摘要:
Stretched blow molding articles are prepared by using an aliphatic polyester composition having a melting point of at least 70.degree. C. including: 97.5 to 75 parts by weight of an aliphatic polyester copolymer (A) having a Mn of at least 50,000 which is obtained by reacting 100 parts by weight of a polyester diol (a) with 0.1 to 5 parts by weight of diisocyanate, wherein the polyester diol (a) is obtained by conducting a polycondensation of 1 mol of an acid component consisting of 70 to 90 mol % of succinic acid and 10 to 30 mol % of adipic acid, with 1 to 1.1 mol of glycol; and 2.5 to 25 parts by weight of potybutylene succinate (B) with a linear structure, (C) with a branched long chain structure, or (D) with a branched longer chain structure, which have an Mn of at least 50,000 and are composed from some of succinic acid, 1,4-butanediol, polyfunctional comonomer and di- or poly-functional coupling agents.
摘要:
A method for producing a high molecular weight aliphatic polyester, wherein:(A) 100 parts by weight of polyester (a) with a number average molecular weight of at least 10,000, and a weight average molecular weight of at least 30,000, and with end-groups that are substantially hydroxyl groups, and with a melting point of at least 60.degree. C., the polyester (a) having been obtained by reacting the following three ingredients: (i) a glycol ingredient; (ii) an aliphatic dicarboxylic acid ingredient; and (iii) a trifunctional or tetrafunctional ingredient reacts with(B) 0.1-3 parts by weight of a poly-isocyanate in a melted state of the polyester (a).The method provides a high molecular weight aliphatic polyester which has good properties and a melt viscosity required for molding and forming and has a wide molecular weight distribution. The high molecular weight aliphatic polyester is applicable to a variety of fields, such as films, moldings and formings, fibers, etc.
摘要:
Curable resin compositions comprising (A) polyene components, and (B) unsaturated alicyclic compounds having thiol groups. The compositions are odorless and also excellent in heat resistance, adhesion properties and mechanical properties compared with conventional polyene-polythiols.
摘要:
A laminate is disclosed, comprising substrates which are impregnated with a curable composition, laminated and cured, wherein the curable composition comprises (i) a curable prepolymer having a main chain consisting essentially of a random copolymer of a vinyl monomer and an acrylic or methacrylic monomer, and a side chain containing an acryloyl or methacryloyl group at the terminal, as a main component, and (ii) a crosslinkable vinyl monomer.