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公开(公告)号:US07875742B2
公开(公告)日:2011-01-25
申请号:US12712793
申请日:2010-02-25
申请人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号: C07C69/74
CPC分类号: C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物,特别是不饱和有机化合物的方法,所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物,特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。
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公开(公告)号:US08143438B2
公开(公告)日:2012-03-27
申请号:US12967254
申请日:2010-12-14
申请人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号: C07C69/74
CPC分类号: C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物,特别是不饱和有机化合物的方法,所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物,特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。
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公开(公告)号:US20110082311A1
公开(公告)日:2011-04-07
申请号:US12967254
申请日:2010-12-14
申请人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号: C07C67/303
CPC分类号: C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物,特别是不饱和有机化合物的方法,所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物,特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。
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公开(公告)号:US20100184895A1
公开(公告)日:2010-07-22
申请号:US12712793
申请日:2010-02-25
申请人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号: C08K5/12 , C07C67/303 , C07C69/757
CPC分类号: C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物,特别是不饱和有机化合物的方法,所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物,特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。
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公开(公告)号:US07732634B2
公开(公告)日:2010-06-08
申请号:US10534075
申请日:2003-11-18
申请人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
发明人: Stuart Leon Soled , Andrzej Malek , James Clarke Vartuli , Jennifer Schaefer Feeley , Sabato Miseo , Shifang Luo , Richard Henry Schlosberg , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T. Ragomo
IPC分类号: C07C62/00
CPC分类号: C08F8/04 , B01J23/462 , B01J23/75 , B01J35/0053 , B01J35/0066 , B01J35/1023 , B01J35/1028 , B01J35/1061 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C29/19 , C07C67/303 , C07C69/75
摘要: The present invention is directed to a process for hydrogenating one or more organic compounds especially unsaturated organic compounds by bringing the compound into contact with a hydrogen-containing gas in the presence of a catalyst, which comprises one or more catalytically active metals applied to a porous catalyst support. The one or more catalytically active metals having been derived via a decomposed organic complex of the metal on the support, in particular amine complexes of the metal. The decomposed complex may be treated with hydrogen to activate the catalyst before use as a hydrogenation catalyst.
摘要翻译: 本发明涉及一种通过在催化剂存在下使化合物与含氢气体接触来氢化一种或多种有机化合物,特别是不饱和有机化合物的方法,所述催化剂包含一种或多种催化活性金属施加到多孔 催化剂载体。 一种或多种催化活性金属已经通过载体上的金属的分解的有机络合物,特别是金属的胺络合物衍生。 分解的络合物可以用氢处理以在使用前活化催化剂作为氢化催化剂。
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公开(公告)号:US07585808B2
公开(公告)日:2009-09-08
申请号:US10534072
申请日:2003-11-18
申请人: Andrzel Malek , James Clarke Vartuli , Stuart Leon Soled , Sabato Miseo , Jennifer Schaefer Feeley , Gary L. Casty , Gabor Kiss , Jeffrey M. Dysard , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T Ragomo
发明人: Andrzel Malek , James Clarke Vartuli , Stuart Leon Soled , Sabato Miseo , Jennifer Schaefer Feeley , Gary L. Casty , Gabor Kiss , Jeffrey M. Dysard , Joseph Ernest Baumgartner , Christine E. Kliewer , Steven T Ragomo
IPC分类号: B01J23/00
CPC分类号: C10G2/331 , B01J20/02 , B01J20/08 , B01J20/103 , B01J20/223 , B01J20/3204 , B01J20/3236 , B01J23/462 , B01J23/75 , B01J23/8896 , B01J37/0203 , B01J37/08 , B01J37/082 , C07C7/12 , C10G25/003 , C10G29/04
摘要: The present invention is directed to processes for preparing supported metal catalysts comprising one or more catalytically active metals applied to a porous catalyst support and to processes that use such catalysts. The process requires the formation of an organic complex during the manufacture of the catalyst which after its formation is either partially or fully decomposed before reduction if the metal to form the catalyst. The catalysts have high levels of metal dispersion and uniform distribution of catalytically active metals on the support. The catalysts obtained form the processes are particularly effective in catalysing Fischer-Tropsch reactions and as adsorbants for the removal or organosulfur compounds from hydrocarbons.
摘要翻译: 本发明涉及用于制备负载金属催化剂的方法,所述催化剂包含施加到多孔催化剂载体上的一种或多种催化活性金属和使用这种催化剂的方法。 该方法需要在制备催化剂期间形成有机络合物,其在形成催化剂之前在还原之前部分或完全分解之后部分或完全分解。 催化剂具有高水平的金属分散性和催化活性金属在载体上的均匀分布。 从该方法获得的催化剂在催化费 - 托反应和作为烃的去除或有机硫化合物的吸附剂方面特别有效。
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公开(公告)号:US07605107B2
公开(公告)日:2009-10-20
申请号:US11238929
申请日:2005-09-29
申请人: Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Christine E. Kliewer , Andrzej Malek , Andrew C. Moreland
发明人: Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Christine E. Kliewer , Andrzej Malek , Andrew C. Moreland
CPC分类号: B01J35/002 , B01J21/08 , B01J23/85 , B01J23/882 , B01J23/8885 , B01J37/0203 , B01J37/0205 , B01J37/086 , B01J37/20 , C10G45/08
摘要: This invention relates to supported multi-metallic catalysts for use in the hydroprocessing of hydrocarbon feeds, as well as a method for preparing such catalysts. The catalysts are prepared from a catalyst precursor comprised of at least one Group VIII metal and a Group VI metal and an organic agent selected from the group consisting of amino alcohols and amino acids. The catalyst precursor is thermally treated to partially decompose the organic agent, then sulfided.
摘要翻译: 本发明涉及用于烃进料加氢处理的负载型多金属催化剂,以及制备这种催化剂的方法。 催化剂由至少一种VIII族金属和第Ⅵ族金属的催化剂前体和选自氨基醇和氨基酸的有机试剂制备。 催化剂前体被热处理以部分分解有机试剂,然后硫化。
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公开(公告)号:US10017448B2
公开(公告)日:2018-07-10
申请号:US15511975
申请日:2015-10-09
申请人: Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Christine E. Kliewer , Hans K. T. Goris
发明人: Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Christine E. Kliewer , Hans K. T. Goris
CPC分类号: C07C51/36 , B01J8/0278 , B01J23/462 , B01J23/464 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C2601/16
摘要: A process for ring hydrogenation of a benzenepolycarboxylic acid or derivative thereof, includes contacting a feed stream comprising the acid or derivative thereof with a hydrogen containing gas in the presence of a catalyst under hydrogenation conditions to produce a hydrogenated product, wherein the catalyst contains rhodium and ruthenium.
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公开(公告)号:US08969639B2
公开(公告)日:2015-03-03
申请号:US13512625
申请日:2010-12-17
申请人: Teng Xu , Stuart L. Soled , Edward A. Lemon, Jr. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
发明人: Teng Xu , Stuart L. Soled , Edward A. Lemon, Jr. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
CPC分类号: B01J37/0203 , B01J23/40 , C07C5/367 , C07C5/373 , C07C13/19 , C07C2523/42 , Y02P20/52 , C07C15/04 , C07C9/14
摘要: In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a dehydrogenation catalyst produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid. The contacting is conducted under conditions effective to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to benzene and to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to paraffins.
摘要翻译: 在脱氢方法中,包含至少一种非芳族六元环化合物和至少一种五元环化合物的烃流与脱氢催化剂接触,所述脱氢催化剂通过包括用包含脱氢组分的液体组合物处理载体的方法制备 或其前体和至少一种选自氨基醇和氨基酸的有机分散剂。 该接触在有效将烃流中的至少一种非芳香族六元环化合物的至少一部分转化为苯并将至少一部分至少一种五元环化合物转化为 烃流至石蜡。
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公开(公告)号:US20120271077A1
公开(公告)日:2012-10-25
申请号:US13512625
申请日:2010-12-17
申请人: Teng Xu , Stuart L. Soled , Edward A. Lemon, JR. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
发明人: Teng Xu , Stuart L. Soled , Edward A. Lemon, JR. , Christine E. Kliewer , Tan-Jen Chen , Joseph E. Baumgartner , Sabato Miseo
IPC分类号: C07C5/367
CPC分类号: B01J37/0203 , B01J23/40 , C07C5/367 , C07C5/373 , C07C13/19 , C07C2523/42 , Y02P20/52 , C07C15/04 , C07C9/14
摘要: In a dehydrogenation process a hydrocarbon stream comprising at least one non-aromatic six-membered ring compound and at least one five-membered ring compound is contacted with a dehydrogenation catalyst produced by a method comprising treating the support with a liquid composition comprising the dehydrogenation component or a precursor thereof and at least one organic dispersant selected from an amino alcohol and an amino acid. The contacting is conducted under conditions effective to convert at least a portion of the at least one non-aromatic six-membered ring compound in the hydrocarbon stream to benzene and to convert at least a portion of the at least one five-membered ring compound in the hydrocarbon stream to paraffins.
摘要翻译: 在脱氢方法中,包含至少一种非芳族六元环化合物和至少一种五元环化合物的烃流与脱氢催化剂接触,所述脱氢催化剂通过包括用包含脱氢组分的液体组合物处理载体的方法制备 或其前体和至少一种选自氨基醇和氨基酸的有机分散剂。 该接触在有效将烃流中的至少一种非芳香族六元环化合物的至少一部分转化为苯并将至少一部分至少一种五元环化合物转化为 烃流至石蜡。
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