公开(公告)号：US5244487A

公开(公告)日：1993-09-14

申请号：US653643

申请日：1991-02-11

申请人： Takashi Oritani ,  Mitsunori Oda ,  Taketo Maruyama ,  Takashi Suzuki ,  Akinori Tanaka ,  Toshio Kajita ,  Shigeo Yoshinaka ,  Masakazu Furushima

发明人： Takashi Oritani ,  Mitsunori Oda ,  Taketo Maruyama ,  Takashi Suzuki ,  Akinori Tanaka ,  Toshio Kajita ,  Shigeo Yoshinaka ,  Masakazu Furushima

IPC分类号： A01N43/90 ,  C07D473/34

CPC分类号： C07D473/34 ,  A01N43/90

摘要： Disclosed are novel adenine derivatives represented by the formula I and agriculturally acceptable acid addition salts thereof represented by the formula: ##STR1## wherein n is an integer of 2-4. Compositions for increasing yield of crops such as leguminous crops and gramineous crops which contain the above adenine derivatives or salts thereof as an active ingredient and methods for increasing yield of crops using these compositions are also disclosed.

摘要翻译： 公开了由式I表示的新型腺嘌呤衍生物及其农业上可接受的由下式表示的酸加成盐：其中n为2-4的整数。 还公开了增加含有上述腺嘌呤衍生物或其盐作为活性成分的豆科作物和禾本科作物的作物的产量的组合物和使用这些组合物提高作物产量的方法。

公开(公告)号：US4929267A

公开(公告)日：1990-05-29

申请号：US938872

申请日：1986-12-08

申请人： Akinori Suzuki ,  Suong B. Hyeon ,  Toshio Kajita ,  Masakazu Furushima ,  Shigeo Yoshinaka ,  Takashi Suzuki ,  Mitsunori Oda ,  Akinori Tanaka

发明人： Akinori Suzuki ,  Suong B. Hyeon ,  Toshio Kajita ,  Masakazu Furushima ,  Shigeo Yoshinaka ,  Takashi Suzuki ,  Mitsunori Oda ,  Akinori Tanaka

IPC分类号： A01N33/08 ,  A01N33/12 ,  A01N33/18 ,  A01N37/02 ,  A01N37/06 ,  A01N37/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/84 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20 ,  C07D295/08

CPC分类号： A01N33/12 ,  A01N33/18 ,  A01N37/02 ,  A01N37/06 ,  A01N37/10 ,  A01N47/06 ,  A01N47/12 ,  A01N47/20

摘要： Use of agriculturally acceptable salts of compounds of the following formula for promoting the growth of plants. ##STR1## wherein Hal represents a chlorine, bromine or iodine atom, X.sub.1 represents a hydrogen or chlorine atom, or a methyl, trifluoromethyl, nitro, methoxy or t-butyl group, and X.sub.2 represents a hydrogen atom, or both X.sub.1 and X.sub.2 represent a chlorine atom or a methyl group; and Y represents a hydrogen atom, or a C.sub.2-6 alkylcarbonyl, benzoyl, N-phenylcarbamoyl, N-3,4-dichlorophenylcarbamoyl, chloropropylcarbonyl, methoxycarbonyl, carbamoyl or methacryloyl group.

公开(公告)号：US5409957A

公开(公告)日：1995-04-25

申请号：US35903

申请日：1993-03-23

申请人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

发明人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

IPC分类号： A01N39/00 ,  C07C217/00 ,  C07C217/20 ,  A01N33/26

CPC分类号： A01N39/00 ,  C07C217/20

摘要： Disclosed are a phenoxyalkylamine represented by the following general formula I and a salt of said phenoxyalkylamine represented by the following general formula II: ##STR1## wherein R represents a linear saturated hydrocarbon having 7 to 12 carbon atoms, n is an integer of from 1 to 5, m is an integer of from 2 to 4, and HX represents a mineral acid.These compounds have strong bacteriostatic and bactericidal actions for plants with no phytotoxicity. Therefore, these compounds are effectively used as the active ingredient of an agricultural and horticultural bactericide.

摘要翻译： 公开了由以下通式I表示的苯氧基烷基胺和由以下通式II表示的所述苯氧基烷基胺的盐：其中R表示具有7至12个碳原子的直链饱和烃，n是 1〜5的整数，m为2〜4的整数，HX表示无机酸。 这些化合物对没有植物毒性的植物具有很强的抑菌和杀菌作用。 因此，这些化合物有效地用作农业和园艺杀菌剂的活性成分。

公开(公告)号：US5331011A

公开(公告)日：1994-07-19

申请号：US43854

申请日：1993-04-07

申请人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

发明人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

IPC分类号： A01N39/00 ,  C07C217/20 ,  A01N37/30 ,  C07C63/08 ,  C07C217/08

CPC分类号： C07C217/20 ,  A01N39/00

摘要： Disclosed is an N-benzyl-N-phenoxyethylamine selected from the group consisting of the N-benzyl-N-phenoxyethylamine represented by the following formula (I): ##STR1## and an agriculturally acceptable acid addition salt represented by the following formula (II): ##STR2## wherein m represents a number of 1 or 2 with a proviso that when m is 1 and a chlorine atom in the ring A is present at para(4)-position of the ring A, two chlorine atoms in the ring B are present at 2,3-, 2,5-, 2,6-, 3,4- or 3,5-positions of the ring B, and HX represents an acid.

摘要翻译： 公开了N-苄基-N-苯氧基乙胺，其选自由下式（I）表示的N-苄基-N-苯氧基乙胺：由下式（I）表示的农业上可接受的酸加成盐 式（II）：其中m表示1或2的数，条件是当m为1且环A中的氯原子存在于环A的对位（4）位时， 环B中的两个氯原子存在于环B的2,3-，2,5-，2,6-，3,4-或3,5位，HX表示酸。

公开(公告)号：US5221694A

公开(公告)日：1993-06-22

申请号：US691798

申请日：1991-04-26

申请人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

发明人： Mitsunori Oda ,  Kazutoshi Kikkawa ,  Akinori Tanaka ,  Satoko Imaruoka ,  Shigeo Yoshinaka

IPC分类号： A01N39/00 ,  C07C217/20

CPC分类号： C07C217/20 ,  A01N39/00

摘要： Disclosed is an N-benzyl-N-phenoxyethylamine selected from the group consisting of the N-benzyl-N-phenoxyethylamine represented by the following formula (I): ##STR1## and an agriculturally acceptable acid addition salt represented by the following formula (II): ##STR2## wherein m represents a number of 1 or 2 with a proviso that when m is 1 and a chlorine atom in the ring A is present at para(4)-position of the ring A, two chlorine atoms in the ring B are present at 2,3-, 2,5-, 2,6-, 3,4- or 3,5-positions of the ring B and HX represents an acid.

公开(公告)号：US4029560A

公开(公告)日：1977-06-14

申请号：US671698

申请日：1976-03-29

申请人： Shigeo Yoshinaka ,  Masaharu Doya ,  Seiiji Uchiyama ,  Sadao Nozaki

发明人： Shigeo Yoshinaka ,  Masaharu Doya ,  Seiiji Uchiyama ,  Sadao Nozaki

IPC分类号： C07C17/00 ,  C07C17/14 ,  C07C22/04 ,  C07C51/00 ,  C07C51/60 ,  C07C63/15 ,  C07C63/30 ,  C07C67/00 ,  C08G69/32 ,  B01J1/10

CPC分类号： C08G69/32 ,  C07C17/14 ,  C07C51/60 ,  Y10S204/914

摘要： This invention concerns to a process for .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene by reacting m-xylene or p-xylene or a partially chlorinated product thereof with chlorine under the irradiation of ultraviolet rays, the process comprising (1) a first-step chlorination reaction which is carried out in the presence of .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene as a solvent added at the initial stage of the reaction, and continued until a compound convertible to .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene by chlorination becomes substantially absent in the reaction mixture, and (2) a second-step chlorination reaction which is continued from the first-step chlorination and carried out to convert difficulty-separable by-products present in the reaction mixture to easily-separable compounds. This invention also concerns to a process for producing an aromatic dicarboxylic acid chloride which comprise reacting the resulting .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene with isophthalic acid or terephthalic acid.

摘要翻译： 本发明涉及一种通过在紫外线照射下使间二甲苯或对二甲苯或其部分氯化产物与氯反应的α，α，α，α'，α'，α'-六氯二氧化碳的方法，该方法包括 （1）第一步氯化反应，其在α，α，α，α'，α'，α'-六氯二苯作为反应初始阶段加入的溶剂存在下进行，并持续进行到化合物 在反应混合物中通过氯化可转化成α，α，α，α'，α'，α'-六氯二苯基本上不存在，和（2）第二步氯化反应，继续从第一步氯化并进行 将反应混合物中存在的难以分离的副产物转化成容易分离的化合物。 本发明还涉及一种制备芳族二羧酰氯的方法，其包括使所得的α，α，α，α'，α'，α'-六氯代二甲苯与间苯二甲酸或对苯二甲酸反应。

公开(公告)号：US4507510A

公开(公告)日：1985-03-26

申请号：US566377

申请日：1983-12-28

申请人： Shigeo Yoshinaka ,  Tsukasa Toki ,  Tomoji Tsuji ,  Seiji Uchiyama

发明人： Shigeo Yoshinaka ,  Tsukasa Toki ,  Tomoji Tsuji ,  Seiji Uchiyama

IPC分类号： C07C29/09 ,  C07C27/00 ,  C07C29/00 ,  C07C33/26 ,  C07C67/00

CPC分类号： C07C29/00

摘要： Xylyleneglycol is produced by diazotization reaction of xylylenediamine in the presence of more than 5 parts by weight of water per 1 part of xylylenediamine, while maintaining the PH of the reaction mixture in the range of 1.5 to 5.0.

摘要翻译： 苯二甲醇通过苯甲二胺在每5份（重量）水/ 1份苯二甲胺存在下进行重氮化反应，同时将反应混合物的PH保持在1.5至5.0的范围内。

公开(公告)号：US4399311A

公开(公告)日：1983-08-16

申请号：US282733

申请日：1981-07-13

申请人： Shigeo Yoshinaka ,  Tsukasa Toki ,  Misuzu Wakatsuki ,  Seiji Uchiyama

发明人： Shigeo Yoshinaka ,  Tsukasa Toki ,  Misuzu Wakatsuki ,  Seiji Uchiyama

IPC分类号： C07C47/52 ,  C07C45/00 ,  C07C45/27 ,  C07C45/28 ,  C07C45/43 ,  C07C47/54 ,  C07C47/544 ,  C07C67/00 ,  C07C45/42

CPC分类号： C07C45/27

摘要： In a process for producing aromatic aldehydes by reacting chlorinated methylbenzenes with nitric acid, the improvement wherein a lead compound is added to the residue left after separation and recovery of the resulting aromatic aldehydes from the reaction mixture thereby to remove a chlorine ion present in the residue as a precipitate of lead chloride, and the residue left after removal of the lead chloride is recycled to the reaction of the chlorinated methylbenzenes with nitric acid.

摘要翻译： 在氯代甲基苯与硝酸反应生成芳族醛的方法中，其中在从反应混合物中分离和回收所得芳族醛后留下的残留物中加入铅化合物，由此除去残留物中存在的氯离子 作为氯化铅的沉淀物，并且在除去氯化铅后留下的残余物被再循环到氯化甲基苯与硝酸的反应中。

公开(公告)号：US4328374A

公开(公告)日：1982-05-04

申请号：US166114

申请日：1980-07-07

申请人： Shigeo Yoshinaka ,  Masaharu Doya

发明人： Shigeo Yoshinaka ,  Masaharu Doya

IPC分类号： C07C47/544 ,  C07C17/14 ,  C07C45/00 ,  C07C45/27 ,  C07C45/80 ,  C07C45/81 ,  C07C67/00 ,  C07C45/28

CPC分类号： C07C45/80 ,  C07C17/14 ,  C07C45/27 ,  C07C45/81

摘要： A process for the production of aromatic dialdehydes which comprises reacting xylene chloride selected from the group consisting of .alpha.,.alpha.,.alpha.'-trichloroxylene alone, or a mixture of .alpha.,.alpha.,.alpha.'-trichloroxylene and .alpha.,.alpha.'-dichloroxylene, a mixture of .alpha.,.alpha.,.alpha.'-trichloroxylene and .alpha.,.alpha.,.alpha.',.alpha.'-tetrachloroxylene and a mixture of .alpha.,.alpha.,.alpha.'-trichloroxylene, .alpha.,.alpha.'-dichloroxylene and .alpha.,.alpha.,.alpha.',.alpha.'-tetrachloroxylene with nitric acid.

摘要翻译： 一种制备芳族二醛的方法，其包括使选自α，α，α'-三氯代二氧化硅或单独的α，α，α'-三氯代二甲苯和α，α'-二氯二氧化硅的混合物的二甲苯氯反应， α，α，α'-三氯代二甲苯和α，α，α'，α'-四氯代二甲苯和α，α，α'-三氯代二甲苯，α，α'-二氯二氧化碳和α，α，α'，α ' - 四氯二氧化硅与硝酸。

公开(公告)号：US4165337A

公开(公告)日：1979-08-21

申请号：US844814

申请日：1977-10-25

申请人： Shigeo Yoshinaka ,  Masaharu Doya ,  Seiji Uchiyama ,  Sadao Nozaki

发明人： Shigeo Yoshinaka ,  Masaharu Doya ,  Seiji Uchiyama ,  Sadao Nozaki

IPC分类号： C07C63/15 ,  B01J19/12 ,  C07C17/14 ,  C07C51/00 ,  C07C51/60 ,  C07C67/00 ,  C07C51/58

CPC分类号： C07C17/14 ,  C07C51/60

摘要： A batchwise or continuous process for producing isophthaloyl dichloride or terephthaloyl dichloride having a high purity which comprises, in combination, (1) a first step of producing .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene by reacting meta- or para-xylene with chlorine under the irradiation of ultraviolet-containing rays, the reaction being carried out in the presence of, as a solvent, .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene added at the outset of the reaction; (2) a second step of producing isophthaloyl dichloride or terephthaloyl dichloride by reacting the .alpha.,.alpha.,.alpha.,.alpha.',.alpha.',.alpha.'-hexachloroxylene obtained in the first step with isophthalic acid or terephthalic acid; and (3) a third step of purifying the isophthaloyl dichloride or terephthaloyl dichloride obtained in the second step by dissolving the isophthaloyl dichloride or terephthaloyl dichloride in 0.3 to 6 parts by weight; per part by weight of the phthaloyl dichloride, of C.sub.6 -C.sub.10 aliphatic hydrocarbon solvent, and cooling the solution to a temperature of the specified range thereby to recrystallize the phthaloyl dichloride.

摘要翻译： 用于制备具有高纯度的间苯二酰二氯或对苯二甲酰氯的间歇或连续方法，其组合包括（1）通过使间位化合物反应生成α，α，α，α'，α'，α'-六氯代二甲苯的第一步骤， 或对二甲苯与氯在紫外线照射下反应，反应在作为溶剂的存在下进行，α，α，α，α'，α'，α'-六氯化碳在开始时加入 反应; （2）通过使第一步获得的α，α，α，α'，α'，α'-六氯二苯与间苯二甲酸或对苯二甲酸反应，生产间苯二酰二氯或对苯二甲酰氯的第二步; 和（3）通过将间苯二酰二氯或对苯二酰氯溶解在0.3至6重量份中来纯化在第二步中获得的间苯二酰二氯或对苯二甲酰氯的第三步骤; 每重量份邻苯二甲酰二氯化物，C 6 -C 10脂族烃溶剂，并将溶液冷却至指定范围的温度，从而使邻苯二甲酰氯二氯化物重结晶。