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    Photographic element having improved magenta dye light stability and process for its use
    2.
    发明授权
    Photographic element having improved magenta dye light stability and process for its use 失效
    具有改善的品红染料光稳定性的照相元件及其使用方法

    公开(公告)号：US5985533A

    公开(公告)日：1999-11-16

    申请号：US24034

    申请日：1998-02-16

    申请人： Robert F. Romanet ,  Paul A. Burns ,  Susan M. Fischer ,  Paul P. Spara ,  Rajiv P. Balasubramanian ,  David G. Lincoln ,  Daniel L. Kapp

    发明人： Robert F. Romanet ,  Paul A. Burns ,  Susan M. Fischer ,  Paul P. Spara ,  Rajiv P. Balasubramanian ,  David G. Lincoln ,  Daniel L. Kapp

    IPC分类号： G03C7/38 ,  G03C1/08 ,  G03C7/26 ,  G03C7/32

    CPC分类号： G03C7/3835

    摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula II: whereinX is hydrogen or a coupling-off group;R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent;R.sup.a is hydrogen or a substituent;Y is a substituent with at least one Y substituent having a formula selected from the group consisting of --CONR.sup.b R.sup.c, --NHCOR.sup.d, and --SO.sub.2 R.sup.e, wherein R.sup.b, R.sup.c, and R.sup.d are independently selected from the group consisting of H, alkyl, aryl, and heterocyclic groups and R.sup.e is selected from the group consisting of an alkyl group, an aryl group, a heterocyclic group, --NR.sup.g R.sup.h, and --OR.sup.i wherein R.sup.g, R.sup.h, and R.sup.i are selected from the same group as R.sup.a and n is from 1 to 5.The element exhibits improved magenta dye light stability.

    摘要翻译： 本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式II所代表的染料形成成色剂：其中X为氢或偶合离去基团; R 1，R 2和R 3是独立选择的烷基，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; Ra是氢或取代基; Y是具有至少一个具有选自-CONRbRc，-NHCORd和-SO2Re的Y取代基的取代基，其中Rb，Rc和Rd独立地选自H，烷基，芳基， 和杂环基，并且Re选自烷基，芳基，杂环基，-NRgRh和-ORi，其中R g，Rh和R i选自与Ra相同的基团，n为1 该元件表现出改善的品红染料光稳定性。

    Photographic element having improved dye stability, compound, and imaging process
    3.
    发明授权
    Photographic element having improved dye stability, compound, and imaging process 失效
    具有改善的染料稳定性，化合物和成像方法的摄影元件

    公开(公告)号：US06291152B1

    公开(公告)日：2001-09-18

    申请号：US09707636

    申请日：2000-11-07

    申请人： Paul A. Burns ,  Robert F. Romanet ,  Susan M. Fischer ,  David G. Lincoln ,  Paul P. Spara

    发明人： Paul A. Burns ,  Robert F. Romanet ,  Susan M. Fischer ,  David G. Lincoln ,  Paul P. Spara

    IPC分类号： G03C108

    CPC分类号： G03C7/3825 ,  G03C7/3212 ,  G03C7/3835

    摘要： Disclosed is a photographic element comprising a light-sensitive silver halide emulsion layer having associated therewith a bicyclic azole dye-forming coupler, having appended to a ring carbon at a non-coupling position thereof a substituent group represented by the formula: wherein the arrow represents the point of attachment of the substituent group to a non-coupling position of the coupler; R1, R2, R3 and R4 are independently selected hydrogen or substituent groups, provided that any two of R1, R2, R3 and R4 may join to form a ring; Ra and Rb are independently hydrogen or a substituent; each Rc and Rd is an independently selected hydrogen or an alkyl or aryl group, provided that any two of them may join to form a ring and n is 1 to 10; Re is hydrogen or an alkyl or aryl group; each Y is an independently selected substituent group and m is from 0 to 4; and Z is a substituent selected from the group consisting of —C(O)R5, —S(O)2R5, —SOR5, —P(═O)(R6)2 and —P(═O)(OR6)2 in which R5 is selected from the group consisting of alkyl, aryl, heterocyclic, alkoxy, aryloxy, alkylamino, and arylamino groups and each R6 is independently selected from the group consisting of alkyl and aryl groups; provided that Z can form a ring with any one of Rc and Rd. Such an element provides improved image dye stability.

    摘要翻译： 公开了一种照相元件，其包含感光卤化银乳剂层，该感光卤化银乳剂层具有与其相连的双环唑形染料形成成色剂，其在非偶合位置附加有环碳，由下式表示的取代基：其中箭头表示 取代基与偶联剂的非偶联位置的连接点; R 1，R 2，R 3和R 4独立地选自氢或取代基，条件是R 1，R 2，R 3和R 4中的任何两个可以连接形成 R a和R b独立地是氢或取代基;每个R c和R d是独立选择的氢或烷基或芳基，条件是它们中的任何两个可以连接形成环，n是1至10; Re是氢 或烷基或芳基;每个Y是独立选择的取代基，m是0-4; 并且Z是选自-C（O）R 5，-S（O）2 R 5，-SOR 5，-P（= O）（R 6）2和-P（= O）（OR 6）2的取代基，其中 R5选自烷基，芳基，杂环，烷氧基，芳氧基，烷基氨基和芳基氨基，每个R6独立地选自烷基和芳基; 只要Z可以与Rc和Rd中的任何一个形成环。 这样的元素提供了改进的图像染料稳定性。

    Photographic element having improved magenta dye light stability and process for its use
    4.
    发明授权
    Photographic element having improved magenta dye light stability and process for its use 失效
    具有改善的品红染料光稳定性的照相元件及其使用方法

    公开(公告)号：US5972587A

    公开(公告)日：1999-10-26

    申请号：US024032

    申请日：1998-02-16

    申请人： Robert F. Romanet ,  Paul A. Burns ,  Susan M. Fischer ,  Paul P. Spara ,  Rajiv P. Balasubramanian ,  David G. Lincoln

    发明人： Robert F. Romanet ,  Paul A. Burns ,  Susan M. Fischer ,  Paul P. Spara ,  Rajiv P. Balasubramanian ,  David G. Lincoln

    IPC分类号： G03C7/384 ,  G03C7/38 ,  G03C1/08 ,  G03C7/26 ,  G03C7/32

    CPC分类号： G03C7/3835

    摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula II: ##STR1## wherein X is hydrogen or a coupling-off group;R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2 and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent;R.sup.a is hydrogen or a substituent;each Y is an independently selected substituent with at least one Y substituent in the 2-position (relative to oxygen) having the formula --NHSO.sub.2 R.sup.f, wherein R.sup.f is an alkyl or aryl group, and n is from 1 to 5.The element exhibits improved magenta dye light stability.

    摘要翻译： 本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式II所代表的染料形成成色剂：其中X为氢或偶合离去基团; R 1，R 2和R 3是独立选择的烷基，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; Ra是氢或取代基; 每个Y是在具有式-NHSO 2 R f的2-位（相对于氧）中具有至少一个Y取代基的独立选择的取代基，其中Rf是烷基或芳基，n是1至5.元素表现出改进 品红染料光稳定。

    Photographic element having improved magenta dye light stability and process for its use
    6.
    发明授权
    Photographic element having improved magenta dye light stability and process for its use 失效
    具有改善的品红染料光稳定性的照相元件及其使用方法

    公开(公告)号：US5925503A

    公开(公告)日：1999-07-20

    申请号：US784851

    申请日：1997-01-15

    申请人： John W. Harder ,  Paul A. Burns ,  Paul P. Spara

    发明人： John W. Harder ,  Paul A. Burns ,  Paul P. Spara

    IPC分类号： G03C7/38 ,  G03C7/46

    CPC分类号： G03C7/3835

    摘要： The invention provides a photographic element comprising a silver halide emulsion layer having associated therewith a dye-forming coupler represented by formula I: ##STR1## wherein X is hydrogen or a coupling-off group; andR' is a tertiary alkyl group and R" represents the group ##STR2## in which R.sup.1, R.sup.2, and R.sup.3 are independently selected alkyl groups, provided that any two of R.sup.1, R.sup.2, and R.sup.3 may join to form a ring;R.sup.4 is hydrogen or a substituent, provided that R.sup.3 and R.sup.4 may join to form a ring when R.sup.4 is a substituent; andW is a substituent selected from the group consisting of --C(O)R.sup.5, --SO.sub.2 R.sup.5, and --P(O)(OR.sup.6).sub.2 in which R.sup.5 is selected from the group consisting of alkyl, aryl, alkoxy, aryloxy, alkylamino, and arylamino groups and R.sup.6 is selected from the group consisting of alkyl and aryl groups.The element exhibits improved magenta dye light stability.

    摘要翻译： 本发明提供了一种照相元件，其包含卤化银乳剂层，其具有与式I化合物形成的染料形成成色剂：其中X为氢或偶合离去基团; 并且R'是叔烷基，R“表示其中R 1，R 2和R 3是独立选择的烷基的基团，条件是R 1，R 2和R 3中的任何两个可以连接形成环; R4是氢或取代基，条件是当R 4为取代基时，R 3和R 4可以连接形成环; 并且W是选自-C（O）R 5，-SO 2 R 5和-P（O）（OR 6）2的取代基，其中R 5选自烷基，芳基，烷氧基，芳氧基，烷基氨基 和芳基氨基，R 6选自烷基和芳基。 该元件表现出改善的品红染料光稳定性。

    Compositions of iodophenoxy alkanes and iodophenyl ethers in film-forming materials for visualization of the gastrointestinal tract
    7.
    发明授权
    Compositions of iodophenoxy alkanes and iodophenyl ethers in film-forming materials for visualization of the gastrointestinal tract 失效
    用于可视化胃肠道的成膜材料中碘苯氧基烷烃和碘苯基醚的组成

    公开(公告)号：US5326553A

    公开(公告)日：1994-07-05

    申请号：US12171

    申请日：1993-02-02

    申请人： Carl R. Illig ,  Eugene R. Cooper ,  John L. Toner ,  Donald A. Upson ,  Brent D. Douty ,  Thomas J. Caulfield ,  Bacon, Edward R. ,  Kimberly G. Estep ,  Kurt A. Josef ,  Shaughnessy Robinson ,  Paul P. Spara

    发明人： Carl R. Illig ,  Eugene R. Cooper ,  John L. Toner ,  Donald A. Upson ,  Brent D. Douty ,  Thomas J. Caulfield ,  Bacon, Edward R. ,  Kimberly G. Estep ,  Kurt A. Josef ,  Shaughnessy Robinson ,  Paul P. Spara

    IPC分类号： A61K49/04 ,  A61K31/075

    CPC分类号： A61K49/0433 ,  Y10S514/941 ,  Y10S514/942

    摘要： Disclosed are x-ray contrast compositions for oral or retrograde examination of the gastrointestinal tract comprising a polymeric material capable of forming a coating on the gastrointestinal tract and an x-ray producing agent of the formula ##STR1## and methods for their use in diagnostic radiology of the gastrointestinal tract whereinZ=H, halo, C.sub.1 -C.sub.20 alkyl, cycloalkyl, lower alkoxy, cyano, where the alkyl and cycloalkyl groups can be substituted with halogen or halo-lower-alkyl groups;R=C.sub.1 -C.sub.25 alkyl, cycloalkyl, or halo-lower-alkyl, optionally substituted with halo, fluoro-lower-alkyl, aryl, lower-alkoxy, hydroxy, carboxy, lower-alkoxy carbonyl or lower-alkoxycarbonyloxy, (CR.sub.1 R.sub.2).sub.p-- (CR.sub.3 .dbd.CR.sub.4).sub.m Q, or (CR.sub.1 R.sub.2).sub.p --C.tbd.C--Q;R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently lower-alkyl, optionally substituted with halo;x is 1-4;n is 1-5;m is 1-15;p is 1-10; andQ is H, lower-alkyl, lower-alkenyl, lower-alkynyl, lower-alkylene, aryl, or aryl-lower alkylin a pharmaceutically acceptable carrier.

    摘要翻译： 公开了用于口腔或逆行检查胃肠道的x射线造影剂组合物，其包含能够在胃肠道上形成涂层的聚合物材料和具有式“IMAGE”的X射线产生剂及其用于诊断放射学的方法 的胃肠道，其中Z = H，卤素，C 1 -C 20烷基，环烷基，低级烷氧基，氰基，其中烷基和环烷基可被卤素或卤代低级烷基取代; 任选被卤素，氟 - 低级 - 烷基，芳基，低级 - 烷氧基，羟基，羧基，低级 - 烷氧基羰基或低级 - 烷氧基羰基氧基取代的C 1 -C 25烷基，环烷基或卤代低级烷基，（CR 1 R 2）p - （CR3 = CR4）mQ，或（CR1R2）pC 3BOND CQ; R 1，R 2，R 3和R 4独立地为低级烷基，任选被卤素取代; x为1-4; n为1-5; m为1-15; p为1-10; Q为药学上可接受的载体中的H，低级烷基，低级烯基，低级炔基，低级亚烷基，芳基或芳基 - 低级烷基。

    Low melting point ionizable epoxy scavengers for residual magenta couplers
    8.
    发明授权
    Low melting point ionizable epoxy scavengers for residual magenta couplers 失效
    用于残留品红色成色剂的低熔点电离环氧清除剂

    公开(公告)号：US5627017A

    公开(公告)日：1997-05-06

    申请号：US427764

    申请日：1995-04-25

    申请人： Krishnan Chari ,  Paul P. Spara ,  Sundaram Krishnamurthy

    发明人： Krishnan Chari ,  Paul P. Spara ,  Sundaram Krishnamurthy

    IPC分类号： C07D303/16 ,  C07D303/22 ,  C07D303/34 ,  C07D303/42 ,  C07D303/46 ,  C07D405/12 ,  C07F5/02 ,  C07F9/655 ,  G03C1/005 ,  G03C7/392 ,  G03C7/388

    CPC分类号： C07D303/22 ,  C07D303/16 ,  C07D303/34 ,  C07D303/42 ,  C07D303/46 ,  C07D405/12 ,  C07F5/025 ,  C07F9/65502 ,  G03C1/005 ,  G03C7/39268 ,  G03C7/39296 ,  Y10S430/136

    摘要： Low melting point epoxy scavenger compounds are disclosed which contain a pH dependent ionizable group to facilitate migration of the scavenger from an adjacent scavenger layer (that does not contain any coupler) to an imaging layer (containing coupler and emulsion) of a photographic element at the pH of development. One aspect of the invention comprises a process of forming an aqueous dispersion of an epoxy compound of the structural formula SI: ##STR1## wherein: R is H, an alkyl group, or an aryl group; L.sub.1 is an alkyl group or an aryl group; L.sub.2 is --O--, --CO--, --S--, --SO.sub.2 --, --PO.sub.2 --, --CO.sub.2 --, --NHCO-- or --NHSO.sub.2 --, wherein L.sub.2 may be orientated in either direction; L.sub.3 is an alkyl group; m is 0 or 1; p is 0 or 1; and X is ##STR2## wherein R' is H or an alkyl or aryl group, with the proviso that where L.sub.2 comprises an ionizable group, X may also be an alkyl group or an aryl group; wherein the compound has a melting point of less than about 50.degree. C. and the process comprises adding the compound in a liquid state to an aqueous solution, and directly dispersing the compound in the aqueous solution. Thermal and photochemical yellowing of a color photographic element, such as a color print, is inhibited by incorporating such compounds into the photographic element.

    摘要翻译： 公开了低熔点环氧清除剂化合物，其含有pH依赖性可电离基团，以促进清除剂从相邻的清除剂层（不含任何偶合剂）迁移至摄影元件的成像层（含有偶联剂和乳液） 发展pH。 本发明的一个方面包括形成结构式为SI：n芳基的环氧化合物的水分散体的方法; L1是烷基或芳基; L 2是-O-，-CO-，-S-，-SO 2 - ， - O 2 - ， - CO 2 - ， - NHCO-或-NHSO 2 - ，其中L2可以沿任一方向取向; L3是烷基; m为0或1; p为0或1; 并且X是，其中R'是H或烷基或芳基，条件是其中L2包含可离子化基团，X也可以是烷基或芳基; 其中所述化合物具有小于约50℃的熔点，并且所述方法包括将液体中的化合物加入到水溶液中，并将化合物直接分散在水溶液中。 通过将这样的化合物并入照相元件中，可以抑制彩色照相元件如彩色印刷的热和光化学变黄。