公开(公告)号：US11529769B2

公开(公告)日：2022-12-20

申请号：US16619129

申请日：2018-07-30

Applicant: Toray Industries, Inc.

Inventor： Shin Hirata ,  Yuki Nitsutsuji ,  Atsuki Tsuchiya

IPC: B29C70/08 ,  C08J5/04 ,  B29K101/12 ,  B29K105/00 ,  B29K301/12 ,  B29K307/04

Abstract: A fiber reinforced thermoplastic resin molded article contains inorganic fibers (A), organic fibers (B), and a thermoplastic resin (C), the fiber reinforced thermoplastic resin molded article containing 5 to 45 parts by weight of the inorganic fibers (A), 1 to 45 parts by weight of the organic fibers (B), and 10 to 94 parts by weight of the thermoplastic resin (C), based on 100 parts by weight of the total of the inorganic fibers (A), the organic fibers (B), and the thermoplastic resin (C), the inorganic fibers (A) in the fiber reinforced thermoplastic resin molded article having a weight average fiber length (Lwa) of 0.01 mm or more and 3 mm or less, the organic fibers (B) having a weight average fiber length (Lwb) of more than 4 mm and 20 mm or less.

公开(公告)号：US10583591B2

公开(公告)日：2020-03-10

申请号：US15519383

申请日：2015-10-20

Applicant: Toray Industries, Inc.

Inventor： Yuki Mitsutsuji ,  Sora Bang ,  Shin Hirata ,  Atsuki Tsuchiya

IPC: B29C45/00 ,  C08J5/04 ,  C08K3/04 ,  C08K7/06 ,  C08L101/00 ,  C08L45/00 ,  C08L63/00 ,  C08L61/04 ,  C08L81/04 ,  C08J5/06 ,  C08L69/00 ,  C08J5/10 ,  C01B32/05 ,  B29C70/16 ,  C08K3/22 ,  B29K307/04

Abstract: A fiber reinforced thermoplastic resin molded article includes (A) carbon fibers, (B) graphite and (C) a thermoplastic resin, wherein the carbon fibers (A), the graphite (B) and the thermoplastic resin (C) are contained in amounts of 1 to 30 parts by weight, 1 to 40 parts by weight and 30 to 98 parts by weight, respectively, relative to 100 parts by weight, of the carbon fibers (A), the graphite (B) and the thermoplastic resin (C), the weight average fiber length of the carbon fibers (A) is 0.3 to 3 mm and the specific gravity of the molded article is 1.1 to 1.9 g/cm3. The fiber reinforced thermoplastic resin molded article has excellent bending strength and heat conductivity.

公开(公告)号：US09879123B2

公开(公告)日：2018-01-30

申请号：US14372078

申请日：2013-01-17

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kentaro Sano ,  Noriyuki Hirano ,  Masato Honma ,  Atsuki Tsuchiya

IPC: C08J5/04 ,  D06M15/55 ,  C08J5/24 ,  C08L23/08 ,  C08L23/10 ,  C08J5/06 ,  D06M101/40 ,  C08L23/26

CPC classification number: C08J5/042 ,  C08J5/043 ,  C08J5/06 ,  C08J5/24 ,  C08J2323/12 ,  C08J2423/00 ,  C08J2423/14 ,  C08J2423/36 ,  C08K7/06 ,  C08K9/04 ,  C08L23/0846 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  D06M15/55 ,  D06M2101/40 ,  D10B2101/06 ,  Y10T428/249944 ,  Y10T428/249948 ,  Y10T428/2929

Abstract: A molded article excellent in dynamic characteristics and water degradation resistance can be obtained by using a fiber-reinforced polypropylene resin composition including a carbodiimide-modified polyolefin (a), a polypropylene resin (b) and reinforcing fibers (c), wherein the content of the carbodiimide group contained in a resin component in the fiber-reinforced polypropylene resin composition is 0.0005 to 140 mmol based on 100 g of a matrix resin component, and the reinforcing fibers (c) are sizing-treated with a polyfunctional compound (s); and a molding material using the fiber-reinforced polypropylene resin composition.

公开(公告)号：US20230067964A1

公开(公告)日：2023-03-02

申请号：US17796730

申请日：2020-02-21

Applicant: Toray Industries, Inc.

Inventor： Chiasa Kitani ,  Satoshi Matsumoto ,  Shigeru Kawashima ,  Atsuki Tsuchiya

IPC: B29C70/48 ,  B29C33/64

Abstract: Provided are a fiber-reinforced composite molded article prepared by heat-curing, as a molding material of a fiber-reinforced resin material, a resin composition to which an internal mold release agent is added, the fiber-reinforced composite molded article being capable of effectively producing mold releasability even with a small amount of the mold release agent added, and being capable of achieving high productivity, and a method of forming the fiber-reinforced composite molded article. A fiber-reinforced composite molded article prepared by curing reinforcing fibers and a resin composition, the resin composition including an internal mold release agent, wherein the value obtained by normalizing a Poisson-corrected ion intensity derived from the internal mold release agent detected on the surface of the fiber-reinforced composite molded article, by the Poisson-corrected gross positive secondary ion intensity detected in the predetermined area is higher than 0.1, and a molding method therefor.

公开(公告)号：US20180312648A1

公开(公告)日：2018-11-01

申请号：US15770132

申请日：2016-10-21

Applicant: Toray Industries, Inc.

Inventor： Yuki Mitsutsuji ,  Shin Hirata ,  Atsuki Tsuchiya

IPC: C08J5/04 ,  C08K7/06 ,  C08K7/02 ,  B29B9/06

Abstract: A fiber reinforced thermoplastic resin molded article includes 5 to 45 parts by weight of carbon fibers (A), 1 to 45 parts by weight of organic fibers (B), and 10 to 94 parts by weight of a thermoplastic resin (C), based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C). The carbon fibers (A) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LA) of 0.3 to 3 mm. The organic fibers (B) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LB) of 0.5 to 5 mm, and a number average fiber diameter (dB) of 35 to 300 μm. The fiber reinforced thermoplastic resin molded article is excellent in impact strength and surface appearance.

公开(公告)号：US10093802B2

公开(公告)日：2018-10-09

申请号：US15032214

申请日：2014-10-24

Applicant: Toray Industries, Inc.

Inventor： Kentaro Sano ,  Keisuke Inose ,  Naokichi Imai ,  Atsuki Tsuchiya

IPC: C08L81/04 ,  C08K5/29 ,  C08K9/04 ,  C08J3/22 ,  C08L101/00 ,  C08J5/06 ,  C08L69/00

Abstract: A molding material includes 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50° C., and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C).

公开(公告)号：US20160272814A1

公开(公告)日：2016-09-22

申请号：US15032214

申请日：2014-10-24

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kentaro Sano ,  Keisuke Inose ,  Naokichi Imai ,  Atsuki Tsuchiya

IPC: C08L81/04 ,  C08L69/00 ,  C08J3/22

CPC classification number: C08L81/04 ,  C08J3/22 ,  C08J5/06 ,  C08L69/00 ,  C08L79/08

Abstract: A molding material includes 5 to 50 parts by mass of reinforcing fibers (A) with a sizing agent (s) deposited thereon, 1 to 20 parts by mass of a component (B) containing a polycarbodiimide compound (B-1) that is liquid at 50° C., and 30 to 94 parts by mass of a thermoplastic resin (C) containing an element other than carbon in the repeating unit structure of the main chain, based on 100 parts by mass of the total of the components (A) to (C), wherein the molding material is a composite in which a composite fiber bundle (D) with the component (A) impregnated with the component (B) is covered with the component (C).

Abstract translation: 成型材料包括5〜50质量份的具有上浆剂的增强纤维（A），1〜20质量份含有作为液体的聚碳二亚胺化合物（B-1）的成分（B） 相对于主链的重复单元结构中含有除碳以外的元素的热塑性树脂（C），相对于100质量份的组分（A ）至（C），其中，所述成型材料为复合纤维束（D）与组分（B）浸渍的组分（A）被组分（C）覆盖的组合物。

公开(公告)号：US20140356612A1

公开(公告)日：2014-12-04

申请号：US14372078

申请日：2013-01-17

Applicant: TORAY INDUSTRIES, INC.

Inventor： Kentaro Sano ,  Noriyuki Hirano ,  Masato Honma ,  Atsuki Tsuchiya

IPC: C08J5/04

CPC classification number: C08J5/042 ,  C08J5/043 ,  C08J5/06 ,  C08J5/24 ,  C08J2323/12 ,  C08J2423/00 ,  C08J2423/14 ,  C08J2423/36 ,  C08K7/06 ,  C08K9/04 ,  C08L23/0846 ,  C08L23/10 ,  C08L23/26 ,  C08L51/06 ,  D06M15/55 ,  D06M2101/40 ,  D10B2101/06 ,  Y10T428/249944 ,  Y10T428/249948 ,  Y10T428/2929

Abstract: A molded article excellent in dynamic characteristics and water degradation resistance can be obtained by using a fiber-reinforced polypropylene resin composition including a carbodiimide-modified polyolefin (a), a polypropylene resin (b) and reinforcing fibers (c), wherein the content of the carbodiimide group contained in a resin component in the fiber-reinforced polypropylene resin composition is 0.0005 to 140 mmol based on 100 g of a matrix resin component, and the reinforcing fibers (c) are sizing-treated with a polyfunctional compound (s); and a molding material using the fiber-reinforced polypropylene resin composition.

Abstract translation: 通过使用包含碳二亚胺改性聚烯烃（a），聚丙烯树脂（b）和增强纤维（c））的纤维增强聚丙烯树脂组合物，可以获得动态特性和耐水分劣化性优异的成型体，其中， 纤维增强聚丙烯树脂组合物中的树脂成分中所含的碳二亚胺基团，相对于100g基体树脂成分为0.0005〜140mmol，增强纤维（c）用多官能化合物进行施胶处理。 以及使用纤维增强聚丙烯树脂组合物的成型材料。

公开(公告)号：US10584218B2

公开(公告)日：2020-03-10

申请号：US15770132

申请日：2016-10-21

Applicant: Toray Industries, Inc.

Inventor： Yuki Mitsutsuji ,  Shin Hirata ,  Atsuki Tsuchiya

IPC: B29B9/06 ,  C08J5/04 ,  C08K7/06 ,  C08L101/00 ,  C08J5/06 ,  C08L23/12 ,  C08K7/02 ,  B29B15/14 ,  B29K101/12 ,  B29K307/04

Abstract: A fiber reinforced thermoplastic resin molded article includes 5 to 45 parts by weight of carbon fibers (A), 1 to 45 parts by weight of organic fibers (B), and 10 to 94 parts by weight of a thermoplastic resin (C), based on 100 parts by weight of the total amount of the carbon fibers (A), the organic fibers (B), and the thermoplastic resin (C). The carbon fibers (A) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LA) of 0.3 to 3 mm. The organic fibers (B) in the fiber reinforced thermoplastic resin molded article have an average fiber length (LB) of 0.5 to 5 mm, and a number average fiber diameter (dB) of 35 to 300 μm. The fiber reinforced thermoplastic resin molded article is excellent in impact strength and surface appearance.

公开(公告)号：US20180362760A1

公开(公告)日：2018-12-20

申请号：US16008926

申请日：2018-06-14

Applicant: Toray Industries, Inc.

Inventor： Naokichi Imai ,  Atsuki Tsuchiya ,  Masato Honma ,  Kohei Yamashita ,  Shunsuke Horiuchi ,  Koji Yamauchi

IPC: C08L71/08 ,  B29B15/12 ,  B29C70/48 ,  B29C70/52 ,  B29C70/30 ,  B29C70/40 ,  C08J5/04

Abstract: Provided is a molding material which includes a composite of 1 to 50 wt % of a continuous reinforcing fiber bundle (A) and 0.1 to 20 wt % of a poly(phenylene ether ether ketone) oligomer (B); and 30 to 98.9 wt % of a thermoplastic resin (C) adhering to the composite, wherein the component (B) has a melting point of not higher than 270° C. Also provided are a method for molding the molding material, a method for producing the molding material, and a method for producing a fiber-reinforced composite material. A molded article having high heat resistance and dynamic properties can be easily produced without impairing the economic efficiency and productivity during the process for producing a molding material. In addition, a fiber-reinforced composite material can be produced with more ease and high productivity.