公开(公告)号：US20230220159A1

公开(公告)日：2023-07-13

申请号：US17927327

申请日：2021-05-24

Applicant: Toray Industries, Inc

Inventor： Taisuke Hirano ,  Risano Nakajima ,  Masato Akahira ,  Soichiro Iwahana ,  Koji Yamauchi

IPC: C08G65/40

CPC classification number: C08G65/40 ,  C08G2250/00 ,  C08G2650/50

Abstract: A crystalline polyethernitrile with a difference between a melting point and a crystallization temperature at a time of temperature-fall being 40° C. or more and 100° C. or less, the crystalline polyethernitrile includes N repeating units represented by Formula (I) and M repeating units represented by Formula (II), N and M being integers satisfying 0.90

公开(公告)号：US20180362760A1

公开(公告)日：2018-12-20

申请号：US16008926

申请日：2018-06-14

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Atsuki Tsuchiya ,  Masato Honma ,  Kohei Yamashita ,  Shunsuke Horiuchi ,  Koji Yamauchi

IPC: C08L71/08 ,  B29B15/12 ,  B29C70/48 ,  B29C70/52 ,  B29C70/30 ,  B29C70/40 ,  C08J5/04

Abstract: Provided is a molding material which includes a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly(phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.

公开(公告)号：US09150695B2

公开(公告)日：2015-10-06

申请号：US14353204

申请日：2012-10-22

Applicant: TORAY INDUSTRIES, INC.

Inventor： Tomoyuki Odashima ,  Shunsuke Horiuchi ,  Naoto Kumagai ,  Koji Yamauchi

IPC: C08G75/00 ,  C08G75/14 ,  C07D341/00 ,  C08G75/02

CPC classification number: C08G75/14 ,  C07D341/00 ,  C08G75/02

Abstract: There is provided a production method of a cyclic polyarylene sulfide from a reaction mixture including at least a sulfidizing agent (a), a dihalogenated aromatic compound (b) and an organic polar solvent (c). The production method includes: a process 1 of heating the reaction mixture having an arylene unit of not less than 0.80 mol but less than 1.05 mol per 1 mol of the sulfur content in the reaction mixture; and subsequent to the process 1, a process 2 of further causing the reaction to proceed after addition of the dihalogenated aromatic compound (b) to have the arylene unit of not less than 1.05 mol and not greater than 1.50 mol per 1 mol of the sulfur content in the reaction mixture.

Abstract translation: 提供了由至少包含硫化剂（a），二卤化芳香族化合物（b）和有机极性溶剂（c）的反应混合物构成的环状聚芳硫醚的制造方法。 该制备方法包括：加热反应混合物的反应混合物的方法1，该反应混合物具有相对于反应混合物中每1摩尔硫含量为0.80摩尔但小于1.05摩尔的亚芳基单元; 在方法1之后，进一步使加入二卤代芳族化合物（b）后使反应进行的方法2具有相对于每1摩尔硫为1.05摩尔且不大于1.50摩尔的亚芳基单元 反应混合物中的含量。

公开(公告)号：US20160319082A1

公开(公告)日：2016-11-03

申请号：US15107705

申请日：2014-12-24

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kohei Yamashita ,  Takeshi Unohara ,  Kosaku Takeuchi ,  Daisuke Yamamoto ,  Koji Yamauchi

IPC: C08G81/00 ,  C08J9/26

CPC classification number: C08G81/00 ,  C08G75/0204 ,  C08G75/0259 ,  C08G75/0286 ,  C08J9/26 ,  C08J2201/046 ,  C08J2381/02 ,  C08J2381/04 ,  C08L81/04

Abstract: A heat-resistant, chemical-resistant polyphenylene sulfide block copolymer containing polyphenylene sulfide units and aromatic polyester units, wherein the polyphenylene sulfide units have a number average molecular weight in the range of 6,000 to 100,000. Provided is a polyphenylene sulfide block copolymer that overcomes the disadvantages of block copolymers including a low-molecular-weight polyphenylene sulfide segment and having poor heat resistance and chemical resistance.

Abstract translation: 含有聚苯硫醚单元和芳香族聚酯单元的耐热耐化学性聚苯硫醚嵌段共聚物，其中，所述聚苯硫醚单元的数均分子量为6000〜100000。 提供一种聚苯硫醚嵌段共聚物，其克服了包括低分子量聚苯硫醚嵌段和具有差的耐热性和耐化学性的嵌段共聚物的缺点。

公开(公告)号：US20150329677A1

公开(公告)日：2015-11-19

申请号：US14655170

申请日：2013-12-26

Applicant: TORAY INDUSTRIES, INC.

Inventor： Tomoyuki Odashima ,  Syunsuke Horiuchi ,  Junji Ishibashi ,  Naoto Kumagai ,  Koji Yamauchi

IPC: C08G75/14

CPC classification number: C08G75/14 ,  C08G75/02

Abstract: There is provided a production method of a cyclic polyarylene sulfide by heating and reacting a raw material mixture (a) including at least a sulfidizing agent, a dihalogenated aromatic compound and an organic polar solvent. The production method continually performs each of an operation (A) of supplying the raw material mixture (a) to a reaction mixture (b) in a reaction vessel which includes a reaction product obtained from the raw material mixture (a), an operation (B) of withdrawing part of the reaction mixture (b) from the reaction vessel, and an operation (C) of heating the reaction vessel.

Abstract translation: 通过加热和反应至少包含硫化剂，二卤代芳族化合物和有机极性溶剂的原料混合物（a）来提供环状聚芳硫醚的制造方法。 制造方法连续地进行在反应容器中向原料混合物（a）供给原料混合物（a）的反应混合物（a）的工序（A），反应容器含有从原料混合物（a）得到的反应物， B）将反应混合物（b）的一部分从反应容器中取出，以及加热反应容器的操作（C）。

公开(公告)号：US09771465B2

公开(公告)日：2017-09-26

申请号：US15107655

申请日：2014-12-19

Applicant: TORAY INDUSTRIES, INC.

Inventor： Keiko Ichinose ,  Hidenobu Takao ,  Daisuke Yamamoto ,  Koji Yamauchi

IPC: C08K5/09 ,  C08K5/098 ,  C08J5/18

CPC classification number: C08K5/098 ,  C08J5/18 ,  C08J2381/04 ,  C08L81/02

Abstract: A polyarylene sulfide resin composition including a polyarylene sulfide (A) and an alkaline earth metal organic carboxylate (B) in an amount of 0.001 to 10 mol % based on the formula —(Ar—S)—, a repeating unit of polyarylene sulfide, wherein the polyarylene sulfide (A) has a weight average molecular weight of 10,000 or more and a weight reduction during heating that satisfies the equation ΔWr=(W1−W2)/W1×100≦0.18 (%), wherein ΔWr is a weight reduction ratio (%) determined by a thermogravimetric analysis performed in a non-oxidizing atmosphere under normal pressure at a temperature rise rate of 20° C./min from 50° C. to any temperature equal to or higher than 330° C., wherein W1 is a sample weight at 100° C., and W2 is a sample weight at 330° C.

公开(公告)号：US09567437B2

公开(公告)日：2017-02-14

申请号：US14655170

申请日：2013-12-26

Applicant: TORAY INDUSTRIES, INC.

Inventor： Tomoyuki Odashima ,  Syunsuke Horiuchi ,  Junji Ishibashi ,  Naoto Kumagai ,  Koji Yamauchi

IPC: C08G75/14 ,  C08G75/02 ,  C07D341/00

CPC classification number: C08G75/14 ,  C08G75/02

Abstract: There is provided a production method of a cyclic polyarylene sulfide by heating and reacting a raw material mixture (a) including at least a sulfidizing agent, a dihalogenated aromatic compound and an organic polar solvent. The production method continually performs each of an operation (A) of supplying the raw material mixture (a) to a reaction mixture (b) in a reaction vessel which includes a reaction product obtained from the raw material mixture (a), an operation (B) of withdrawing part of the reaction mixture (b) from the reaction vessel, and an operation (C) of heating the reaction vessel.

Abstract translation: 通过加热和反应至少包含硫化剂，二卤代芳族化合物和有机极性溶剂的原料混合物（a）来提供环状聚芳硫醚的制造方法。 制造方法连续地进行在反应容器中向原料混合物（a）供给原料混合物（a）的反应混合物（a）的工序（A），反应容器含有从原料混合物（a）得到的反应物， B）将反应混合物（b）的一部分从反应容器中取出，以及加热反应容器的操作（C）。

公开(公告)号：US09029484B2

公开(公告)日：2015-05-12

申请号：US14381803

申请日：2013-02-27

Applicant: Toray Industries, Inc.

Inventor： Akinori Kanomata ,  Yosuke Nishimura ,  Shunsuke Horiuchi ,  Shu Kaiho ,  Kazusada Takeda ,  Koji Yamauchi ,  Junya Suzuki

IPC: C08F283/00 ,  C08G75/14 ,  C08G75/06 ,  C08J3/12 ,  B29B13/00

CPC classification number: C08G75/14 ,  B29B13/00 ,  C08G75/02 ,  C08G75/06 ,  C08J3/12 ,  C08J2381/04

Abstract: A production method includes a process (I) of heating a cyclic polyarylene sulfide composition under reduced pressure and a process (II) of heating and polymerizing a cyclic polyarylene sulfide composition. This simple method allows for production of a polyarylene sulfide of the higher molecular weight and can produce a polyarylene sulfide having a narrow molecular weight distribution, low gas generation and high industrial usability. Additionally, pelletization after the process (I) can produce a cyclic polyarylene sulfide pellet having ease of conveyance, excellent molding processability, less gas generation amount and high industrial usability.

Abstract translation: 制备方法包括在减压下加热环状聚芳硫醚组合物的方法（I）和加热和聚合环状聚芳硫醚组合物的方法（II）。 这种简单的方法允许生产较高分子量的聚芳硫醚，并且可以生产具有窄分子量分布，低气体产生和高工业可用性的聚芳硫醚。 另外，工序（I）之后的造粒可以制造出具有易于输送，优异的成型加工性，较少气体产生量和高工业可用性的环状聚芳硫醚丸粒。

公开(公告)号：US20150057429A1

公开(公告)日：2015-02-26

申请号：US14381803

申请日：2013-02-27

Applicant: Toray Industries, Inc.

Inventor： Akinori Kanomata ,  Yosuke Nishimura ,  Shunsuke Horiuchi ,  Shu Kaiho ,  Kazusada Takeda ,  Koji Yamauchi ,  Junya Suzuki

IPC: C08G75/14 ,  C08J3/12

CPC classification number: C08G75/14 ,  B29B13/00 ,  C08G75/02 ,  C08G75/06 ,  C08J3/12 ,  C08J2381/04

Abstract: A production method includes a process (I) of heating a cyclic polyarylene sulfide composition under reduced pressure and a process (II) of heating and polymerizing a cyclic polyarylene sulfide composition. This simple method allows for production of a polyarylene sulfide of the higher molecular weight and can produce a polyarylene sulfide having a narrow molecular weight distribution, low gas generation and high industrial usability. Additionally, pelletization after the process (I) can produce a cyclic polyarylene sulfide pellet having ease of conveyance, excellent molding processability, less gas generation amount and high industrial usability.

Abstract translation: 制备方法包括在减压下加热环状聚芳硫醚组合物的方法（I）和加热和聚合环状聚芳硫醚组合物的方法（II）。 这种简单的方法允许生产较高分子量的聚芳硫醚，并且可以生产具有窄分子量分布，低气体产生和高工业可用性的聚芳硫醚。 另外，工序（I）之后的造粒可以制造出具有易于输送，优异的成型加工性，较少气体产生量和高工业可用性的环状聚芳硫醚丸粒。

公开(公告)号：US20140256907A1

公开(公告)日：2014-09-11

申请号：US14353204

申请日：2012-10-22

Applicant: TORAY INDUSTRIES, INC.

Inventor： Tomoyuki Odashima ,  Shunsuke Horiuchi ,  Naoto Kumagai ,  Koji Yamauchi

IPC: C08G75/14

CPC classification number: C08G75/14 ,  C07D341/00 ,  C08G75/02

Abstract: There is provided a production method of a cyclic polyarylene sulfide from a reaction mixture including at least a sulfidizing agent (a), a dihalogenated aromatic compound (b) and an organic polar solvent (c). The production method includes: a process 1 of heating the reaction mixture having an arylene unit of not less than 0.80 mol but less than 1.05 mol per 1 mol of the sulfur content in the reaction mixture; and subsequent to the process 1, a process 2 of further causing the reaction to proceed after addition of the dihalogenated aromatic compound (b) to have the arylene unit of not less than 1.05 mol and not greater than 1.50 mol per 1 mol of the sulfur content in the reaction mixture.

Abstract translation: 提供了由至少包含硫化剂（a），二卤化芳香族化合物（b）和有机极性溶剂（c）的反应混合物构成的环状聚芳硫醚的制造方法。 该制备方法包括：加热反应混合物的反应混合物的方法1，该反应混合物具有相对于反应混合物中每1摩尔硫含量为0.80摩尔但小于1.05摩尔的亚芳基单元; 在方法1之后，进一步使加入二卤代芳族化合物（b）后使反应进行的方法2具有相对于每1摩尔硫为1.05摩尔且不大于1.50摩尔的亚芳基单元 反应混合物中的含量。