公开(公告)号：US20240178445A1

公开(公告)日：2024-05-30

申请号：US18518741

申请日：2023-11-24

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： Keiichi MINAMI ,  Ryoji KANNO ,  Satoshi HORI

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01M2004/028

Abstract: A sulfide solid electrolyte material contains element M1, element M2, element M3 and element S. Element M1 is at least one type selected from the group consisting of Li, Na, K, Mg Ca and Zn, and contains at least one of Li and Na. Element M2 is at least one type selected from the group consisting of P, Sb, Si, Ge, Sn, B, Al, Ga, In, Ti, Zr and V, and contains at least P.

公开(公告)号：US20230253613A1

公开(公告)日：2023-08-10

申请号：US17958785

申请日：2022-10-03

Applicant: TOKYO INSTITUTE OF TECHNOLOGY ,  TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Ryoji KANNO ,  Satoshi HORI ,  Keiichi MINAMI ,  Shinya SHIOTANI

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01M2300/0068

Abstract: A main object of the present disclosure is to provide a sulfide solid electrolyte with excellent water resistance. The present disclosure achieves the object by providing a sulfide solid electrolyte including a LGPS type crystal phase, and containing Li, Ge, P, and S, wherein: when an X-ray photoelectron spectroscopy measurement is conducted to a surface of the sulfide solid electrolyte, a proportion of Ge2+ with respect to total amount of Ge is 20% or more.

公开(公告)号：US20240088434A1

公开(公告)日：2024-03-14

申请号：US18512840

申请日：2023-11-17

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Motoshi ISONO ,  Masato ONO ,  Keiichi MINAMI ,  Kazuhito KATO ,  Katsuaki ODAGI

IPC: H01M10/0562 ,  H01M4/134 ,  H01M10/0525 ,  H01M10/0585 ,  H01M10/42

CPC classification number: H01M10/0562 ,  H01M4/134 ,  H01M10/0525 ,  H01M10/0585 ,  H01M10/42 ,  H01M2004/028

Abstract: An all-solid-state battery includes a case, a battery element, and a restraint component. The case accommodates the battery element. The battery element includes an electrode part and a resin part. The resin part covers at least a part of a side face of the electrode part. The restraint component applies a first pressure to the electrode part. The restraint component applies a second pressure to the resin part. The ratio of the second pressure to the first pressure is from 1.5 to 18.

公开(公告)号：US20230411735A1

公开(公告)日：2023-12-21

申请号：US18135888

申请日：2023-04-18

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: H01M10/6571 ,  H01M10/63 ,  H01M10/0562 ,  H01M10/48

CPC classification number: H01M10/6571 ,  H01M10/63 ,  H01M10/0562 ,  H01M10/48 ,  H01M2300/0071 ,  H01M2300/0068

Abstract: The secondary battery system according to the present disclosure includes a secondary battery, a heating device, and a control device, and the secondary battery includes a positive electrode and a negative electrode, and one or both of the positive electrode and the negative electrode include an active material, a solid electrolyte, and a Li containing salt, and the active material includes a material whose volume changes with charging and discharging of the secondary battery, and a target heated by the heating device includes Li containing salt, and the control device controls the heating by the heating device such that when it is determined that the performance of the secondary battery is equal to or lower than a certain level, the temperature of Li containing salt becomes equal to or higher than the melting point of Li containing salt.

公开(公告)号：US20200313234A1

公开(公告)日：2020-10-01

申请号：US16829018

申请日：2020-03-25

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: H01M10/0562 ,  H01M10/0525

Abstract: A main object of the present disclosure is to provide a sulfide solid electrolyte with high ion conductivity. In the present disclosure, the above object is achieved by providing a sulfide solid electrolyte comprising: a Li element, an M element (M is at least one kind of P, Ge, Si and Sn), and a S element, and the sulfide solid electrolyte has an argyrodite type crystal phase, in 31P-MAS-NMR, the sulfide solid electrolyte has peak A at 82.1 ppm±0.5 ppm and peak B at 86.1 ppm±0.5 ppm, and when an area ratio of the peak A is regarded as SA, and an area ratio of the peak B is regarded as SB, a proportion of the SB to the SA, that is SB/SA, is 0.23 or less.

公开(公告)号：US20160023192A1

公开(公告)日：2016-01-28

申请号：US14789068

申请日：2015-07-01

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: B01J23/889 ,  B01D53/86 ,  B01J23/00

CPC classification number: B01J23/8892 ,  B01D53/8628 ,  B01D53/9418 ,  B01D2255/20707 ,  B01D2255/2073 ,  B01D2255/20746 ,  B01D2257/404 ,  B01D2258/012 ,  B01J23/002 ,  B01J2523/00 ,  Y02C20/10 ,  B01J2523/47 ,  B01J2523/72 ,  B01J2523/845

Abstract: To provide an excellent exhaust gas purification catalyst with satisfactory NOx selective reductive purification performance at lower temperature, and having a satisfactory N2O formation rate.A selective reduction catalyst for exhaust gas purification, represented by the formula: CoxMn(1−x)TiO3 (where x in the molar ratio is a value greater than 0 and 0.2 or less).

Abstract translation: 提供在较低温度下具有令人满意的NOx选择还原净化性能的优异的废气净化催化剂，并且具有令人满意的N2O形成速率。 一种用于排气净化的选择性还原催化剂，其由下式表示：CoxMn（1-x）TiO3（其中x的摩尔比为大于0且为0.2或更小的值）。

公开(公告)号：US20240347762A1

公开(公告)日：2024-10-17

申请号：US18627445

申请日：2024-04-05

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI ,  Hikaru SUGANUMA

IPC: H01M10/0562

CPC classification number: H01M10/0562 ,  H01M2300/0068

Abstract: A method of producing a sulfide solid-state electrolyte having an LGPS-type crystal phase containing Li, Sn, P and S includes: amorphizing a raw material composition, to obtain an ion-conductive material; heating the ion-conductive material in an inert gas stream, to obtain a sulfide solid-state electrolyte intermediate; pulverizing the sulfide solid-state electrolyte intermediate into a fine particle form, to obtain intermediate fine particles; and heating the intermediate fine particles at a temperature of from 300° C. to 450° C. in an inert gas stream, to obtain a sulfide solid-state electrolyte.

公开(公告)号：US20230299334A1

公开(公告)日：2023-09-21

申请号：US18119542

申请日：2023-03-09

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: H01M10/0562 ,  H01M10/0525

CPC classification number: H01M10/0562 ,  H01M10/0525 ,  H01M2300/008

Abstract: A main object of the present disclosure is to provide a sulfide solid electrolyte including water resistance while maintaining an argyrodite type crystal structure. The present disclosure achieves the object by providing a sulfide solid electrolyte including an argyrodite type crystal phase, and containing Li, Ge, Sb, S, I, and A, the A is an anion with ionic radius larger than that of a sulfide ion.

公开(公告)号：US20200235422A1

公开(公告)日：2020-07-23

申请号：US16743061

申请日：2020-01-15

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: H01M10/0562 ,  H01M10/0525 ,  H01M4/58

Abstract: Provided are sulfide solid electrolyte particles which have sufficient ion conductivity and which are, when used in an all-solid-state battery, configured to suppress a resistance increase rate after charge-discharge cycles, and an all-solid-state battery comprising the sulfide solid electrolyte particles. The sulfide solid electrolyte particles may be sulfide solid electrolyte particles comprising a sulfide solid electrolyte that comprises Li, P, S and a halogen as constituent elements, wherein an oxygen/sulfur element ratio of a particle surface measured by XPS, is 0.79 or more and 1.25 or less, and an oxygen/sulfur element ratio at a depth of 30 nm (in terms of a SiO2 sputter rate) from the particle surface measured by XPS, is 0.58 or less.

公开(公告)号：US20160296920A1

公开(公告)日：2016-10-13

申请号：US15090994

申请日：2016-04-05

Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHA

Inventor： Keiichi MINAMI

IPC: B01J29/076 ,  B01J27/188 ,  B01J35/00 ,  B01J29/072

CPC classification number: B01J29/076 ,  B01D53/9418 ,  B01D2251/2062 ,  B01D2255/2065 ,  B01D2255/20707 ,  B01D2255/20761 ,  B01D2255/20776 ,  B01D2255/40 ,  B01D2255/90 ,  B01J23/002 ,  B01J27/02 ,  B01J27/188 ,  B01J29/072 ,  B01J35/008 ,  B01J35/023 ,  B01J2523/00 ,  B01J2523/3712 ,  B01J2523/47 ,  B01J2523/51 ,  B01J2523/69 ,  B01J2523/62

Abstract: The problem to be solved by the present invention is to provide a good NOx selective reduction catalyst. To solve the problem is a NOx selective reduction catalyst containing a composite oxide of Ti, Ce, W, and P or S.

Abstract translation: 本发明要解决的问题是提供一种良好的NOx选择还原催化剂。 为了解决这个问题，含有Ti，Ce，W和P或S的复合氧化物的NOx选择还原催化剂