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公开(公告)号：US4581329A
公开(公告)日：1986-04-08
申请号：US588410
申请日：1984-03-12
申请人： Tadao Sugimoto , Sumito Yamada , Hideo Ikeda , Masaki Okazaki , Tadashi Ikeda
发明人： Tadao Sugimoto , Sumito Yamada , Hideo Ikeda , Masaki Okazaki , Tadashi Ikeda
CPC分类号： G03C1/005 , G03C1/0051 , G03C1/12 , G03C1/32 , G03C1/34 , G03C2001/03594 , G03C2001/091 , G03C2001/095 , G03C2001/7635 , G03C2005/168 , G03C2007/3025 , G03C2200/28 , G03C5/17
摘要： A silver halide photographic light-sensitive material which comprises a support, a hydrophilic colloid layer or layers and a silver halide emulsion layer or layers, wherein at least one of said silver halide emulsion layers contains tabular silver halide grains having a diameter:thickness ratio of 5:1 or more and at least one compound represented by the following general formula (I) or general formula (II): ##STR1## wherein Z.sub.1 represents the non-metal atoms necessary to complete a 5- or 6-membered heterocyclic ring; R.sub.1 represents an unsubstituted or substituted alkyl group; R.sub.2 represents an unsubstituted or substituted aryl group with up to 2 aromatic fused rings, or an unsubstituted or substituted aralkyl group; R.sub.3 represents a hydrogen atom or with R.sub.1 an alkylene group forming a ring; R.sub.4 represents a hydrogen atom, an unsubstituted or substituted lower alkyl group, an unsubstituted or substituted aryl group, or an unsubstituted or substituted aralkyl group; n represents 0 or 1, with n being 0 when an inner salt is formed; and X represents an acid anion.
摘要翻译： 一种卤化银照相感光材料，其包含载体，亲水胶体层或卤化银乳剂层，其中所述卤化银乳剂层中的至少一种包含具有直径：厚度比的板状卤化银颗粒 （I）或通式（II）表示的至少一种化合物：其中Z1表示完成一个或多个所需的非金属原子 5-或6-元杂环; R1表示未取代或取代的烷基; R2代表未取代或取代的芳基，最多含2个芳香稠环，或未取代或取代的芳烷基; R3表示氢原子或R1表示亚烷基形成环; R4表示氢原子，未取代或取代的低级烷基，未取代或取代的芳基，或未取代或取代的芳烷基; n表示0或1，当形成内盐时，n为0; X表示酸性阴离子。
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公开(公告)号：US4609621A
公开(公告)日：1986-09-02
申请号：US714415
申请日：1985-03-20
申请人： Tadao Sugimoto , Sumito Yamada , Tadashi Ikeda , Haruo Takei , Masaki Okazaki
发明人： Tadao Sugimoto , Sumito Yamada , Tadashi Ikeda , Haruo Takei , Masaki Okazaki
IPC分类号： G03C1/035 , G03C1/06 , G03C1/12 , G03C1/14 , G03C1/28 , G03C1/34 , E03C1/02 , E03C1/12 , E03C1/16
CPC分类号： G03C1/346 , G03C1/12 , G03C1/14 , G03C1/28 , Y10S430/167
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having provided thereon a hydrophilic colloid layer and a silver halide emulsion layer. The silver halide emulsion layer contains tubular silver halide grains having a diameter at least 3 times their thickness and also contains a compound represented by general formula (I) or (II): ##STR1## the substituents are defined within the specification. The material obtains the advantages of utilizing tabular silver halide grains while having a reduced dependents of its photographic properties on development processing conditions which normally effect materials containing tabular silver halide grains.
摘要翻译： 公开了一种卤化银照相感光材料。 该材料由其上设置有亲水胶体层和卤化银乳剂层的支撑基底组成。 卤化银乳剂层含有直径至少为其厚度3倍的管状卤化银颗粒，并且还含有由通式（I）或（II）表示的化合物：（I） 在规范内定义。 该材料获得了利用片状卤化银颗粒的优点，同时对其通常影响含有片状卤化银颗粒的材料的显影处理条件的照相性能降低。
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公开(公告)号：US4665012A
公开(公告)日：1987-05-12
申请号：US774864
申请日：1985-09-11
申请人： Tadao Sugimoto , Sumito Yamada
发明人： Tadao Sugimoto , Sumito Yamada
CPC分类号： G03C1/0051 , G03C2001/03523 , G03C2001/03535 , G03C2200/49
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support having thereon a silver halide emulsion layer containing light-sensitive silver halide grains, at least 10% (in number) of said halide grains being tabular grains having a diameter/thickness ratio of not less than 5. The tabular grains include an iodine-containing silver halide solid solution in an interior portion thereof which is contained in areas covering, with regard to its major or minor axis direction, 80% by mole of the silver contained in the grain. Further, the tabular grains have an average iodine content in the internal high iodine phase which is five times that of the silver bromide, iodobromide or chloroiodobromide contained in the phase present outside of the internal high iodide phase. In addition, the silver contained in the internal high iodine phase is not more than 50% by mole of the total amount of silver in the tabular grains. The photographic material has the advantages inherent to the use of tabular grains and has improved pressure resistant characteristics.
摘要翻译： 公开了一种卤化银照相感光材料。 该材料包括其上具有含有感光卤化银颗粒的卤化银乳剂层的载体，至少10％（数量）所述卤化物颗粒是直径/厚度比不小于5的片状颗粒。 片状颗粒包括其内部的含碘卤化银固体溶液，其包含在相对于其主轴或短轴方向覆盖颗粒中所含银的80摩尔％的区域中。 此外，片状颗粒的内部高碘相中的平均碘含量是存在于内部高碘化物相外部的相中所含的溴化银，碘溴化物或氯碘溴化物的平均碘含量。 此外，内部高碘相中所含的银不超过片状颗粒中银的总量的50摩尔％。 照相材料具有使用片状颗粒所固有的优点并且具有改善的耐压特性。
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公开(公告)号：US4585729A
公开(公告)日：1986-04-29
申请号：US696861
申请日：1985-01-30
申请人： Tadao Sugimoto , Sumito Yamada
发明人： Tadao Sugimoto , Sumito Yamada
CPC分类号： G03C5/16 , G03C1/46 , Y10S430/167
摘要： A silver halide photographic light-sensitve material is disclosed. The material is comprised of a transparent support having provided on one side of the support at least two silver halide emulsion layers and a surface-protecting layer. One of the two silver halide emulsion layers is a tabular silver halide emulsion layer containing tabular silver halide grains having a diameter at least five times the thickness of the grains. The other silver halide emulsion layer is a non-tabular silver halide emulsion layer containing non-tabular silver halide grains. The tabular silver halide emulsion layer is positioned closer to the support than the non-tabular silver halide emulsion layer, and the non-tabular silver halide emuslion layer is positioned closer to the support than the surface-protecting layer. The material may include two similar silver halide emulsion layers and a surface-protecting layer on the opposite side of the support. The material provides images with improved sharpness without a decrease in sensitivity while effectively utilizing the amount of silver.
摘要翻译： 公开了一种卤化银摄影光敏材料。 该材料由在载体的一侧上提供至少两个卤化银乳剂层和表面保护层的透明载体组成。 两个卤化银乳剂层之一是片状卤化银乳剂层，其含有直径至少为颗粒厚度的五倍的片状卤化银颗粒。 另一卤化银乳剂层是含有非平板状卤化银颗粒的非平板状卤化银乳剂层。 片状卤化银乳剂层位于比非片状卤化银乳剂层更靠近载体的位置，并且非平板状卤化银发泡层位于比表面保护层更靠近载体的位置。 该材料可以包括两个类似的卤化银乳剂层和在载体的相对侧上的表面保护层。 该材料提供具有改善的清晰度的图像，而不降低灵敏度，同时有效地利用银的量。
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公开(公告)号：US5008181A
公开(公告)日：1991-04-16
申请号：US248747
申请日：1988-09-26
申请人： Akihiko Ikegawa , Masaki Okazaki , Tadao Sugimoto
发明人： Akihiko Ikegawa , Masaki Okazaki , Tadao Sugimoto
CPC分类号： G03C1/28 , Y10S430/156 , Y10S430/159
摘要： A silver halide photographic material comprising a support having thereon at least one silver halide emulsion layer spectrally sensitized by at least one adsorptive spectral sensitizing dye, wherein the emulsion layer or a hydrophilic colloid layer adjacent to the emulsion layer contains at least one compound represented by following formula (I), (II), or (III); ##STR1##A.sub.2 --Time.sub.1).sub..sbsb.t.sbsb.1 X (II)A.sub.3 --Time.sub.2).sub.t.sbsb.2 Y (III)(all the symbols of which are defined in the specification) are disclosed.
摘要翻译： 一种卤化银照相材料，包括其上具有至少一种由至少一种吸附光谱增感染料光谱增感的卤化银乳剂层的载体，其中所述乳剂层或邻近所述乳剂层的亲水胶体层含有至少一种以下化合物 式（I），（II）或（III）; （I）A2-Time1）t1X（II）A3-Time2）t2Y（III）（其全部符号在说明书中定义）。
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公开(公告)号：US4820606A
公开(公告)日：1989-04-11
申请号：US127137
申请日：1987-12-01
申请人： Tsutomu Miyasaka , Masaki Okazaki , Tadao Sugimoto
发明人： Tsutomu Miyasaka , Masaki Okazaki , Tadao Sugimoto
CPC分类号： G03C1/29
摘要： A silver halide photographic material having at least one silver halide emulsion layer having been spectrally sensitized with adsorbable spectral sensitizing dye is disclosed, wherein a hydrophilic dispersion medium contains a substantially non-adsorbable luminescent dye which is easily removable by development processing the satisfies the following conditions (1) to (3):(1) The luminescent dye has an equilibrium adsorption of not more than 5.times.10.sup.-7 mol per m.sup.2 of silver bromide grain surface in a 5% by weight gelatin aqueous solution containing silver bromide grains whose outer surface is composed substantially of a [111] face under conditions of 40.degree. C. in temperature, 6.5.+-.0.05 in pH, and 10.sup.-4 mol/l in dye concentration in the solution phase;(2) The luminescent dye has an emission quantium yield of not less than 0.1 at room temperature in dry gelatin at a concentration of 10.sup.-4 mol/dm.sup.3 ; and(3) The luminescent dye has an emission band at least a part of which overlaps an optical absorption band of the absorbable spectral sensitizing dye on silver halide grains. Use of the non-adsorbable luminescent dye markedly improves spectral sensitivity of the silver halide photographic material without causing desensitization.
摘要翻译： 公开了具有至少一种卤化银乳剂层的卤化银照相材料，其具有可吸附光谱增感染料的光谱增感作用，其中亲水性分散介质含有通过显影处理容易除去的基本上不可吸附的发光染料，满足以下条件 （1）〜（3）：（1）发光染料在5重量％的含有溴化银颗粒的明胶水溶液中的平均吸附量为5×10 -7 mol / m 2以下的溴化银颗粒表面， 在温度为40℃，pH为6.5 +/- 0.05，溶液相中的染料浓度为10 -4 mol / l的条件下，基本上由[111]面组成。 （2）发光染料在室温下的干燥明胶浓度为10 -4 mol / dm 3时的发射定量产率不低于0.1; 和（3）发光染料的至少一部分发射带与可吸收光谱增感染料在卤化银颗粒上的光吸收带重叠。 使用不可吸附的发光染料显着提高了卤化银照相材料的光谱灵敏度，而不会导致脱敏。
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7.发明授权
公开(公告)号：US4876183A
公开(公告)日：1989-10-24
申请号：US127139
申请日：1987-12-01
申请人： Tsutomu Miyasaka , Masaki Okazaki , Tadao Sugimoto
发明人： Tsutomu Miyasaka , Masaki Okazaki , Tadao Sugimoto
CPC分类号： G03C1/0051 , G03C1/12
摘要： A silver halide photosensitive material comprising a support having thereon at least one silver halide emulsion layer comprising tabular grains whose diameter of an average projected area/average thickness ratio is 5/1 or higher is provided. Said emulsion layer contains one or more luminescent dyes whose luminescence quantum yield is 0.3 or more when its concentration is dry gelatin is 10.sup.-4 mol/dm.sup.3 at room temperature and that can be substantially removed by development processing, and the content of said luminescent dye is 3.0 .mu.mol/m.sup.2 or more for the total surface area of the silver halide grains in said emulsion layer, or is 2.0 mmol/dm.sup.3 or more in a hydrophilic dispersion medium excluding the silver halide grain surfaces in said emulsion layer.
摘要翻译： 一种卤化银感光材料，其包括其上具有至少一个包含平均投影面积/平均厚度比为5/1或更高的直径的片状颗粒的卤化银乳剂层的载体。 所述乳剂层含有一种或多种发光量子产率在室温下为10 -4 mol / dm 3的干凝胶时其发光量子产率为0.3以上且可通过显影处理基本上除去的发光染料，并且所述发光染料的含量 对于所述乳剂层中的卤化银颗粒的总表面积为3.0μmol/ m 2以上，或者在除了所述乳剂层中的卤化银颗粒表面之外的亲水性分散介质中为2.0mmol / dm 3以上。
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公开(公告)号：US4604339A
公开(公告)日：1986-08-05
申请号：US556667
申请日：1983-11-30
申请人： Tadao Sugimoto , Hideo Ikeda , Hiroyuki Mifune , Koki Nakamura
发明人： Tadao Sugimoto , Hideo Ikeda , Hiroyuki Mifune , Koki Nakamura
IPC分类号： G03C5/29 , C07D473/38 , C07D487/04 , G03C1/34 , G03C5/30 , G03C5/54 , G03C5/24
CPC分类号： C07D487/04 , C07D473/38 , G03C1/346 , G03C5/30
摘要： A method of developing silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally-fogged silver halide emulsion, in which the internally-fogged emulsion has internal fogging nuclei at a depth of 0.02.mu. or more below the surface of the grains is disclosed. The photographic material is developed in the presence of at least one compound selected from the group consisting of tetraazaindenes containing at least one mercapto group, purines containing at least one mercapto group, triazaindenes containing at least one mercapto group and pentaazaindenes containing at least one mercapto group, to increase photographic speed, contrast and maximum density as well as remove uneven stain.
摘要翻译： 一种显影卤化银照相材料的方法，其含有感光卤化银乳剂和内部雾化的卤化银乳剂，其中内部雾化的乳液在内表面上的0.02μm或更多的深度处具有内部雾化核 披露了谷物。 照相材料在至少一种选自含有至少一个巯基的四氮杂茚基，含有至少一个巯基的嘌呤，含有至少一个巯基的三嗪类和含有至少一个巯基的五唑烷酮的化合物存在下显影 ，以提高摄影速度，对比度和最大密度，以及去除不均匀的污渍。
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公开(公告)号：US4551419A
公开(公告)日：1985-11-05
申请号：US579048
申请日：1984-02-10
申请人： Tadao Sugimoto , Hideo Ikeda , Koki Nakamura
发明人： Tadao Sugimoto , Hideo Ikeda , Koki Nakamura
IPC分类号： G03C5/26 , C07C323/25 , C07D277/36 , C07D487/04 , G03C1/005 , G03C1/09 , G03C1/34
CPC分类号： C07D487/04 , C07C323/25 , C07D277/36 , G03C1/005 , G03C1/09 , G03C1/346
摘要： A silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally fogged silver halide emulsion is development-processed in the presence of at least one compound selected from the group consisting of compounds represented by the general formulae (I) and (II) and at least one azaindene having a mercapto group to exhibit high photographic speed, high contrast and high maximum image density:R.sub.1 --(R.sub.3).sub.l X}.sub.n R.sub.3 '--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an aryl group, an aryl group, or a heterocyclic group; R.sub.3 and R.sub.3 ' each represents an alkylene group, an arylene group, a heterocyclic group; X presents ##STR1## R.sub.4 represents a hydrogen atom or --R.sub.5 --Y}.sub.m R.sub.5 '--R.sub.6 ; R.sub.5 and R.sub.5 ' have the same meanings as R.sub.3 and R.sub.3 '; R.sub.6 has the same meaning as R.sub.1 and R.sub.2 ; Y represents ##STR2## R.sub.7 has the same meaning as R.sub.1 and R.sub.2 ; l represents 0 or 1, n represents an integer of 1 to 110, and m represents an integer of 0 to 10, and at least one X therein must be a sulfur atom: ##STR3## wherein Q represents atoms necessary to form a heterocyclic ring, and A represents an alkyl group, or an aryl group.
摘要翻译： 含有感光卤化银乳剂和内部雾化卤化银乳剂的卤化银照相材料在至少一种选自由通式（I）和（I）表示的化合物组成的组的存在下进行显影处理， II）和具有巯基的至少一种具有巯基的亚烷基，以显示高照相速度，高对比度和高最大图像密度：R1-（R3）1X} nR3'-R2（I）其中R1和R2各自表示氢原子， 芳基，芳基或杂环基; R 3和R 3'各自表示亚烷基，亚芳基，杂环基; X表示
+ TR C（R4）2; R4表示氢原子或-R5-Y} mR5'-R6; R5和R5'与R3和R3'具有相同的含义; R6与R1和R2具有相同的含义; Y表示 + TR R7与R1和R2具有相同的含义; l表示0或1，n表示1至110的整数，m表示0至10的整数，并且其中至少一个X必须为硫原子：其中Q表示形成所需的原子 杂环，A表示烷基或芳基。 -
公开(公告)号：US4521508A
公开(公告)日：1985-06-04
申请号：US549515
申请日：1983-11-07
申请人： Tadao Sugimoto , Hideo Ikeda , Hiroyuki Mifune , Koki Nakamura
发明人： Tadao Sugimoto , Hideo Ikeda , Hiroyuki Mifune , Koki Nakamura
CPC分类号： G03C1/09 , Y10S430/141 , Y10S430/15
摘要： A silver halide photographic light-sensitive material is disclosed. The material is comprised of a support base having thereon a silver halide emulsion layer and a protective layer. The material contains a photosensitive silver halide emulsion and inside fogged silver halide emulsion as well as a disulfide compound. The disulfide compound is a compound represented by the general formula (I):A--S--S--B (I)wherein A and B independently represent an alkyl group, an aralkyl group, an aryl group, a heterocyclic group or ##STR1## wherein R represents an alkyl group, an aryl group, an aralkyl group, a heterocyclic group or an amino group. The material can form images having high contrast and a high maximum density. Further, the material has high sensitivity to light and can be developed at a low temperature in a reduced amount of time.
摘要翻译： 公开了一种卤化银照相感光材料。 该材料由其上具有卤化银乳剂层和保护层的支撑基底组成。 该材料含有光敏卤化银乳剂和雾化的卤化银乳剂以及二硫化物。 二硫化物是由通式（I）表示的化合物：ASSB（I）其中A和B独立地表示烷基，芳烷基，芳基，杂环基或其中R表示烷基 芳基，芳烷基，杂环基或氨基。 该材料可以形成具有高对比度和高最大密度的图像。 此外，该材料对光具有高灵敏度，并且可以在较短的时间内在低温下显影。
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