公开(公告)号：US5380510A

公开(公告)日：1995-01-10

申请号：US166261

申请日：1993-12-09

申请人： Takashi Matsui ,  Nobuki Watanabe ,  Masayuki Arimura ,  Eiji Kanemaru ,  Yuzo Horinouchi ,  Mutsuhiro Ito

发明人： Takashi Matsui ,  Nobuki Watanabe ,  Masayuki Arimura ,  Eiji Kanemaru ,  Yuzo Horinouchi ,  Mutsuhiro Ito

IPC分类号： C01B33/152 ,  C01B33/14

CPC分类号： C01B33/152

摘要： This invention provides a method for manufacturing silica gels in a form of scales or needles having a pore volume and a specific surface area being relatively large and being controlled. Silicic acid sol is frozen, crystallized and deposited in gaps among crystal faces of crystals of solvent of the sol, thus obtaining the frozen silica hydrogels in the form of scales or needles. After unfreezing the frozen silica hydrogels, a hydrothermal polymerization is carried out. Subsequently, the silica hydrogels are dried, thus obtaining the silica gels in the form of scales or needles. Furthermore in the invention, by controlling the gelation time period of silica sol, the silica gels with their configuration controlled can result from even inexpensive silica sol. The invention has the advantage that a freeze-drying step is not required: just through freezing, unfreezing, washing and hydrothermal polymerization steps, the physical properties of the silica gels can be controlled.

摘要翻译： 本发明提供了一种制备具有孔体积和比表面积相对较大并被控制的鳞片或针状形式的硅胶的方法。 将硅酸溶胶冷冻，结晶沉积在溶胶溶剂晶体的晶面之间的间隙中，从而获得鳞片或针状冷冻的二氧化硅水凝胶。 解冻冷冻二氧化硅水凝胶后，进行水热聚合。 随后，将二氧化硅水凝胶干燥，得到鳞片或针形状的硅胶。 此外，在本发明中，通过控制二氧化硅溶胶的凝胶化时间，其控制结构的硅胶可由廉价的二氧化硅溶胶得到。 本发明的优点是不需要冷冻干燥步骤：通过冷冻，解冻，洗涤和水热聚合步骤，可以控制硅胶的物理性能。

公开(公告)号：US5589150A

公开(公告)日：1996-12-31

申请号：US845528

申请日：1992-03-04

申请人： Jiro Kano ,  Ryuji Orii ,  Yuzo Horinouchi ,  Mutsuhiro Ito

发明人： Jiro Kano ,  Ryuji Orii ,  Yuzo Horinouchi ,  Mutsuhiro Ito

IPC分类号： C01B33/158 ,  B01J21/08 ,  B01J37/00 ,  C01B33/154 ,  C01B33/157 ,  C01B33/16 ,  C08F4/06 ,  C08F4/18 ,  C08F10/00 ,  C01B33/12

CPC分类号： C01B33/16 ,  B01J21/08 ,  B01J37/0045 ,  C01B33/154 ,  C01B33/157

摘要： In the present invention, minute spherular silica gel particles suitable as polymer catalyst carriers can easily be obtained without using organic substances simply by controlling the moisture content in a slurry of silica hydrogel particles and water. The obtained spherular silica gel particles have physical properties, such as specific surface area, average pore diameter, and pore volume, that may be easily controlled. The spherular silica gel particles also have sufficient particle strength.

摘要翻译： 在本发明中，通过控制二氧化硅水凝胶颗粒和水的浆料中的水分含量，可以容易地获得适合作为聚合物催化剂载体的微小球状硅胶颗粒而不使用有机物质。 获得的球状硅胶颗粒具有可以容易地控制的物理性质，例如比表面积，平均孔径和孔体积。 球状硅胶颗粒也具有足够的颗粒强度。

公开(公告)号：US5389268A

公开(公告)日：1995-02-14

申请号：US137825

申请日：1993-10-15

申请人： Mutsuhiro Ito ,  Nobuki Watanabe ,  Sakio Takahashi ,  Yuji Takahashi

发明人： Mutsuhiro Ito ,  Nobuki Watanabe ,  Sakio Takahashi ,  Yuji Takahashi

IPC分类号： B01D39/06 ,  C12H1/07

CPC分类号： C12H1/063 ,  B01D39/06

摘要： The present invention provides a novel filter aid which has excellent filtration properties and forms a stable cake layer on a filter member. The filter aid includes a flake-like, scale-like, or rod-like silica gel as a primary component thereof. The silica gel is approximately 5 through 100 micrometer in grain diameter and has a pore volume of approximately 0.2 through 1.5 ml/g and a specific surface area of approximately 100 through 1,000 m.sup.2 /g.

摘要翻译： 本发明提供了一种具有优异的过滤性能的新型助滤剂，并且在过滤构件上形成了稳定的滤饼层。 助滤剂包括片状，鳞状或棒状硅胶作为其主要组分。 硅胶的晶粒直径为约5至100微米，孔体积为约0.2至1.5ml / g，比表面积为约100至1,000m 2 / g。

公开(公告)号：US06604374B2

公开(公告)日：2003-08-12

申请号：US09939915

申请日：2001-08-27

申请人： Mutsuhiro Ito ,  Tatsuya Asano ,  Masanobu Hasatani ,  Fujio Watanabe

发明人： Mutsuhiro Ito ,  Tatsuya Asano ,  Masanobu Hasatani ,  Fujio Watanabe

IPC分类号： F25B2700

CPC分类号： F24F3/1411 ,  B60H1/00007 ,  B60H1/3201

摘要： In a cooling apparatus, air within a room is first introduced into a radiator-type adsorber (1), where moisture contained in the air is adsorbed by A-type silica gel. The resulting low-humidity air is subsequently introduced into a desorption cooler (5), where moisture is desorbed from B-type silica gel, thereby humidifying and cooling the air. The resulting low-temperature air is then used for cooling. When a cooling capacity of the cooling apparatus is lowered, air from a heat source is introduced into the radiator-type adsorber (1), where the moisture is desorbed from the A-type silica gel, thereby recovering the adsorbability thereof. The high-humidity air resulting from the desorption of the moisture is subsequently introduced into the desorption cooler (5), where the moisture contained in the air is adsorbed by the B-type silica gel, thereby recovering the desorption cooling capacity thereof.

摘要翻译： 在冷却装置中，室内的空气首先被引入散热器型吸附器（1），其中包含在空气中的水分被A型硅胶吸附。 随后将所得低湿空气引入解吸冷却器（5）中，其中水分从B型硅胶中解吸，从而加湿和冷却空气。 然后将所得到的低温空气用于冷却。 当冷却装置的冷却能力降低时，来自热源的空气被引入散热器型吸附器（1）中，其中水分从A型硅胶中解吸，从而回收其吸附性。 然后将由水分解吸附的高湿空气引入到解吸冷却器（5）中，其中包含在空气中的水分被B型硅胶吸附，从而回收其解吸冷却能力。

公开(公告)号：US5109716A

公开(公告)日：1992-05-05

申请号：US605958

申请日：1990-10-30

申请人： Mutsuhiro Ito ,  Toshiyasu Abe ,  Ryuji Orii ,  Tomio Yamakoshi

发明人： Mutsuhiro Ito ,  Toshiyasu Abe ,  Ryuji Orii ,  Tomio Yamakoshi

IPC分类号： G01N15/08

CPC分类号： G01N15/0893

摘要： The actual flow rate of gas to the solid-sample container or to the gas reservoir can be precisely obtained according to variances in the pressure of the gas reservoir without directly adjusting the flow rate precisely. The volume of gas not adsorbed in the sample container can be obtained from the pressure in the sample container. The adsorption can easily be determined from the difference between the flow rate of gas and the volume of gas not adsorbed in the sample container. Even if the flow rate fluctuates, the adsorption can precisely be obtained. The desorption can easily be obtained in the same way. Gas is exhausted from the gas reservoir in advance. When desorbed gas in the sample container is continuously exhausted to the gas reservoir, the pressure in the gas reservoir is measured. Since the adsorption and desorption are thus precisely obtained, the adsorption of desorption isotherm can be drawn by plotting the pressure at each point of time and the corresponding adsorption or desorption of the solid sample. Consequently, the surface area, pore diameter distribution, pore volume and the like of the solid sample can precisely be calculated.

公开(公告)号：US06565905B1

公开(公告)日：2003-05-20

申请号：US08889563

申请日：1997-07-08

申请人： Mutsuhiro Ito ,  Shinji Yamamoto ,  Akihiko Okada ,  Yoshihisa Ishiwata

发明人： Mutsuhiro Ito ,  Shinji Yamamoto ,  Akihiko Okada ,  Yoshihisa Ishiwata

IPC分类号： C10B3312

CPC分类号： C01B33/157 ,  C12H1/0408

摘要： There is proposed a silica gel for preventing the generation of haze in beer, a method of manufacturing the silica gel and a method of stabilization treatment of beer. The silica gel is provided with a specific surface area of 700-1000 m2/g, a pore volume of 1.1-1.6 ml/g and a average pore diameter of 6-10 nm, and has a relatively high adsorbability per unit weight. In the method of manufacturing the silica gel, the washed, hydrothermally treated, acid treated, ground and dried silica hydrogel is calcined at 400-800° C. for 10 seconds to 10 hours. A haze causing component can be removed from beer by contacting the silica gel with the beer and subsequently separating the silica gel from the beer.

摘要翻译： 提出了一种用于防止啤酒中产生雾度的硅胶，制备硅胶的方法和啤酒的稳定化处理方法。 硅胶的比表面积为700〜1000m2 / g，孔体积为1.1〜1.6ml / g，平均孔径为6-10nm，每单位重量的吸附性比较高。 在制造硅胶的方法中，洗涤，水热处理的酸处理，研磨和干燥的二氧化硅水凝胶在400-800℃下煅烧10秒至10小时。 通过使硅胶与啤酒接触并随后将硅胶与啤酒分离，可以从啤酒中除去雾霾成分。