公开(公告)号：US20150315331A1

公开(公告)日：2015-11-05

申请号：US14650027

申请日：2013-10-31

Applicant: TORAY INDUSTRIES, INC.

Inventor： Jun MISUMI ,  Nobuyuki ARAI ,  Hiroshi TAIKO ,  Shizue UENO

IPC: C08G59/28 ,  C08G59/24 ,  C08J5/04 ,  C08G59/38 ,  C08L63/00 ,  C08J5/24 ,  C08G59/22 ,  C08G59/50

CPC classification number: C08G59/28 ,  C08G59/10 ,  C08G59/226 ,  C08G59/245 ,  C08G59/38 ,  C08G59/5033 ,  C08G59/504 ,  C08G59/54 ,  C08J5/042 ,  C08J5/24 ,  C08J2363/00 ,  C08J2363/02 ,  C08L63/00

Abstract: Provided are: an epoxy resin composition which enables the production of a carbon-fiber-reinforced composite material having excellent tensile strength and compressive strength and suitable as a material for structures; a prepreg; and a carbon-fiber-reinforced composite material. An epoxy resin composition characterized by comprising at least [A] an epoxy resin having a structure represented by formula (1), [B] an epoxy resin having at least one amine-type glycidyl group or at least one ether-type glycidyl group and having a liquid form at 40° C. and [C] a curing agent; and a prepreg and a carbon-fiber-reinforced composite material, each produced using the epoxy resin composition. (In the formula, R1 to R4 independently represent at least one atom or group selected from the group consisting of a hydrogen atom, an aliphatic hydrocarbon group having 1 to 4 carbon atoms, an alicyclic hydrocarbon group having 4 or less carbon atoms, and a halogen atom.)

Abstract translation: 提供：能够生产具有优异的拉伸强度和抗压强度并适合作为结构材料的碳纤维增强复合材料的环氧树脂组合物; 预浸料 和碳纤维增强复合材料。 一种环氧树脂组合物，其特征在于至少包含[A]具有式（1）所示结构的环氧树脂，[B]具有至少一个胺型缩水甘油基或至少一种醚型缩水甘油基的环氧树脂和 在40℃具有液体形式，和[C]固化剂; 和预浸料坯和碳纤维增强复合材料，各自使用环氧树脂组合物制造。 （式中，R 1〜R 4分别独立地表示选自氢原子，碳原子数1〜4的脂肪族烃基，碳原子数4以下的脂环式烃基，碳原子数4以下的脂肪族烃基， 卤素原子）

公开(公告)号：US20160152785A1

公开(公告)日：2016-06-02

申请号：US14896865

申请日：2014-07-10

Applicant: TORAY INDUSTRIES, INC.

Inventor： Shizue UENO ,  Nobuyuki ARAI ,  Jun MISUMI ,  Hiroshi TAIKO

IPC: C08J5/24 ,  C08L63/00 ,  C08G59/38 ,  C08G59/44

CPC classification number: C08J5/24 ,  B32B27/26 ,  B32B27/38 ,  C08G59/3227 ,  C08G59/38 ,  C08G59/4223 ,  C08G59/44 ,  C08G59/5033 ,  C08G59/504 ,  C08J2363/00 ,  C08J2363/02 ,  C08K3/04 ,  C08K7/06 ,  C08L63/00

Abstract: An epoxy resin composition including [A1] a hardener represented by Formula (1), and [B] an aromatic epoxy resin having tri- or higher functionality, wherein a carbon nuclear relaxation time T1C corresponding to a benzene ring carbon atom in the main backbone of Formula (1) assigned to 130 ppm in a solid-state 13C-NMR spectrum is 42 seconds or longer, and a prepreg and a carbon fiber-reinforced composite material obtained using the epoxy resin composition: wherein X represents any one selected from —CH2—, —O—, —CO—, —C(═O)O—, —S—, —SO2—, and —NHC(═O)—; n represents 1 to 5; and R1 to R6 each represent at least one selected from the group consisting of a hydrogen atom, an aliphatic hydrocarbon group having 1 to 4 carbon atoms, an alicyclic hydrocarbon group having 4 or less carbon atoms, and an a halogen atom, wherein when X is —C(═O)O— or —NHC(═O)—, X may be in either direction. Provided are an epoxy resin composition that provides a carbon fiber-reinforced composite material excellent in tensile strength and compression strength and suitable as a structural material, a prepreg, and a carbon fiber-reinforced composite material.

Abstract translation: 一种环氧树脂组合物，其包含[A1]式（1）表示的固化剂，[B]具有三官能度以上的芳香族环氧树脂，其中，与主骨架中的苯环碳原子对应的碳核弛豫时间T1C 在固态13 C-NMR光谱中分配至130ppm的式（1）为42秒以上，使用环氧树脂组合物得到的预浸料坯和碳纤维增强复合材料：其中，X表示选自 CH 2 - ， - O - ， - CO - ， - C（= O）O-，-S-，-SO 2 - 和-NHC（= O） - ; n表示1〜5; R1〜R6各自表示选自氢原子，碳原子数1〜4的脂肪族烃基，碳原子数4以下的脂环族烃基和卤素原子中的至少一种，其中，当X 是-C（= O）O-或-NHC（= O） - ），X可以在任一方向上。 提供一种环氧树脂组合物，其提供抗拉强度和抗压强度优异的碳纤维增强复合材料，并且适合作为结构材料，预浸料和碳纤维增强复合材料。