Soft homogeneous isotactic polypropylene compositions
    5.
    发明申请
    Soft homogeneous isotactic polypropylene compositions 有权
    软均匀全同立构聚丙烯组合物

    公开(公告)号:US20080249231A1

    公开(公告)日:2008-10-09

    申请号:US12080486

    申请日:2008-04-03

    IPC分类号: C08L23/16 C08L9/00

    摘要: The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.

    摘要翻译: 本发明还公开了一种均匀的共混组合物,其包含: a)1重量%至99重量%的第一聚合物组分的共混物,其包含5重量%至35重量%的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量%至95重量% 来自全同立构聚丙烯序列的结晶度为0.1%至约25%的丙烯衍生单元的第一聚合物组分,熔点为45℃至105℃,并且其中熔体流动速率(MFR @ 230℃ 。)的第一聚合物组分在300g / 10min至5000g / 10min之间。 b)1重量%至99重量%的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物,其中共聚物中共聚α-烯烃的百分比为0.0-9重量% 所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点,其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。

    Soft heterogeneous isotactic polypropylene compositions
    6.
    发明授权
    Soft heterogeneous isotactic polypropylene compositions 有权
    软异相全同立构聚丙烯组合物

    公开(公告)号:US08263707B2

    公开(公告)日:2012-09-11

    申请号:US12080495

    申请日:2008-04-03

    IPC分类号: C08L23/00 C08L23/10 C08K5/00

    摘要: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.

    摘要翻译: 本发明还公开了一种非均相共混组合物,其包含: a)1重量%至99重量%的第一聚合物组分的共混物,其包含5重量%至35重量%的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量%至95重量% 来自全同立构聚丙烯序列的结晶度为0.1%至约25%的丙烯衍生单元的第一聚合物组分,熔点为45℃至105℃,并且其中熔体流动速率(MFR @ 230℃ 第一聚合物组分的重量比在300g / 10min至5000g / 10min之间b)1重量%至99重量%的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物,其中 共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0%至9%,其中第二聚合物组分的熔点大于约110℃,其中第一聚合物组分的含量小于 产生1000ppm的反应产物 来自分子降解剂的化学反应。

    Soft homogeneous isotactic polypropylene compositions
    7.
    发明授权
    Soft homogeneous isotactic polypropylene compositions 有权
    软均匀全同立构聚丙烯组合物

    公开(公告)号:US07858701B2

    公开(公告)日:2010-12-28

    申请号:US12080486

    申请日:2008-04-03

    IPC分类号: C08L23/10

    摘要: The present invention also discloses a homogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR @ 230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min. b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.

    摘要翻译: 本发明还公开了一种均匀的共混组合物,其包含: a)1重量%至99重量%的第一聚合物组分的共混物,其包含5重量%至35重量%的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量%至95重量% 来自全同立构聚丙烯序列的结晶度为0.1%至约25%的丙烯衍生单元的第一聚合物组分,熔点为45℃至105℃,并且其中熔体流动速率(MFR @ 230℃ 。)的第一聚合物组分在300g / 10min至5000g / 10min之间。 b)1重量%至99重量%的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物的共混物,其中共聚物中共聚α-烯烃的百分比为0.0-9重量% 所述第二聚合物组分并且其中所述第二聚合物组分具有大于约110℃的熔点,其中所述第一聚合物组分具有小于1000ppm的由分子降解剂的化学反应产生的反应产物。

    Soft heterogeneous isotactic polypropylene compositions
    8.
    发明申请
    Soft heterogeneous isotactic polypropylene compositions 有权
    软异相全同立构聚丙烯组合物

    公开(公告)号:US20080249232A1

    公开(公告)日:2008-10-09

    申请号:US12080495

    申请日:2008-04-03

    IPC分类号: C08L23/16 C08L9/00

    摘要: The present invention also discloses a heterogeneous blend composition comprising; a) from 1% to 99% by weight of the blend of a first polymer component comprising a copolymer of 5% to 35% by weight of the first polymer component consisting predominantly of alpha olefin derived units and 65% to 95% by weight of the first polymer component of propylene derived units having a crystallinity of 0.1% to about 25% from isotactic polypropylene sequences, a melting point of from 45° C. to 105° C., and wherein the Melt Flow Rate (MFR@230° C.) of the first polymer component is between 300 g/10 min to 5000 g/10 min b) from 1% to 99% by weight of the blend of a second polymer component comprising isotactic polypropylene and random copolymers of isotactic propylene, wherein the percentage of the copolymerized alpha-olefin in the copolymer is between 0.0% and 9% by weight of the second polymer component and wherein the second polymer component has a melting point greater than about 110° C., wherein the first polymer component has less than 1000 ppm of reaction products arising from the chemical reaction of a molecular degradation agent.

    摘要翻译: 本发明还公开了一种非均相共混组合物,其包含: a)1重量%至99重量%的第一聚合物组分的共混物,其包含5重量%至35重量%的主要由α-烯烃衍生单元组成的第一聚合物组分和65重量%至95重量% 来自全同立构聚丙烯序列的结晶度为0.1%至约25%的丙烯衍生单元的第一聚合物组分,熔点为45℃至105℃,并且其中熔体流动速率(MFR @ 230℃ )第一聚合物组分的量为300g / 10min至5000g / 10min,b)1重量%至99重量%的包含全同立构聚丙烯的第二聚合物组分和全同立构丙烯的无规共聚物的共混物,其中 共聚物中的共聚α-烯烃的百分比为第二聚合物组分的0.0%至9%,其中第二聚合物组分的熔点大于约110℃,其中第一聚合物组分的含量小于 产生1000ppm的反应产物 来自分子降解剂的化学反应。

    Sprayable hot melt adhesives
    9.
    发明授权
    Sprayable hot melt adhesives 有权
    可喷涂热熔胶

    公开(公告)号:US06582762B2

    公开(公告)日:2003-06-24

    申请号:US09839316

    申请日:2001-04-20

    IPC分类号: B05D510

    摘要: This invention relates to a process for atomizing, spiral spraying, oscillation spraying or melt blowing propylene copolymers onto a substrate comprising selecting a poly-alpha olefin inter-polymer comprising: A) from 60 to 94% of units derived from an alpha mono-olefin having from 3 to 6 carbon atoms and B) from 6 to 40 mol % of units derived from ethylene or one or more other mono-olefins having from 4 to 10 carbon atoms and at least one carbon atom more than A); and C) optionally from 0 to 10 mol % of units derived from another copolymerizable unsaturated hydrocarbon, different from A) and B); wherein the inter-polymer has: i) an Mw/Mn of 6 or less; ii) a storage modulus G′, determined upon cooling, intersecting a value of 0.3 M Pa at a temperature of less than 85° C.; iii) a G″/G′ ratio of 18 or more when G′ is 10 Pa when measured at a frequency of 1 hz; and iv) a viscosity of 5000 mPa·sec or less at 190° C., and atomizing, spiral spraying, oscillation spraying or melt blowing the inter-polymer into a substrate. Blends of the above copolymers can also be used herein.

    摘要翻译: 本发明涉及一种在基材上雾化,螺旋喷涂,振荡喷涂或熔融丙烯共聚物的方法,包括选择聚α-烯烃聚合物,其包含:A)60至94%的衍生自α-单烯烃的单元 具有3至6个碳原子和B)6至40摩尔%的衍生自乙烯或一种或多种其它具有4至10个碳原子和至少1个碳原子的其它单烯烃的单元; 和C)任选地0至10摩尔%来自不同于A)和B)的另一种可共聚不饱和烃的单元;其中所述共聚物具有:i)Mw / Mn为6以下; ii)储能模量G ',在低于85℃的温度下与0.3Mpa的值相交; iii)当G'为10Pa时,G“/ G'比为18或更大,当以 1 hz; andiv)在190℃下的粘度为5000mPa.sec或更低,并进行溶解,螺旋喷涂,振荡喷雾或将共聚物熔融吹制到基底中。上述共聚物的延伸部分也可用于本文。

    Isotactic polypropylene nucleation
    10.
    发明授权
    Isotactic polypropylene nucleation 有权
    全同立构聚丙烯成核

    公开(公告)号:US09096747B2

    公开(公告)日:2015-08-04

    申请号:US12013183

    申请日:2008-01-11

    摘要: Low molecular weight semicrystalline propylene-alpha olefin copolymers containing propylene crystallinity are used as a nucleating agent in crystalline polypropylene and polypropylene copolymers. The nucleating copolymers are propylene-alpha olefin copolymers having a percent crystallinity of 5-75%, a melting point of 45° C.-105° C., and an MFR between 300 and 5000 g/10 min. Nucleated polypropylene compositions comprise a nucleating amount of the copolymer blended in a matrix of polypropylene homopolymer, or 0.01 to 9 wt % α-olefin copolymer, having a melting point greater than 110° C. The nucleating copolymer improves processing time with little or no effect on the crystallinity-associated characteristics of the matrix. The invention also provides methods of crystallizing polypropylene with the nucleating agent and of forming articles with the composition, and also provides articles formed from the composition and/or by the method.

    摘要翻译: 含有丙烯结晶度的低分子量半结晶丙烯-α烯烃共聚物用作结晶聚丙烯和聚丙烯共聚物中的成核剂。 成核共聚物是结晶度为5-75%,熔点为45℃-105℃,MFR为300-5000g / 10min的丙烯-α-烯烃共聚物。 成核聚丙烯组合物包含在聚丙烯均聚物基质中混合的成核量的共聚物,或熔点大于110℃的0.01至9重量%的α-烯烃共聚物。成核共聚物改善处理时间,几乎没有或没有效果 关于基质的结晶性相关特征。 本发明还提供了使聚丙烯与成核剂结晶并形成具有该组合物的制品的方法,还提供了由该组合物和/或该方法形成的制品。