摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, mis 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I)to at least one compound of formula (II) CF3CZCHZ (II).where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要:
The present invention provides an ink for recordable media comprising a coating moiety and at least one fluorinated alcohol solvent for said at least one coating moiety, the fluorinated alcohol solvent preferably having a surface tension of not greater than about 27 dynes/cm. In certain preferred embodiments the fluorinated alcohol has the structure Rf—OH, wherein Rf is selected from the group consisting of H—[CX2]n—; Z-[CX2—CX2]n—; Z-[CZX—CX2]n—; Z-[CZX—CZX]n—; CZ2CH—; Z-[CX═CX]n—; Z-[CZ═CX]n; Z-[CZ═CZ]n—; Z-[CX2]n—; CX2═CX—[CX2]n—; and Z-CZX—CX(CZX2)—, wherein Z is independently —CF3, —CHF2, —CH2F; —R—CF3, —R—CHF2, or —R—CH2F, wherein R is a substituted or unsubstituted C1-C12 alkyl radical, or a substituted or unsubstituted fluorinated C1-C12 alkyl radical; X is independently hydrogen, Cl, Br, F, I, or Z; and n is an integer from 1 to 20.
摘要:
Ionic liquids having melting points below about 100 C formed by reaction of a heterocyclic amine with about 2.8 and about 3.2 moles of anhydrous hydrogen fluoride per mole of amine nitrogen. Electrochemical devices having non-aqueous electrolytes containing the ionic liquids are also disclosed, as well as silicon oxide etching compositions containing the ionic liquids and etching methods in which silicon oxides are selectively removed by the etching compositions in the presence of aluminum.
摘要:
The subject innovation relates to a system and method for presenting a multimedia object at a user device, the multimedia object having a predetermined format and being embedded into a document. Based upon a feature of the user device, a detection function is executed, the detection function determining that the document includes the multimedia object of the predetermined format, and based upon the determination, a multimedia player function is invoked in the user device, the multimedia player function being adapted to render the multimedia object.
摘要:
An improved system and method for the storage, transportation or delivery of chlorine is provided by mixing or dissolving the chlorine in organic salts that are non-reactive with chlorine and that lowers the vapor pressure of the chlorine to ambient pressure of about 14.7 psia or lower, and wherein the chlorine can be released or delivered by subjecting the mixture to heating or a vacuum.
摘要:
A method for the development or generation of pollution credits by the substitution of lower global warming potential (GWP) mixtures of halogenated hydrocarbons or mixtures of halogenated hydrocarbons with CO2 for fluorocarbons or fluorocarbon-containing compositions of higher GWP, such as for perfluorocarbon compounds (PFC's), hydrofluorocarbon compounds (HFC's), chlorofluorocarbons (CFC's), hydrochlorofluorocarbon compounds (HCFC's), and compositions thereof, in compositions and processes employing the higher GWP compounds, and receive allocation of pollution credits for such substitution.
摘要:
The invention relates to azeotropic and azeotrope-like mixtures of 1,1,1,3,3-pentachloropropane (HCC-240fa) and carbon tetrachloride and a process for separating the azeotrope-like mixtures. The compositions of the invention are useful as an intermediate in the production of HFC-245fa. The latter is useful as a nontoxic, zero ozone depleting fluorocarbon useful as a solvent, blowing agent, refrigerant, cleaning agent and aerosol propellant.
摘要:
Provided are azeotrope-like compositions comprising difluoroethane and trifluoroiodomethane, azeotrope-like compositions comprising difluoroethane, tetrafluoropropene and trifluoroiodomethane, and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, aerosol propellants and others.
摘要:
Provided are azeotrope-like compositions comprising tetrafluoropropene and hydrofluorocarbons and uses thereof, including use in refrigerant compositions, refrigeration systems, blowing agent compositions, and aerosol propellants.