公开(公告)号：US4447555A

公开(公告)日：1984-05-08

申请号：US481957

申请日：1983-04-04

申请人： Stephen L. Parrott ,  John W. Myers

发明人： Stephen L. Parrott ,  John W. Myers

IPC分类号： B01J29/076 ,  B01J37/04 ,  C10G47/20 ,  B01J29/06 ,  B01J29/16

CPC分类号： B01J37/04 ,  B01J29/076 ,  C10G47/20

摘要： The activity and deactivation rate of hydrocracking catalysts are improved by making them via a particular production sequence.

摘要翻译： 加氢裂化催化剂的活性和失活速率通过使其通过特定的生产顺序得到改善。

公开(公告)号：US4619759A

公开(公告)日：1986-10-28

申请号：US726760

申请日：1985-04-24

申请人： John W. Myers ,  Stephen L. Parrott ,  Edward L. Sughrue

发明人： John W. Myers ,  Stephen L. Parrott ,  Edward L. Sughrue

IPC分类号： C10G65/04

CPC分类号： C10G65/04

摘要： The catalytic hydrotreatment of a mixture comprising a resid and a light cycle oil is carried out in a multiple catalyst bed in which the portion of the catalyst bed with which the feedstock is first contacted contains a catalyst which comprises of alumina, cobalt and molybdenum and the second portion of the catalyst bed through which the feedstock is passed after passing through the first portion contains a catalyst comprising alumina to which molybdenum and nickel have been added.

摘要翻译： 包含渣油和轻循环油的混合物的催化加氢处理在多催化剂床中进行，其中原料首先接触的催化剂床部分含有包含氧化铝，钴和钼的催化剂， 在通过第一部分之后原料通过的催化剂床的第二部分包含含有已加入钼和镍的氧化铝的催化剂。

公开(公告)号：US4720472A

公开(公告)日：1988-01-19

申请号：US763592

申请日：1985-08-08

申请人： Stephen L. Parrott

发明人： Stephen L. Parrott

IPC分类号： B01J23/88 ,  B01J23/883 ,  B01J37/02 ,  B01J37/03 ,  C10G47/12 ,  B01J27/19 ,  B01J21/08 ,  B01J27/051 ,  B01J31/00

CPC分类号： B01J37/024 ,  B01J23/883 ,  C10G47/12 ,  B01J37/033

摘要： A novel catalyst for recovering middle distillates comprising silica/titanium compound impregnated on an alumina and promoted with nickel and molybdenum.

摘要翻译： 一种用于回收中间馏出物的新催化剂，其包含浸渍在氧化铝上并用镍和钼促进的二氧化硅/钛化合物。

公开(公告)号：US5341313A

公开(公告)日：1994-08-23

申请号：US924138

申请日：1992-08-03

申请人： Stephen L. Parrott ,  Raul Adarme ,  Fan-Nan Lin ,  Edwin P. Sasscer

发明人： Stephen L. Parrott ,  Raul Adarme ,  Fan-Nan Lin ,  Edwin P. Sasscer

IPC分类号： C10G45/72 ,  G06F17/50 ,  G06G7/58

CPC分类号： C10G45/72 ,  G06F17/50 ,  G06F2217/16

摘要： Catalyst life in desulfurization of distillate hydrocarbon streams is predicted with the aid of a computer simulation which embodies an analytical kinetic model of a hydrodesulfurization reaction and a semi-empirical model for catalyst deactivation. The simulation specifies the decline of catalyst activity with time and a current reaction temperature required to maintain the initial catalyst activity. The useful life of the catalyst is considered to be the time required for catalyst activity in the simulated reaction to decline sufficiently from its initial level so that a predefined maximum reaction temperature is reached while maintaining a desired level of sulfur in the desulfurized product. The computer time needed to simulate the reaction is decreased by combining superior features of LOTUS 1-2-3 and FORTRAN language, such that input/output and graphic operations are implemented with LOTUS 1-2-3 and numerical calculations are executed in FORTRAN.

摘要翻译： 借助于体现加氢脱硫反应的分析动力学模型和催化剂失活的半经验模型的计算机模拟预测了馏出物烃流脱硫的催化剂寿命。 该模拟规定了催化剂活性随时间的下降以及维持初始催化剂活性所需的当前反应温度。 催化剂的使用寿命被认为是模拟反应中的催化剂活性从其初始水平充分降低所需的时间，从而达到预定的最大反应温度，同时在脱硫产物中保持所需水平的硫。 通过结合LOTUS 1-2-3和FORTRAN语言的优越特性，可以减少模拟反应的计算机时间，从而使用LOTUS 1-2-3实现输入/输出和图形操作，并在FORTRAN中执行数值计算。

公开(公告)号：US4687757A

公开(公告)日：1987-08-18

申请号：US843489

申请日：1986-03-24

申请人： Stephen L. Parrott ,  Simon G. Kukes ,  Karlheinz K. Brandes

发明人： Stephen L. Parrott ,  Simon G. Kukes ,  Karlheinz K. Brandes

IPC分类号： B01J23/28 ,  C10G45/04 ,  C10G45/12 ,  C10G47/16 ,  B01J21/04 ,  B01J21/06 ,  B01J27/051

CPC分类号： C10G45/04 ,  B01J23/28

摘要： A composition of matter comprising alumina, at least one compound of titanium and at least one compound of molybdenum is prepared either by the steps of impregnating an alumina support material with an aqueous solution of at least one titanium compound, drying, impregnating the Ti-impregnated material with an aqueous solution of at least one molybdenum compound, drying and calcining; or by the steps of impregnating an alumina support material with an aqueous solution of at least one titanium compound and at least one molybdenum compound, drying and calcining. The compositions of matter of this invention are useful as catalysts for hydrotreating substantially liquid hydrocarbon-containing feed streams (particularly heavy oils) which also contain compounds of nickel, vanadium and sulfur.

摘要翻译： 包含氧化铝，至少一种钛化合物和至少一种钼化合物的物质组合物可以通过以下步骤制备：用至少一种钛化合物的水溶液浸渍氧化铝载体材料，干燥，浸渍Ti浸渍 材料与至少一种钼化合物的水溶液，干燥和煅烧; 或通过用至少一种钛化合物和至少一种钼化合物的水溶液浸渍氧化铝载体材料的步骤，干燥和煅烧。 本发明的物质组合物可用作加氢处理基本上液体含烃的进料流（特别是重油）的催化剂，其还含有镍，钒和硫化合物。

公开(公告)号：US4588706A

公开(公告)日：1986-05-13

申请号：US748112

申请日：1985-06-24

申请人： Simon G. Kukes ,  Stephen L. Parrott

发明人： Simon G. Kukes ,  Stephen L. Parrott

IPC分类号： B01J27/188 ,  C10G45/08 ,  B01J27/19

CPC分类号： B01J27/188 ,  C10G45/08

摘要： A catalyst composition is prepared by dissolving a suitable oxygen containing compound of a Group VIB metal (preferably Mo), a suitable compound of a Group VIII metal (preferably Ni) and phosphorous acid in water, mixing this solution with an alumina containing support material, and calcining this mixture. This catalyst composition is used primarily for hydrotreating of hydrocarbon feed stream, which contain nitrogen and sulfur impurities, particularly heavy cycle oils.

摘要翻译： 通过将VIB族金属（优选Mo），适合的VIII族金属（优选Ni）和亚磷酸的合适的化合物溶解在水中来制备催化剂组合物，将该溶液与含氧化铝的载体材料混合， 并煅烧该混合物。 该催化剂组合物主要用于加氢处理含有氮和硫杂质的烃进料流，特别是重循环油。

公开(公告)号：US4762814A

公开(公告)日：1988-08-09

申请号：US80843

申请日：1987-08-03

申请人： Stephen L. Parrott ,  Lloyd E. Gardner

发明人： Stephen L. Parrott ,  Lloyd E. Gardner

IPC分类号： B01J23/887 ,  C10G45/08 ,  B01J21/04 ,  B01J23/80 ,  B01J23/88 ,  B01J27/185

CPC分类号： C10G45/08 ,  B01J23/8873

摘要： A catalyst composition comprises (a) alumina, (b) zinc titanate, (c) at least one compound of molybdenum, (d) at least one compound of at least one of nickel and cobalt, and (e) at least one compound containing phosphorus and oxygen. This catalyst composition is used for hydrotreating a liquid hydrocarbon-containing feed stream (such as a heavy oil) which contains compounds of nickel, vanadium and sulfur, under such conditions as to obtain a product having reduced levels of nickel, vanadium and sulfur.

摘要翻译： 催化剂组合物包含（a）氧化铝，（b）钛酸锌，（c）至少一种钼化合物，（d）至少一种镍和钴中的至少一种化合物和（e）至少一种含 磷和氧气。 该催化剂组合物用于加氢处理含有镍，钒和硫化合物的含液烃的进料流（例如重油），以获得具有降低的镍，钒和硫含量的产物。

公开(公告)号：US4724069A

公开(公告)日：1988-02-09

申请号：US896916

申请日：1986-08-15

申请人： Arthur W. Aldag, Jr. ,  Stephen L. Parrott ,  Simon G. Kukes

发明人： Arthur W. Aldag, Jr. ,  Stephen L. Parrott ,  Simon G. Kukes

IPC分类号： C07F15/02 ,  B01J23/88 ,  B01J23/94 ,  C07F15/06 ,  C10G45/02 ,  C10G45/12 ,  C10G45/00 ,  C10G45/06

CPC分类号： C10G45/02

摘要： An additive comprising a metal naphthenate selected from the group consisting of cobalt naphthenate and iron naphthenate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing the additive is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the inventive additive may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occuring in each case.

摘要翻译： 将包含选自环烷酸钴和环烷酸铁的环烷酸金属的添加剂与含烃进料流混合。 然后将含有添加剂的含烃进料物流在加氢精制过程中与包含选自氧化铝，二氧化硅和二氧化硅 - 氧化铝的载体的催化剂组合物和包含至少一种选自组VIB的金属的组合物 VIIB和第八期。 本发明添加剂的引入可以在催化剂是新的，部分失活的或在每种情况下产生有益结果的情况下消耗或开始。

公开(公告)号：US4652361A

公开(公告)日：1987-03-24

申请号：US878558

申请日：1986-06-26

申请人： Simon G. Kukes ,  Stephen L. Parrott

发明人： Simon G. Kukes ,  Stephen L. Parrott

IPC分类号： B01J21/06 ,  B01J23/00 ,  B01J23/10 ,  C10G45/04 ,  C10G17/00 ,  C10G45/00

CPC分类号： B01J21/066 ,  B01J23/00 ,  B01J23/10 ,  C10G45/04

摘要： A composition of matter consisting essentially of alumina and at least one compound (preferably oxide) of yttrium and/or zirconium is provided and is employed as a catalyst in the hydrotreating of a substantially liquid hydrocarbon containing feed stream (particularly a heavy oil) which also contains compounds of nickel, vanadium and sulfur. The preferred preparation of the catalyst compositions of this invention comprises at least one impregnating step using a solution containing at least one aluminum compound, which is at least partially converted to aluminum oxide in a subsequent calcining step.

摘要翻译： 提供了基本上由氧化铝和至少一种钇和/或锆化合物（优选氧化物）组成的物质组合物，并且用作加氢处理基本上液体的含烃进料流（特别是重油）中的催化剂， 含有镍，钒和硫的化合物。 本发明的催化剂组合物的优选制备方法包括使用至少一种铝化合物的溶液进行至少一次浸渍步骤，该化合物在随后的煅烧步骤中至少部分转化为氧化铝。

公开(公告)号：US4585751A

公开(公告)日：1986-04-29

申请号：US748113

申请日：1985-06-24

申请人： Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

发明人： Simon G. Kukes ,  Stephen L. Parrott ,  Karlheinz K. Brandes

IPC分类号： B01J23/885 ,  B01J27/19 ,  C10G45/04

CPC分类号： C10G45/04 ,  B01J23/885 ,  B01J27/19

摘要： A catalyst composition is prepared by dissolving a suitable molybdenum and oxygen containing compound (preferably MoO.sub.3), a suitable divalent copper and/or manganese compound and a suitable phosphorus and oxygen containing compound (preferably H.sub.3 PO.sub.4) in water, mixing this solution with an alumina-containing support material, and calcining this mixture. This catalyst composition is used primarily for hydrotreating of hydrocarbon feed streams, which contain sulfur, vanadium and nickel impurities, particularly heavy oils.

摘要翻译： 通过将合适的含钼和氧的化合物（优选MoO 3），合适的二价铜和/或锰化合物和合适的含磷和氧的化合物（优选H 3 PO 4）溶解在水中来制备催化剂组合物，将该溶液与氧化铝 - 含有载体材料，并煅烧该混合物。 该催化剂组合物主要用于加氢处理含有硫，钒和镍杂质，特别是重油的烃进料流。