摘要:
A polymeric solid electrolyte capable of conducting lithium ions which contains silylamide bonds in its polymer skeleton structure, for example, which is obtained by a method comprising subjecting a mixture of lithium silylamide and an organic compound having at least one carbon—carbon double bond to a polymerization in a dry atmosphere; and a lithium secondary cell using the polymeric solid electrolyte. The polymeric solid electrolyte is a “dry” polymeric solid electrolyte which contains counter ions forming lithium salts with lithium ions in its polymer skeleton structure and thus has a single ion electron conducting system wherein lithium ions alone are mobile ions, and hence has excellent conductivity, and further is easy to produce. The polymeric solid electrolyte can therefore be used for producing a novel lithium secondary cell which is an alternative for conventional lithium cells using an organic solvent and is safe and excellent in the capability of corresponding to a variety of shapes and has a high cell voltage.
摘要:
In a non-aqueous electrolyte secondary battery, a cyclic carboxylic acid ester having a high conductivity in a low-temperature environment is used as an electrolyte, and, furthermore, a cyclic carbonic acid ester having at least one carbon-carbon unsaturated bond is added thereto for the inhibition of reductive decomposition of the cyclic carboxylic acid ester.
摘要:
A lithium secondary cell comprising a safe aqueous-solution electrolyte free from danger of firing and explosion and capable of supplying a high voltage of more than 3 V. The cell includes a positive plate having an active material absorbing/desorbing lithium ions and exhibiting a high voltage, a negative plate having an active material exhibiting a low voltage, a polymer solid electrolyte having a lithium-ionic conductivity, and an aqueous-solution electrolyte. The positive and negative plates are coated with a polymer solid electrolyte having an ionic conductivity and therefore isolated from the aqueous-solution electrolyte by the plate coating layers.
摘要:
The present invention relates to an electrolyte for non-aqueous electrochemical device containing at least one of 6-substituted-1,3,5-triazine-2,4-dithiol and derivatives thereof as an additive and a non-aqueous electrochemical device, particularly a lithium secondary battery by the use thereof. The additive of the present invention forms a stable and low resistance film on the positive electrode, inhibiting characteristics of the electrochemical device from deteriorating on account of gas generated due to the decomposition of electrolyte.
摘要:
The invention relates to a non-aqueous electrochemical apparatus in which the difference (γl−γse) between the surface tension γl of non-aqueous electrolyte and the surface free energy γse of electrode is not more than 10 dynes/cm.
摘要:
In an electrolyte of a non-aqueous electrolyte secondary battery using a cyclic carboxylic-acid ester exerting high conductivity under a low temperature condition, for suppressing reductive decomposition of the cyclic carboxylic acid ester, a cyclic carbonic acid ester having at least one carbon-carbon unsaturated bond is contained, and for suppressing excessive polymerization reaction of the cyclic carbonic acid ester having at least one carbon-carbon unsaturated bond, a cyclic carbonic acid ester having no carbon-carbon unsaturated bond is further contained.
摘要:
For providing a non-aqueous electrolyte secondary battery having excellent storage characteristics when stored in the charged state under a high temperature condition, the non-aqueous electrolyte or the negative electrode is made to contain divinylethylene carbonate, thereby to form a film derived from divinylethylene carbonate on the surface of the negative electrode material.
摘要:
The present invention relates to a nonaqueous electrolyte secondary battery, and more particularly to its separator, and it is an object thereof to prevent electrolyte leakage accident due to elevation of cell internal pressure even if the cell is exposed to high temperature without sacrificing the cell capacity. To achieve the object, by using the polyolefin group separator large in endothermic calorie per unit area by the heat of fusion in a temperature range of 70 to 150° C., and selecting appropriate graphite powder for negative electrode and organic solvent in nonaqueous electrolyte, the electrolyte leakage accident can be successfully eliminated by suppressing the reaction between the cell active substance and organic solvent, thereby suppressing elevation of cell internal pressure.
摘要:
A cell capable of preventing precipitation of lithium on a negative electrode plate in the final stage of a cycle life and achieving a superior cycling performance and high safety and reliability is provided. In a rechargeable secondary cell using a non-aqueous electrolyte, a positive electrode contains an active material and a conductive element, and Ketjenblack, a mixture of Ketjenblack and flake graphite or a mixture of Ketjenblack and acetylene black is employed as such conductive element.
摘要:
A non-aqueous electrolyte secondary battery wherein the non-aqueous electrolyte contains a non-aqueous solvent, a solute dissolved in the non-aqueous solvent, and hydrogenated terphenyl, the solute includes a boron-containing alkali salt and a boron-free alkali salt, the negative electrode includes a negative electrode active material comprising a randomly oriented carbon composite (A), and the carbon composite (A) contains a graphitic carbon substance (B) and a carbon substance (C) that is different from the graphitic carbon substance (B).