摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I) to at least one compound of formula (II) CF3CZCHZ (II). where each X is independently Cl, F, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, mis 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要:
A method for preparing fluorinated organic compounds comprising contacting hydrogen fluoride with at least one compound of formula I: CX3CXYCH3 Iwhere each X is independently Cl, I or Br, and each Y is independently H or F, said contacting step being carried out under conditions effective to produce a compound of formula II CF3CZCH2 IIwhere Z is Cl, I, Br, or F.
摘要翻译:一种制备氟化有机化合物的方法,包括使氟化氢与至少一种式I化合物接触:<?in-line-formula description =“In-Line Formulas”end =“lead”→> 3 SUB >其中每个X独立地为Cl,I或Br,并且每个Y独立地为H,其中每个X独立地为H, 或F,所述接触步骤在有效产生式II化合物的条件下进行。&lt;线内公式描述=“在线配方”末端=“铅”→CF 3 CZCH II II <?in-line-formula description =“In-line Formulas”end =“tail”?>其中Z是Cl,I,Br或F.
摘要:
Disclosed are methods for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CHXCH2X (I) to at least one compound of formula (II) CF3CZCHZ (II). where X is independently Cl, Br, I or F, and Z independently is H or F. In certain preferred embodiments, each Z is different.
摘要:
Disclosed is a method for producing fluorinated organic compounds, including hydrofluoropropenes, which preferably comprises converting at least one compound of formula (I): CF3CFnCHmXa-m (I)to at least one compound of formula (II) CF3CZCHZ (II).where each X is independently Cl, I or Br; each Z is independently H or F; n is 1 or 2; m is 1, 2 or 3, provided that when n is 1, m is 1 or 2; a is 2 or 3, and a-m≧0. Certain embodiments include the step of reacting fluorinated C2 olefin, such as tetrafluoroethylene, with a Cl addition agent under conditions effective to produce a compound of formula (I).
摘要:
The present invention provides an ink for recordable media comprising a coating moiety and at least one fluorinated alcohol solvent for said at least one coating moiety, the fluorinated alcohol solvent preferably having a surface tension of not greater than about 27 dynes/cm. In certain preferred embodiments the fluorinated alcohol has the structure Rf—OH, wherein Rf is selected from the group consisting of H—[CX2]n—; Z-[CX2—CX2]n—; Z-[CZX—CX2]n—; Z-[CZX—CZX]n—; CZ2CH—; Z-[CX═CX]n—; Z-[CZ═CX]n; Z-[CZ═CZ]n—; Z-[CX2]n—; CX2═CX—[CX2]n—; and Z-CZX—CX(CZX2)—, wherein Z is independently —CF3, —CHF2, —CH2F; —R—CF3, —R—CHF2, or —R—CH2F, wherein R is a substituted or unsubstituted C1-C12 alkyl radical, or a substituted or unsubstituted fluorinated C1-C12 alkyl radical; X is independently hydrogen, Cl, Br, F, I, or Z; and n is an integer from 1 to 20.
摘要:
A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.
摘要:
Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising 1,3-dichloro-1,1,2,2,3-pentafluoropropane.
摘要:
Provided are methods for producing hydrofluorocarbons via the selective reduction of a halocarbon blend comprising 1,3-dichloro-1,1,2,2,3-pentafluoropropane.
摘要:
A method for preparing fluorinated organic compounds wherein at least one fluorinated olefin is reacted with methyl fluoride in the gas-phase and in the presence of a Lewis Acid catalyst to form at least one product having at least 3 carbon atoms.
摘要:
Disclosed is a process for the synthesis of 1,3,3,3-tetrafluoropropene comprising: a) reacting a compound of the formula (I) CHFX2 with a compound of formula (II) CH2═CF2 to produce a reaction product comprising a compound of formula (III) CHXFCH2CXF2, wherein each X is independently selected from the group consisting of chlorine, bromine and iodine; and (b) exposing said compound of formula (III) to reaction conditions effective to convert said compound to 1,3,3,3-tetrafluoropropene.