matrix. The catalyst does not contain promoters.
摘要翻译： 公开了一种使用由水不溶性有机铁化合物制备的新型催化剂，以90％塔顶转化合成气至沸点范围小于400°F的液体烃产物的方法。 该新方法包括使合成气与含铁的单一颗粒催化剂接触，二氧化硅与氧化铝之比至少为12的结晶酸性硅铝酸盐沸石，孔径大于约5埃单位，约束指数约为1 到12，和矩阵。 催化剂不含助催化剂。
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公开(公告)号：US4207248A
公开(公告)日：1980-06-10
申请号：US970299
申请日：1978-12-18
CPC分类号： C10G2/334 , B01J29/46 , B01J2229/26 , B01J2229/42
摘要： A method is disclosed for the conversion of synthesis gas to a liquid hydrocarbon product having a boiling point range maximum of less than 400.degree. F. at a 90% overhead and being a predominantly olefinic product. The novel method involves contacting synthesis gas with a single particle catalyst containing cobalt, a crystalline acidic aluminosilicate zeolite having a silica-to-alumina ratio of at least 12, a pore size greater than about 5 Angstrom units, and a constraint index of about 1 to 12, and a siliceous matrix. The catalyst does not contain promoters and the alumina content of the matrix is severely restricted.
摘要翻译： 公开了一种在90％塔顶馏分将合成气转化为沸点范围最大小于400°F的液体烃产物并且主要是烯烃产物的方法。 该新方法包括使合成气与含有钴的单一颗粒催化剂接触，二氧化硅与氧化铝之比至少为12的结晶酸性硅铝酸盐沸石，孔径大于约5埃单位，约束指数约为1 至12，和硅质基质。 催化剂不含助催化剂，并且基体的氧化铝含量受到严格限制。
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公开(公告)号：US4080396A
公开(公告)日：1978-03-21
申请号：US719297
申请日：1976-08-31
申请人： Stephen A. Butter
发明人： Stephen A. Butter
IPC分类号： C07C2/66 , B01J29/00 , B01J29/16 , B01J29/48 , B01J29/78 , B01J29/90 , C07B61/00 , C07C1/00 , C07C2/00 , C07C2/76 , C07C2/86 , C07C6/12 , C07C11/02 , C07C15/00 , C07C15/08 , C07C67/00 , C07C3/02 , B01J29/36
CPC分类号： C07C2/868 , B01J29/48 , B01J29/90 , C07C2/00 , C07C2/76 , C07C2/862 , C07C2/864 , C07C2/865 , C07C6/123 , C07C2523/18 , C07C2529/48 , Y02P20/52 , Y02P20/584
摘要： A catalytic process is provided for the selective production of para-xylene by contacting, under conversion conditions, a charge stock containing, as a major reactant, at least one hydrocarbon selected from the group consisting of toluene, a C.sub.3 -C.sub.10 olefin, a C.sub.5 -C.sub.10 naphthene, a C.sub.3 -C.sub.10 paraffin, and mixtures of the foregoing with a catalyst comprising a composite of a crystalline aluminosilicate zeolite and antimony oxide, said zeolite having a silica to alumina ratio of at least about 12 and a constraint index, as hereinafter defined, within the approximate range of 1 to 12.
摘要翻译： 提供催化方法用于通过在转化条件下使含有作为主要反应物的至少一种选自甲苯，C 3 -C 10烯烃，C 5 -C 10烃， -C 10环烷烃，C 3 -C 10链烷烃，以及前述物质与包含结晶硅铝酸盐沸石和氧化锑的复合物的催化剂的混合物，所述沸石的二氧化硅与氧化铝的比例至少约为12，约束指数如下所述 在1到12的范围内。
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公开(公告)号：US4603040A
公开(公告)日：1986-07-29
申请号：US716429
申请日：1985-03-27
CPC分类号： B01J29/082 , C01B39/22 , B01J37/0018 , Y10S423/21
摘要： Maximum Aluminum X-type zeolite is prepared in the form of essentially binderless aggregates. In the optimal case, the composition possesses the maximum theoretical zeolite cation content in a wide-pored zeolite as a solid, massive body.
摘要翻译： 最大的铝X型沸石以基本上无粘合剂聚集的形式制备。 在最佳情况下，该组合物具有在作为固体，大体积的广泛沸石中的最大理论沸石阳离子含量。
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