Partially deactivated metal catalysts and methods for preparing the same
    2.
    发明授权
    Partially deactivated metal catalysts and methods for preparing the same 有权
    部分失活的金属催化剂及其制备方法

    公开(公告)号:US08012902B2

    公开(公告)日:2011-09-06

    申请号:US12323611

    申请日:2008-11-26

    摘要: Disclosed are partially deactivated metal catalysts useful for modifying structures of nanomaterials. The present invention is also directed to a method for preparing the partially deactivated metal catalysts, which comprises patterning a substrate with micelles containing iron nanoparticles, removing the micelles from the patterned substrate to deposit the iron nanoparticles thereon, nitriding the iron nanoparticles using a nitrogen plasma, and exposing the nitrided iron nanoparticles to a mixture of ethanol and nitric acid to remove iron from the surface of the nitrided nanoparticles. The iron nitride metal catalyst with a nano-size according to the present invention comprises a core that includes deactivated iron nitride and an active shell surrounding the core. Thus, when preparing a carbon nanotube, the metal catalyst can be effectively used to control the number of walls formed in the carbon nanotube.

    摘要翻译: 公开了用于改性纳米材料结构的部分失活的金属催化剂。 本发明还涉及一种制备部分失活的金属催化剂的方法,其包括用含有铁纳米颗粒的胶束对基材进行图案化,从图案化的基底去除胶束以在其上沉积铁纳米颗粒,使用氮等离子体对铁纳米颗粒进行氮化 ,并将氮化铁纳米颗粒暴露于乙醇和硝酸的混合物中以从氮化纳米颗粒的表面除去铁。 根据本发明的具有纳米尺寸的氮化铁金属催化剂包括包含钝化的氮化铁和包围芯的活性壳的芯。 因此,当制备碳纳米管时,金属催化剂可以有效地用于控制在碳纳米管中形成的壁的数量。

    Metal cation-doped covalent organic framework derivatives for hydrogen storage and method of using the same
    3.
    发明申请
    Metal cation-doped covalent organic framework derivatives for hydrogen storage and method of using the same 有权
    用于氢存储的金属阳离子掺杂共价有机骨架衍生物及其使用方法

    公开(公告)号:US20110236301A1

    公开(公告)日:2011-09-29

    申请号:US11987953

    申请日:2007-12-06

    IPC分类号: C01B3/02 B01J20/22

    摘要: Disclosed are a novel hydrogen storage material with enhanced hydrogen storage capacity prepared by doping an organic framework material with light metal cations, and a method of using the same for hydrogen storage. The present inventive material has at least one phenyl group at each face of a triangular building unit, which is doped with metal cations such as alkali metal cations, alkali-earth metal cations, etc., so that the material exhibits greatly improved capacity of hydrogen absorption and desorption at room temperature and can provide hydrogen storage materials practically adapted for fuel batteries useable even at room temperature.

    摘要翻译: 公开了一种具有通过用轻金属阳离子掺杂有机骨架材料制备的具有增强的储氢能力的新型储氢材料,以及将其用于储氢的方法。 本发明的材料在三角形建筑单元的每个面上具有至少一个苯基,其被掺杂有金属阳离子如碱金属阳离子,碱土金属阳离子等,使得该材料显示出大大提高的氢容量 在室温下吸收和解吸,并且可以提供实际适用于甚至在室温下可用的燃料电池的储氢材料。

    Partially Deactivated Metal Catalysts and Methods for Preparing the Same
    4.
    发明申请
    Partially Deactivated Metal Catalysts and Methods for Preparing the Same 有权
    部分去活化金属催化剂及其制备方法

    公开(公告)号:US20100022384A1

    公开(公告)日:2010-01-28

    申请号:US12323611

    申请日:2008-11-26

    IPC分类号: B01J27/24

    摘要: Disclosed are partially deactivated metal catalysts useful for modifying structures of nanomaterials. The present invention is also directed to a method for preparing the partially deactivated metal catalysts, which comprises patterning a substrate with micelles containing iron nanoparticles, removing the micelles from the patterned substrate to deposit the iron nanoparticles thereon, nitriding the iron nanoparticles using a nitrogen plasma, and exposing the nitrided iron nanoparticles to a mixture of ethanol and nitric acid to remove iron from the surface of the nitrided nanoparticles. The iron nitride metal catalyst with a nano-size according to the present invention comprises a core that includes deactivated iron nitride and an active shell surrounding the core. Thus, when preparing a carbon nanotube, the metal catalyst can be effectively used to control the number of walls formed in the carbon nanotube.

    摘要翻译: 公开了用于改性纳米材料结构的部分失活的金属催化剂。 本发明还涉及一种制备部分失活的金属催化剂的方法,其包括用含有铁纳米颗粒的胶束对基材进行图案化,从图案化的基底去除胶束以在其上沉积铁纳米颗粒,使用氮等离子体对铁纳米颗粒进行氮化 ,并将氮化铁纳米颗粒暴露于乙醇和硝酸的混合物中以从氮化纳米颗粒的表面除去铁。 根据本发明的具有纳米尺寸的氮化铁金属催化剂包括包含钝化的氮化铁和围绕芯的活性壳的芯。 因此,当制备碳纳米管时,金属催化剂可以有效地用于控制在碳纳米管中形成的壁的数量。

    Metal cation-doped covalent organic framework derivatives for hydrogen storage and method of using the same
    5.
    发明授权
    Metal cation-doped covalent organic framework derivatives for hydrogen storage and method of using the same 有权
    用于氢存储的金属阳离子掺杂共价有机骨架衍生物及其使用方法

    公开(公告)号:US08088356B2

    公开(公告)日:2012-01-03

    申请号:US11987953

    申请日:2007-12-06

    IPC分类号: B01J20/00 C07F5/02

    摘要: Disclosed are a novel hydrogen storage material with enhanced hydrogen storage capacity prepared by doping an organic framework material with light metal cations, and a method of using the same for hydrogen storage. The present inventive material has at least one phenyl group at each face of a triangular building unit, which is doped with metal cations such as alkali metal cations, alkali-earth metal cations, etc., so that the material exhibits greatly improved capacity of hydrogen absorption and desorption at room temperature and can provide hydrogen storage materials practically adapted for fuel batteries useable even at room temperature.

    摘要翻译: 公开了一种具有通过用轻金属阳离子掺杂有机骨架材料制备的具有增强的储氢能力的新型储氢材料,以及将其用于储氢的方法。 本发明的材料在三角形建筑单元的每个面上具有至少一个苯基,其被掺杂有金属阳离子如碱金属阳离子,碱土金属阳离子等,使得该材料显示出大大提高的氢容量 在室温下吸收和解吸,并且可以提供实际适用于甚至在室温下可用的燃料电池的储氢材料。

    Electromagnetic control valve
    6.
    发明授权
    Electromagnetic control valve 失效
    电磁调节阀

    公开(公告)号:US07007917B2

    公开(公告)日:2006-03-07

    申请号:US10780837

    申请日:2004-02-19

    IPC分类号: F16K31/08

    CPC分类号: F16K31/0655 F16K31/082

    摘要: An electromagnetic control valve having a permanent magnet and a needle are fitted in a cylindrical valve body, and a coil, and first and second yokes are mounted on an outside circumferential surface of the valve body. There are first and second ports in the valve body for making an outside space and an inside space of the valve body in communication. There is an orifice in the valve body for making the first and the second ports in communication. The needle is disposed at a position opposite to a side of the orifice, for moving in an up/down direction when a current is applied to the coil. Direction and amount of movement of the needle are dependent on a direction and an intensity of the current applied to the coil. When the needle moves, a tip of the needle varies an opened area of the orifice linearly, according to which a flow rate of the fluid passed through the orifice is controlled according to a position of the needle.

    摘要翻译: 具有永磁体和针的电磁控制阀装配在圆筒形阀体中,线圈和第一和第二轭安装在阀体的外周面上。 在阀体中有第一和第二端口用于使外部空间和阀体的内部空间连通。 在阀体中存在用于使第一和第二端口连通的孔口。 针设置在与孔的一侧相对的位置,用于当电流施加到线圈时沿上/下方向移动。 针的移动方向和移动量取决于施加到线圈的电流的方向和强度。 当针移动时,针的尖端线性地改变孔的开口面积,根据该尖端,通过孔的流体的流量根据针的位置被控制。