摘要:
A positive electrode active material for a non-aqueous electrolyte secondary battery of the present invention includes composite oxide particles including lithium, nickel, and an element M, the element M being at least one of aluminum and cobalt. The composite oxide particles include primary particles and each particle of the primary particles includes a surface portion and an inner portion. A content of the element M in the surface portion is higher than a content of the element M in the inner portion, and a proportion of the primary particles relative to all of the composite oxide particles is 80 to 100 wt %. According to the invention, a positive electrode active material for a non-aqueous electrolyte secondary battery that has excellent cycle characteristics and storage characteristics and is suitable for use in a wide range of the state of charge and in a high-temperature environment and a non-aqueous electrolyte secondary battery using the same can be obtained.
摘要:
The present invention mainly relates to non-aqueous electrolyte secondary batteries. The present invention intends to provide a non-aqueous electrolyte secondary battery having excellent cycle characteristics and excellent storage characteristics.The non-aqueous electrolyte secondary battery of the present invention includes a positive electrode including a positive electrode active material, a negative electrode including a negative electrode active material, a separator interposed between the positive electrode and the negative electrode, and a non-aqueous electrolyte. The positive electrode active material includes secondary particles each being an aggregate of a plurality of primary particles, and the primary particles have an average particle diameter of 0.8 μm or less. The secondary particles each contain aluminum atoms, and the content of the aluminum atoms is larger in a portion near the surface of each of the secondary particles than in a portion near the center of each of the secondary particles.
摘要:
A lithium nickel composite oxide, having small inner resistance, large battery capacity and high thermal stability, can be used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The positive electrode active material is composed of the lithium nickel composite oxide of LibNi1-aMaO2 (wherein M represents at least one element selected from a transition metal element other than Ni, the second group element and the thirteenth group element; a satisfies 0.01≦a≦0.5; and b satisfies 0.9≦b≦1.1). This is obtained by filtering and drying the fired powder after water washing, wherein it is dried at 90° C. or lower, till moisture is reduced to 1% or less by mass in drying, and then at 120° C., and under gas atmosphere where content of compound components containing carbon is 0.01% or less by volume, or under vacuum atmosphere.
摘要:
A method for producing a lithium-containing transition metal oxide represented by the general formula: Li[Lix(NiaM1−a)1−x]O2 where M is metal other than Li and Ni, 0≦x, and 0
摘要翻译:由Li [Lix(NiaM1-a)1-x] O 2表示的含锂过渡金属氧化物的制造方法,其中M是不同于Li和Ni的金属,0< 1E * x和0
摘要:
A positive electrode active material for a non-aqueous electrolyte secondary battery includes a particle of a composite oxide which contains Li and Co, wherein: the composite oxide further contains an element M1 and an element M2; the element M1 is at least one selected from the group consisting of Mg, Cu and Zn; the element M2 is at least one selected from the group consisting of Al, Ca, Ba, Sr, Y and Zr; the element M1 is uniformly distributed in the particle; and the element M2 is distributed in the surface portion of the particle more than in the inside thereof.
摘要:
A lithium nickel composite oxide, having small inner resistance, large battery capacity and high thermal stability, can be used as a positive electrode active material for a non-aqueous electrolyte secondary battery. The positive electrode active material is composed of the lithium nickel composite oxide of LibNi1-aMaO2 (wherein M represents at least one element selected from a transition metal element other than Ni, the second group element and the thirteenth group element; a satisfies 0.01≦a≦0.5; and b satisfies 0.9≦b≦1.1). This is obtained by filtering and drying the fired powder after water washing, wherein it is dried at 90° C. or lower, till moisture is reduced to 1% or less by mass in drying, and then at 120° C., and under gas atmosphere where content of compound components containing carbon is 0.01% or less by volume, or under vacuum atmosphere.
摘要:
The process for preparing spinel-type lithium manganate according to the present invention is constituted by a process to admix the electrolyzed manganese dioxide, which is obtained by neutralizing manganese dioxide precipitated by means of electrolysis with any of potassium hydroxide, potassium carbonate and lithium hydroxide, and a lithium material and a process to subject the resulting mixture to a sintering process.
摘要:
[Problem] To provide a positive-type photosensitive resin composition that is produced with novolac resin and has good mechanical properties and high storage stability. [Means for Solving the Problem] A positive-type photosensitive resin composition, comprising: (a) a novolac resin; (b) a polymer comprising, as a main component, a structure represented by formula (1) below and/or a structure represented by formula (2) below: (wherein formulae (1) and (2), R1 and R2 may be the same or different and each represent an organic group having at least two carbon atoms and a valence of 2 to 8, R3 and R4 may be the same or different and each represent hydrogen or a monovalent organic group of 1 to 20 carbon atoms, —NH—R5 in formula (1) and —CO—R6 in formula (2) each represent a polymer end group, R5 and R6 each represent a monovalent organic group having 2 to 30 carbon atoms which includes an unsaturated hydrocarbon group, n is in the range of 10 to 100,000, l and m each represent an integer of 0 to 2, and p and q each represent an integer of 0 to 4, provided that p+q>0; (c) a quinone diazide compound; (d) an alkoxymethyl group-containing compound; and (e) a solvent.
摘要:
A positive electrode active material for a non-aqueous electrolyte secondary battery includes a particle of a composite oxide which contains Li and Co, wherein: the composite oxide further contains an element M1 and an element M2; the element M1 is at least one selected from the group consisting of Mg, Cu and Zn; the element M2 is at least one selected from the group consisting of Al, Ca, Ba, Sr, Y and Zr; the element M1 is uniformly distributed in the particle; and the element M2 is distributed in the surface portion of the particle more than in the inside thereof.
摘要:
There is provided a positive electrode active material for a non-aqueous electrolyte secondary battery, comprising a composite oxide represented by the general formula (1): (Li1-xMx)a(Co1-yMy)bOc where lithium and cobalt are partly replaced with element M in the crystal structure of LiCoOc, wherein element M is at least one selected from the group consisting of Al, Cu, Zn, Mg, Ca, Ba and Sr, and 0.02≦x+y≦0.15, 0.90≦a/b≦1.10, and 1.8≦c≦2.2 are satisfied.
摘要翻译:提供一种非水电解质二次电池用正极活性物质,其包含由通式(1)表示的复合氧化物:(Li 1-x M x S / (&lt; 1&gt; 1&gt;&lt;&lt;&gt;&lt;&lt;&gt; 锂和钴在LiCoO C 3的晶体结构中部分被元素M替代,其中元素M是选自Al,Cu,Zn,Mg,Ca,Ba和Sr中的至少一种 ,并且满足0.02 <= x + y <= 0.15,0.90 <= a / b <= 1.10和1.8 <= c <2.2。