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公开(公告)号：US07867647B2
公开(公告)日：2011-01-11
申请号：US11885636
申请日：2006-04-04
CPC分类号： H01M4/94 , C01B3/38 , C01B3/46 , C01B2203/0233 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1247 , H01M8/0258 , H01M8/04007 , H01M8/04223 , H01M8/04225 , H01M8/04268 , H01M8/04373 , H01M8/04753 , H01M8/04761 , H01M8/04776 , H01M8/0618 , H01M8/0662 , H01M8/1246 , H01M8/126 , Y02E60/525 , Y02P20/128 , Y02P70/56
摘要： In a hydrogen generation device according to the invention, PSR reformers have a heat capacity smaller than that of the other PSR reformers. Therefore, the temperature of the catalyst reaches to a reforming-start temperature more quickly in the PSR reformers than in the other PSR reformers. When the hydrogen generation device is started and the reforming reaction is carried out, the mixture of gasoline vapor and water vapor is selectively and preferentially supplied to the PSR reformers so that the reforming reaction is carried out in the PSR reformers.
摘要翻译： 在根据本发明的氢生成装置中，PSR重整器的热容量小于其他PSR重整器的热容量。 因此，在PSR重整器中催化剂的温度比其他PSR重整器更快地达到重整开始温度。 当氢发生装置启动并进行重整反应时，汽油蒸气和水蒸汽的混合物选择性地优先地供应给PSR重整器，从而在PSR重整器中进行重整反应。
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公开(公告)号：US20080160367A1
公开(公告)日：2008-07-03
申请号：US11885636
申请日：2006-04-04
CPC分类号： H01M4/94 , C01B3/38 , C01B3/46 , C01B2203/0233 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1247 , H01M8/0258 , H01M8/04007 , H01M8/04223 , H01M8/04225 , H01M8/04268 , H01M8/04373 , H01M8/04753 , H01M8/04761 , H01M8/04776 , H01M8/0618 , H01M8/0662 , H01M8/1246 , H01M8/126 , Y02E60/525 , Y02P20/128 , Y02P70/56
摘要： In a hydrogen generation device according to the invention, PSR reformers have a heat capacity smaller than that of the other PSR reformers. Therefore, the temperature of the catalyst reaches to a reforming-start temperature more quickly in the PSR reformers than in the other PSR reformers. When the hydrogen generation device is started and the reforming reaction is carried out, the mixture of gasoline vapor and water vapor is selectively and preferentially supplied to the PSR reformers so that the reforming reaction is carried out in the PSR reformers.
摘要翻译： 在根据本发明的氢生成装置中，PSR重整器的热容量小于其他PSR重整器的热容量。 因此，在PSR重整器中催化剂的温度比其他PSR重整器更快地达到重整开始温度。 当氢发生装置启动并进行重整反应时，汽油蒸气和水蒸汽的混合物选择性地优先地供应给PSR重整器，从而在PSR重整器中进行重整反应。
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公开(公告)号：US08263273B2
公开(公告)日：2012-09-11
申请号：US10585875
申请日：2005-02-15
申请人： Shigeru Ogino , Satoshi Aoyama , Satoshi Shiokawa , Hiroyuki Mitsui , Hiroshi Aoki , Takashi Shimazu
发明人： Shigeru Ogino , Satoshi Aoyama , Satoshi Shiokawa , Hiroyuki Mitsui , Hiroshi Aoki , Takashi Shimazu
CPC分类号： C01B3/384 , C01B2203/0233 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/169 , H01M8/04089 , H01M8/0612 , H01M8/0687 , Y02P20/128
摘要： A control device 7 obtains a reformed carbon quantity C supplied to a reform reaction flow channel 21 from a supplied fuel quantity Qf and also obtains a reformed water quantity S supplied to the reform reaction flow channel 21 from a generated power quantity W. Further, it obtains a oxygen consumed quantity consumed through power generation in a fuel cell 3 from the generated power quantity W, a supplied oxygen quantity to be supplied to a cathode flow channel 33 from a supplied cathode gas quantity Qc, and a reformed oxygen quantity O to be supplied to the reform reaction flow channel 21 based on a difference between the supplied oxygen quantity and the consumed oxygen quantity. By correcting a reformed carbon quantity C (delivery of a fuel pump 51) in accordance with the reformed oxygen quantity O, each of O/C and S/C is kept in a target value range.
摘要翻译： 控制装置7从供给燃料量Qf获得供给改性反应流路21的重整碳量C，并且从发电量W获得供给改性反应流路21的重整水量S.此外， 从所产生的电力量W获得从燃料电池3的发电消耗的氧消耗量，从供给的阴极气体量Qc供给到阴极流路33的供给氧量，以及重整用氧量O 基于供给的氧量和消耗的氧量之间的差，供给至改质反应流路21。 通过根据重整氧气量O校正重整碳量C（燃料泵51的输送），O / C和S / C中的每一个都保持在目标值范围内。
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公开(公告)号：US20080145726A1
公开(公告)日：2008-06-19
申请号：US11883163
申请日：2006-03-08
申请人： Keisuke Nagasaka , Naoki Ito , Satoshi Iguchi , Satoshi Aoyama , Hiroshi Aoki , Takashi Shimazu , Hiroyuki Mitsui
发明人： Keisuke Nagasaka , Naoki Ito , Satoshi Iguchi , Satoshi Aoyama , Hiroshi Aoki , Takashi Shimazu , Hiroyuki Mitsui
IPC分类号： H01M8/18
CPC分类号： B60L11/1898 , B60L11/1892 , C01B3/46 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , H01M8/04007 , H01M8/0612 , Y02P20/128 , Y02T90/34
摘要： The present invention provides a hydrogen-generating apparatus comprising two catalytic reactors cyclically operating reforming and regeneration (combustion) mode, in which the reduction in reforming efficiency associated with an increase in switching frequency to the regeneration reaction can be suppressed, and generation of hydrogen by reforming can stably be performed. In the reforming reaction, a cathode offgas discharged from a hydrogen-separation-membrane fuel cell 30 having a hydrogen-permeating film is supplied to PSR reformers 10 and 20, in which the reforming reaction and the regeneration reaction are performed alternately.
摘要翻译： 本发明提供了一种氢发生装置，其包括循环运行的重整和再生（燃烧）模式的两个催化反应器，其中可以抑制与再生反应的开关频率的增加相关的重整效率的降低，以及通过 可以稳定地进行重整。 在重整反应中，从具有氢渗透膜的氢分离膜燃料电池30排出的阴极废气被供给到重整反应和再生反应交替进行的PSR重整器10和20中。
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公开(公告)号：US07132184B2
公开(公告)日：2006-11-07
申请号：US11229498
申请日：2005-09-20
申请人： Shigeru Ogino , Satoshi Aoyama , Hiroyuki Mitsui , Hiroshi Aoki , Takashi Shimazu , Satoshi Shiokawa
发明人： Shigeru Ogino , Satoshi Aoyama , Hiroyuki Mitsui , Hiroshi Aoki , Takashi Shimazu , Satoshi Shiokawa
IPC分类号： H03M8/18
CPC分类号： H01M8/0662 , H01M8/04014 , H01M8/04097 , H01M8/0618
摘要： The fuel cell system according to the present invention comprises a reformer 12 for receiving a hydrocarbon fuel supply and generating a hydrogen-containing reformed gas by making use of a reforming reaction; a fuel cell assembly 14 for generating power after causing an anode to receive the reformed gas and causing a cathode to receive an oxygen-containing cathode gas; cathode off-gas supply flow path 20 for supplying a cathode off-gas, which is discharged from the cathode, to the reformer 12; and bypass flow path 24 for bypassing the cathode and directly supplying the cathode gas to the reformer 12 at the time of system warm-up.
摘要翻译： 根据本发明的燃料电池系统包括用于接收烃燃料供应并通过利用重整反应产生含氢重整气体的重整器12; 用于在使阳极接收重整气体并使阴极接收含氧阴极气体之后发电的燃料电池组件14; 用于将从阴极排出的阴极废气供给到重整器12的阴极废气供给流路20; 旁路流路24绕过阴极，在系统预热时将阴极气体直接供给重整器12。
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公开(公告)号：US08382864B2
公开(公告)日：2013-02-26
申请号：US11883163
申请日：2006-03-08
申请人： Keisuke Nagasaka , Naoki Ito , Satoshi Iguchi , Satoshi Aoyama , Hiroshi Aoki , Takashi Shimazu , Hiroyuki Mitsui
发明人： Keisuke Nagasaka , Naoki Ito , Satoshi Iguchi , Satoshi Aoyama , Hiroshi Aoki , Takashi Shimazu , Hiroyuki Mitsui
IPC分类号： B01J8/00
CPC分类号： B60L11/1898 , B60L11/1892 , C01B3/46 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , H01M8/04007 , H01M8/0612 , Y02P20/128 , Y02T90/34
摘要： The present invention provides a hydrogen-generating apparatus in which the reduction in reforming efficiency associated with an increase in switching frequency to the regeneration reaction can be suppressed, and generation of hydrogen by reforming can stably be performed. In the reforming reaction, a cathode offgas discharged from a hydrogen-separation-membrane fuel cell 30 having a hydrogen-permeating film is supplied to PSR reformers 10 and 20, in which the reforming reaction and the regeneration reaction are performed alternately.
摘要翻译： 本发明提供一种氢发生装置，其中可以抑制与再生反应的开关频率的增加相关的重整效率的降低，并且可以稳定地进行通过重整产生的氢。 在重整反应中，从具有氢渗透膜的氢分离膜燃料电池30排出的阴极废气被供给到重整反应和再生反应交替进行的PSR重整器10和20中。
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公开(公告)号：US20090087696A1
公开(公告)日：2009-04-02
申请号：US11910373
申请日：2006-03-17
申请人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Satoshi Iguchi
发明人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Satoshi Iguchi
CPC分类号： H01M8/0612 , C01B3/38 , C01B3/46 , C01B2203/0227 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1082 , H01M8/04067 , H01M8/04097 , H01M8/04179 , H01M8/04373 , H01M8/04753 , H01M8/04761 , H01M8/04776 , H01M8/0668 , Y02P20/128
摘要： A hydrogen fuel feeding system of a fuel cell system that has: a switching device for switching a reactor, that can carry out a reforming process and a regeneration process, between alternate statuses of a first status of feeding a reactant to the reactor while exhausting a fuel gas and a second status of feeding a gas for regeneration to the reactor while exhausting a regeneration exhaust gas; and a control apparatus for switching the switching device so that residual reforming gas, which is still remaining in the reactor before switching, is combusted in an exhaust air processor and not exhausted as the residual reforming gas without treatment when switching from the first status to the second status.
摘要翻译： 一种燃料电池系统的氢燃料供给系统，其具有：用于切换反应器的切换装置，所述切换装置可以在排出反应物的第一状态下进行重整过程和再生过程 燃料气体，并且在排出再生废气的同时向反应器供给用于再生的气体的第二状态; 以及用于切换开关装置的控制装置，使得在切换之前仍然残留在反应器中的残留重整气体在废气处理器中燃烧并且在从第一状态切换到第一状态时不作为残留重整气体而被排出 第二个地位。
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公开(公告)号：US20070065688A1
公开(公告)日：2007-03-22
申请号：US11486011
申请日：2006-07-14
申请人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Shigeru Ogino , Satoshi Aoyama , Satoshi Shiokawa , Satoshi Iguchi , Kenji Kimura , Hiromichi Satou , Yasuhiro Izawa , Naoki Ito , Masahiko Iijima
发明人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Shigeru Ogino , Satoshi Aoyama , Satoshi Shiokawa , Satoshi Iguchi , Kenji Kimura , Hiromichi Satou , Yasuhiro Izawa , Naoki Ito , Masahiko Iijima
CPC分类号： H01M8/04097 , H01M8/04022 , H01M8/0612
摘要： The fuel cell system 1 has a reformer 2 and a fuel cell 3. The reformer 2 has a reforming reaction channel 21 that generates a hydrogen-containing reformed gas Ga and a heat exchange channel 22 for heating. The fuel cell 3 has an anode channel 32 to which the hydrogen-containing reformed gas Ga is supplied, a cathode channel 33 to which an oxygen-containing gas Gc is supplied, and an electrolyte 31 formed between them. The electrolyte 31 is a laminate of a hydrogen-separating metal layer 311 and a proton conductor layer 312. The fuel cell system 1 has a cathode offgas line 46 for feeding the cathode offgas Oc discharged from the cathode channel 33 to the reforming reaction channel 21.
摘要翻译： 燃料电池系统1具有重整器2和燃料电池3。 重整器2具有产生含氢重整气体Ga的重整反应通道21和用于加热的热交换通道22。 燃料电池3具有供给含氢重整气体Ga的阳极流路32，供给含氧气体Gc的阴极流路33和在它们之间形成的电解液31。 电解质31是氢分离金属层311和质子导体层312的叠层体。 燃料电池系统1具有阴极废气管线46，用于将从阴极通道33排出的阴极废气Oc供给到重整反应通道21。
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公开(公告)号：US07901819B2
公开(公告)日：2011-03-08
申请号：US11910373
申请日：2006-03-17
申请人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Satoshi Iguchi
发明人： Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui , Satoshi Iguchi
IPC分类号： H01M8/18
CPC分类号： H01M8/0612 , C01B3/38 , C01B3/46 , C01B2203/0227 , C01B2203/066 , C01B2203/0811 , C01B2203/0822 , C01B2203/0827 , C01B2203/1082 , H01M8/04067 , H01M8/04097 , H01M8/04179 , H01M8/04373 , H01M8/04753 , H01M8/04761 , H01M8/04776 , H01M8/0668 , Y02P20/128
摘要： A hydrogen fuel feeding system of a fuel cell system that has: a switching device for switching a reactor, that can carry out a reforming process and a regeneration process, between alternate statuses of a first status of feeding a reactant to the reactor while exhausting a fuel gas and a second status of feeding a gas for regeneration to the reactor while exhausting a regeneration exhaust gas; and a control apparatus for switching the switching device so that residual reforming gas, which is still remaining in the reactor before switching, is combusted in an exhaust air processor and not exhausted as the residual reforming gas without treatment when switching from the first status to the second status.
摘要翻译： 一种燃料电池系统的氢燃料供给系统，其具有：用于切换反应器的切换装置，所述切换装置可以在排出反应物的第一状态下进行重整过程和再生过程 燃料气体，并且在排出再生废气的同时向反应器供给用于再生的气体的第二状态; 以及用于切换开关装置的控制装置，使得在切换之前仍然残留在反应器中的残留重整气体在废气处理器中燃烧，并且在从第一状态切换到第一状态时不作为残留重整气体而被排出 第二个地位。
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10.发明授权公开(公告)号：US07666537B2
公开(公告)日：2010-02-23
申请号：US10588218
申请日：2005-02-17
申请人： Shigeru Ogino , Satoshi Aoyama , Yasuhiro Izawa , Satoshi Shiokawa , Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui
发明人： Shigeru Ogino , Satoshi Aoyama , Yasuhiro Izawa , Satoshi Shiokawa , Takashi Shimazu , Hiroshi Aoki , Hiroyuki Mitsui
CPC分类号： H01M8/04089 , H01M4/92 , H01M4/94 , H01M8/04007 , H01M8/0612 , H01M8/0662 , H01M8/1213
摘要： A technology for preventing degradation of a hydrogen permeable metal layer in a fuel cell 210 is provided. A fuel cell system 200 including a fuel cell 210 with an anode which has the hydrogen permeable metal layer comprises a fuel cell controller 230 for controlling the operation status of the fuel cell system 200, a temperature parameter acquisition section for acquiring a temperature parameter of the hydrogen permeable metal layer, and a hydrogen permeable metal layer degradation prevention section which reduces the hydrogen partial pressure in an anode channel 212 for supplying fuel gas to the anode. If a temperature of the hydrogen permeable metal layer represented by the temperature parameter deviates from a specified temperature range, the fuel cell controller 230 cause the hydrogen permeable metal layer degradation prevention section to operate for preventing degradation of the hydrogen permeable metal layer.
摘要翻译： 提供了用于防止燃料电池210中的氢可渗透金属层的劣化的技术。 包括具有氢可渗透金属层的具有阳极的燃料电池210的燃料电池系统200包括用于控制燃料电池系统200的运行状态的燃料电池控制器230，用于获取燃料电池系统200的温度参数的温度参数获取部 氢可渗透金属层和氢可渗透金属层降解防止部，其降低用于向阳极供给燃料气体的阳极通道212中的氢分压。 如果由温度参数表示的氢可渗透金属层的温度偏离规定的温度范围，则燃料电池控制器230使氢可渗透金属层降解防止部分操作以防止氢可渗透金属层的劣化。
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