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    Catalytic oxidative process for producing maleic anhydride
    3.
    发明授权
    Catalytic oxidative process for producing maleic anhydride 失效
    用于生产马来酸酐的催化氧化方法

    公开(公告)号：US4110350A

    公开(公告)日：1978-08-29

    申请号：US816916

    申请日：1977-07-19

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    IPC分类号： B01J23/16 ,  B01J23/22 ,  B01J23/847 ,  B01J27/198 ,  C07C51/25 ,  C07D307/60

    CPC分类号： C07C51/25 ,  B01J23/16 ,  B01J23/22 ,  B01J23/8472 ,  B01J27/198 ,  C07C51/252

    摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride by using a catalyst, which consists essentially of oxides of (A) vanadium, (B) phosphorus, (C) titanium and (D) optionally at least one element selected from sodium, calcium, magnesium, iron, zirconium, boron, manganese, silver and molybdenum in the atomic ratios defined by the following formulaVP.sub.a Ti.sub.b X.sub.c O.sub.dwherein X is the element (D) set forth above and a=1.0 to 5.0, b=2.0 to 12.0 and c=0 to 1.0, and which catalyst is prepared by calcining a mixture of a vanadium-containing compound and titanium dioxide at a temperature of 650.degree. C. to 1,500.degree. C., incorporating into the mixture a phosphorus-containing compound and optionally the element "X"-containing compound and, then, heating the resulting mixture.

    摘要翻译： 具有4-6个碳原子的不饱和烃通过使用催化剂催化氧化成马来酸酐，所述催化剂基本上由（A）钒，（B）磷，（C）钛和（D​​）的氧化物组成，任选地至少一种选自 钠，钙，镁，铁，锆，硼，锰，银和钼，其原子比由下列化学式定义：VPaTibXcOd WHEREIN X是上述元素（D），a = 1.0至5.0，b = 2.0至12.0 并且c = 0至1.0，并且通过在650℃至1500℃的温度下煅烧含钒化合物和二氧化钛的混合物来制备该催化剂，将含磷化合物和任选地 含有元素“X”的化合物，然后加热所得混合物。

    Catalytic oxidative process for producing maleic anhydride
    5.
    发明授权
    Catalytic oxidative process for producing maleic anhydride 失效
    用于生产马来酸酐的催化氧化方法

    公开(公告)号：US4177161A

    公开(公告)日：1979-12-04

    申请号：US902935

    申请日：1978-05-05

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Harumi Ikezawa

    IPC分类号： B01J23/16 ,  B01J23/22 ,  B01J23/847 ,  B01J27/198 ,  C07C51/25 ,  B01J27/14

    CPC分类号： C07C51/25 ,  B01J23/16 ,  B01J23/22 ,  B01J23/8472 ,  B01J27/198 ,  C07C51/252

    摘要： Unsaturated hydrocarbons having 4 to 6 carbon atoms are catalytically oxidized into maleic anhydride by using a catalyst, which consists essentially of oxides of (A) vanadium, (B) phosphorus, (C) titanium and (D) optionally at least one element selected from sodium, calcium, magnesium, iron, zirconium, boron, manganese, silver and molybdenum in the atomic ratios defined by the following formulaVP.sub.a Ti.sub.b X.sub.c O.sub.dwherein X is the element (D) set forth above and a=1.0 to 5.0, b=2.0 to 12.0 and c=0 to 1.0, and which catalyst is prepared by calcining a mixture of a vanadium-containing compound and titanium dioxide at a temperature of 650.degree. C. to 1,500.degree. C., incorporating into the mixture a phosphorus-containing compound and optionally the element "X"-containing compound and, then, heating the resulting mixture.

    摘要翻译： 具有4-6个碳原子的不饱和烃通过使用催化剂催化氧化成马来酸酐，所述催化剂基本上由（A）钒，（B）磷，（C）钛和（D​​）的氧化物组成，任选地至少一种选自 钠，钙，镁，铁，锆，硼，锰，银和钼，其原子比由下式VPaTibXcOd定义，其中X是上述元素（D），a = 1.0至5.0，b = 2.0至12.0 并且c = 0至1.0，并且通过在650℃至1500℃的温度下煅烧含钒化合物和二氧化钛的混合物来制备该催化剂，将含磷化合物和任选地 含有元素“X”的化合物，然后加热所得混合物。

    Process for the preparation of maleic anhydride catalyst
    6.
    发明授权
    Process for the preparation of maleic anhydride catalyst 失效
    马来酸酐催化剂的制备方法

    公开(公告)号：US4154703A

    公开(公告)日：1979-05-15

    申请号：US820338

    申请日：1977-07-29

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Masataka Fuzinaga

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Fumihiko Sakai ,  Yasuo Bando ,  Masataka Fuzinaga

    IPC分类号： C07D307/60 ,  B01J23/00 ,  B01J23/22 ,  B01J27/00 ,  B01J31/36 ,  C07B61/00 ,  C07C51/25 ,  B01J27/14 ,  C07D307/89

    CPC分类号： B01J31/0258 ,  B01J23/22 ,  B01J31/0259 ,  B01J31/0267 ,  B01J31/36 ,  B01J31/38 ,  C07C51/252 ,  B01J2231/70 ,  B01J31/24

    摘要： Maleic anhydride is prepared by the catalytic oxidation of unsaturated hydrocarbons having 4 to 6 carbon atoms, at a temperature of from 350.degree. to 500.degree. C., in the presence of a catalyst which is produced by a method wherein a mixture of a titanium oxide and a vanadium compound in an atomic ratio of from 1 to 15 is calcined at a temperature of from 630.degree. to 1000.degree. C. to prepare a precursory catalyst, and wherein a gas mixture containing an organic phosphorus compound and a carrier gas is brought into contact with a mass of the percursory catalyst at a supply rate of the phosphorus compound being from 0.01 to 10 millimoles/hr per 1 ml of the mass of the percursory catalyst and at a temperature of from 350.degree. to 600.degree. C. during when a total amount of from 0.3 to 30 millimoles of the phosphorus compound per 1 ml of the mass of the precursory catalyst passes through the mass of the precursory catalyst.

    摘要翻译： 马来酸酐通过催化氧化具有4-6个碳原子的不饱和烃，在350-500℃的温度下，在催化剂的存在下制备，所述催化剂是通过以下方法制备的，其中将氧化钛 将原子比为1〜15的钒化合物在630〜1000℃的温度下煅烧，制备前体催化剂，将含有有机磷化合物和载气的气体混合物 以每1毫升质量催化剂的磷化合物的供给速率为0.01至10毫摩尔/小时，并且在350℃至600℃的温度下，与一批质量的催化剂接触， 总量为0.3至30毫摩尔的磷化合物/ 1毫升质量的前体催化剂通过前体催化剂的质量。

    Process for producing methacrolein
    7.
    发明授权
    Process for producing methacrolein 失效
    生产异丁烯醛的方法

    公开(公告)号：US4217309A

    公开(公告)日：1980-08-12

    申请号：US15903

    申请日：1979-02-28

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Yasuo Bando ,  Terumi Hisayuki

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Yasuo Bando ,  Terumi Hisayuki

    IPC分类号： B01J23/887 ,  B01J23/89 ,  C07C5/48 ,  C07C45/35 ,  C07C45/04

    CPC分类号： C07C5/48 ,  B01J23/8877 ,  B01J23/8993 ,  C07C45/35 ,  B01J2523/00

    摘要： Methacrolein is produced in a high yield by catalytically oxidizing isobutylene at a temperature of from 250.degree. to 500.degree. C. by using a catalyst represented by the formula:Mo.sub.a Co.sub.b Fe.sub.c Bi.sub.d Cs.sub.e X.sub.f Y.sub.g O.sub.hwherein X is either both vanadium and palladium, Y is at least one member selected from titanium, nickel, tin and zirconium, a=12, b=2-12, c=0.5-7, d=0.1-5, e=0.0005-0.5, f=0.01-2, g=0-5 and h is a positive number proportional to the number of oxygen atoms satisfying the average valency of the metal atoms stated in the formula, which catalyst has a high resistance to compression and abrasion and exhibits a high catalytic efficiency, mechanical strength and durability.

    摘要翻译： 通过使用由式MoaCobFecBidCseXfYgOh表示的催化剂，在250℃至500℃的温度下催化氧化异丁烯，以高产率生产甲基丙烯醛，其中X既是钒又是钯，Y是至少一种选自 钛，镍，锡和锆，a = 12，b = 2-12，c = 0.5-7，d = 0.1-5，e = 0.0005-0.5，f = 0.01-2，g = 0-5，h为 与氧原子数成比例的正数，其满足式中金属原子的平均价，该催化剂具有高抗压缩和耐磨性，并且具有高催化效率，机械强度和耐久性。

    Catalytic oxidation of isobutylene
    8.
    发明授权
    Catalytic oxidation of isobutylene 失效
    异丁烯的催化氧化

    公开(公告)号：US4171328A

    公开(公告)日：1979-10-16

    申请号：US917793

    申请日：1978-06-22

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Terumi Hisayuki

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Terumi Hisayuki

    IPC分类号： C07C47/22 ,  B01J23/00 ,  B01J23/887 ,  C07B61/00 ,  C07C45/00 ,  C07C45/35 ,  C07C67/00 ,  C07C45/02

    CPC分类号： B01J23/8876 ,  C07C45/35 ,  B01J2523/00

    摘要： Isobutylene is catalytically oxidized in the vapor phase with molecular oxygen to form methacrolein. The catalyst used consists essentially of metal oxides and is represented by the formula:Mo.sub.a Bi.sub.b Fe.sub.c Co.sub.d Zr.sub.e X.sub.f Ti.sub.g O.sub.hwherein Mo=molybdenum, Bi=bismuth, Fe=iron, Co=cobalt, Zr=zirconium, X=calcium and/or zinc, Ti=titanium and O=oxygen, and the subscripts indicating the atomic ratios of the respective metals to bismuth are: a=5-20, b=1, c=0.2-5, d=1-10, e=0.01-2, f=0.01-2, and g=0.01-1. The catalyst exhibits little or no reduction in mechanical strength during the oxidation reaction and results in an enhanced yield of methacrolein.

    摘要翻译： 异丁烯在气相中用分子氧催化氧化形成甲基丙烯醛。 所使用的催化剂基本上由金属氧化物组成，并由下式表示：MoaBibFecCodZreXfTigOh WHEREIN Mo =钼，Bi =铋，Fe =铁，Co =钴，Zr =锆，X =钙和/或锌，Ti =钛和O =氧，表示各金属与铋的原子比的下标为：a = 5-20，b = 1，c = 0.2-5，d = 1-10，e = 0.01-2，f = 2，g = 0.01-1。 该催化剂在氧化反应期间几乎没有或没有降低机械强度，并导致甲基丙烯醛的收率提高。

    Method for the preparation of methacrylic acid
    9.
    发明授权
    Method for the preparation of methacrylic acid 失效
    制备甲基丙烯酸的方法

    公开(公告)号：US4045478A

    公开(公告)日：1977-08-30

    申请号：US658909

    申请日：1976-02-18

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Fumio Adachi

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Kenichi Suzuki ,  Fumio Adachi

    IPC分类号： B01J23/28 ,  B01J27/186 ,  C07C51/25 ,  C07C57/055 ,  C07C51/32

    CPC分类号： B01J27/186 ,  B01J23/28 ,  C07C51/252

    摘要： Methacrylic acid can be produced from methacrolein with a high reaction percentage of methacrolein and a high selectivity percentage of methacrylic acid, by bringing a reaction feed containing methacrolein and molecular oxygen into contact with an oxidation catalyst at a temperature of 200 to 450.degree. C, the oxidation catalyst comprising oxides of molybdenum, phosphorus, calcium, at least one element selected from the group consisting of arsenic, bismuth, tin, titanium, tantalum and boron and, optionally, at least one element selected from the group consisting of antimony, niobium and magnesium.

    摘要翻译： 甲基丙烯酸可以通过甲基丙烯醛的高反应百分率和甲基丙烯酸的高选择性百分比通过使含有甲基丙烯醛和分子氧的反应进料与氧化催化剂在200至450℃的温度下接触来生产， 氧化催化剂，其包含钼，磷，钙的氧化物，选自砷，铋，锡，钛，钽和硼中的至少一种元素，以及任选的至少一种选自锑，铌和 镁。

    Ammoxidation catalyst for the production of acrylonitrile from propylene and process for producing the same
    10.
    发明授权
    Ammoxidation catalyst for the production of acrylonitrile from propylene and process for producing the same 失效
    用于从丙烯生产丙烯腈的氨氧化催化剂及其制备方法

    公开(公告)号：US4290922A

    公开(公告)日：1981-09-22

    申请号：US134053

    申请日：1980-03-26

    申请人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

    发明人： Sumio Umemura ,  Kyoji Ohdan ,  Mikio Hidaka ,  Toshio Kurafuji

    IPC分类号： B01J23/88 ,  C07B61/00 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J21/06 ,  B01J23/24

    CPC分类号： B01J23/8872 ,  B01J23/8876 ,  B01J23/8877 ,  B01J23/8878 ,  C07C253/26 ,  Y02P20/52

    摘要： A catalyst for the ammoxidation of propylene to prepare acrylonitrile with a high yield thereof comprising an oxide composition of the empirical formula (I)Mo.sub.a Co.sub.b Ni.sub.c Fe.sub.d Bi.sub.e V.sub.f Ca.sub.g K.sub.h X.sub.i Si.sub.j O.sub.k (I)wherein X is zirconium and/or chromium, the subscripts a, b, c, d, e, f, g, h, i and j respectively denote the number of the respective atoms of the elements, when a=10, b=0 to 8, c=0 to 8, (b+c)=2 to 10, d=0.3 to 7, e=0.01 to 3, f=0.01 to 2, g=0.01 to 5, h=0.05 to 0.5, i=0 to 2, j=10 to 50, and the subscript k denotes the number of oxygen atoms which satisfies the average valency of the elements other than oxygen and the ratio a:k being in a range of 10:30 to 80, which catalyst is prepared by preparing an aqueous slurry containing respective element-containing compounds, by spray drying the aqueous slurry to prepare a dried solid precursory catalyst and, finally, by calcining the precursory catalyst as a temperature of from 500.degree. to 750.degree. C. to provide an activated catalyst.

    摘要翻译： 用于丙烯氨氧化以制备丙烯腈的高产率的催化剂，其包含经验式（I）的氧化物组合物，其中X是锆和/或铬，下标a，b，c，d，e的MoaCobNicFedBieVfCagKhXiSijOk（I） 当a = 10，b = 0〜8，c = 0〜8，（b + c）= 2〜10时，f，g，h，i，j分别表示各元素的原子数，d = 0.3〜7，e = 0.01〜3，f = 0.01〜2，g = 0.01〜5，h = 0.05〜0.5，i = 0〜2，j = 10〜50，下标k表示氧数 原子，其满足除氧之外的元素的平均化合价，a:k的比例在10:30至80的范围内，该催化剂通过制备含有各含元素化合物的含水浆料，通过喷雾干燥水溶液 浆料以制备干燥的固体前体催化剂，最后通过在500℃至750℃的温度下煅烧前体催化剂以提供活化的催化剂。