摘要:
The present invention provides a redox flow battery including an ion-exchange membrane, a liquid inflow layer, an electrode, and a current collector plate so as to be stacked in this order. The electrode includes a plurality of electrode pieces which are disposed in parallel in a plane direction, a liquid supply passage for supplying an electrolytic solution to the liquid inflow layer is provided between the adjacent electrode pieces, and the electrolytic solution passes through the electrode from an ion-exchange membrane side surface of the electrode to a current collector plate side surface.
摘要:
A fuel reformer which can easily achieve high weight energy density and high volume energy density, and a method for producing the fuel reformer with ease and high efficiency as well as an electrode for electrochemical device, such as a fuel cell, and an electrochemical device are provided. The present invention is to feed hydrogen obtained from a fuel reformer having a catalyst layer containing Pt for taking out hydrogen from a liquid fuel, such as methanol, and a hydrogen permeable layer, such as a Pd thin film, which is impermeable to liquid and permeable to hydrogen to an electrochemical device such as a fuel cell, which comprises a negative electrode, a positive electrode and a proton conductive film sandwiched therebetween. The present invention provides a method of producing the hydrogen permeable layer in the reformer 1 by forming the hydrogen permeable layer and the catalyst layer on a base layer comprising Al or the like, and removing the base layer by dissolution.
摘要:
A metal/air electrochemical cell in one embodiment includes a negative electrode, a positive electrode, an oxygen supply, and a closed oxygen conducting membrane less than about 50 microns thick located between the oxygen supply and the positive electrode.
摘要:
A fuel cell 100 is characterized by including an electrolyte 30, and an electrolyte-strengthening member 10 that has a penetration portion 11 and strengthens the electrolyte. The electrolyte 30 has a high-electrical-current-density region of which electrical current density is higher than an average electrical current density of the electrolyte 30 and has a low-electrical-current-density region of which electrical current density is lower than the average electrical current density, at a face thereof on an opposite side of the electrolyte-strengthening substrate 100. An area where the penetration portion 11 faces with the high-electrical-current-density region is larger than that where the penetration portion 11 faces with the low-electrical-current-density region.
摘要:
A method of manufacturing a fuel cell includes thermally treating a hydrogen permeable membrane in a given temperature higher than an actual operating temperature of the fuel cell, and forming an electrolyte layer on the hydrogen permeable membrane subjected to the thermal treatment. The hydrogen permeable membrane is composed of a polycrystalline metal.
摘要:
The invention is directed to a method for producing Palladium alloy composite membranes that are useful in applications that involve the need to separate hydrogen from a gas mixture. The method includes providing a substrate for supporting a palladium alloy film, seeding the support surface with palladium crystallites to produce an activated surface, first plating, over the activated surface, a palladium film, second plating, over the palladium film, an alloying material other than silver, and annealing the porous substrate, palladium film, and alloying material so that there is intermetallic diffusion of the alloying material into the palladium film to produce a palladium alloy film over the porous substrate.
摘要:
The invention provides thin, hydrogen-permeable, sulfur-resistant membranes formed from palladium or palladium-alloy coatings on porous, ceramic or metal supports. Also disclosed are methods of making these membranes via sequential electroless plating techniques, wherein the method of making the membrane includes decomposing any organic ligands present on the substrate, reducing the palladium crystallites on the substrate to reduced palladium crystallites, depositing a film of palladium metal on the substrate and then depositing a second, gold film on the palladium film. These two metal films are then annealed at a temperature between about 200° C. and about 1200° C. to form a sulfur-resistant, composite PdAu alloy membrane.
摘要:
An automotive or other power system including a flow cell, in which the stack that provides power is readily isolated from the storage vessels holding the cathode slurry and anode slurry (alternatively called “fuel”) is described. A method of use is also provided, in which the “fuel” tanks are removable and are separately charged in a charging station, and the charged fuel, plus tanks, are placed back in the vehicle or other power system, allowing fast refueling. The technology also provides a charging system in which discharged fuel is charged. The charged fuel can be placed into storage tanks at the power source or returned to the vehicle. In some embodiments, the charged fuel in the storage tanks can be used at a later date. The charged fuel can be transported or stored for use in a different place or time.
摘要:
An electrolyte layer (121) and a hydrogen-permeable metal layer (122) are fitted in a fitting portion (131) of a low thermal expansion member (130), and a cathode electrode (110) is provided on the electrolyte layer (121). Gas separators (100, 150) are provided such that a low thermal expansion member (130) is held between the gas separators (100, 150). Since the low thermal expansion member (130) is made of metal which has a thermal expansion coefficient lower than that of the hydrogen-permeable metal layer (122), thermal expansion of the hydrogen-permeable metal layer (122) can be suppressed. Accordingly, it is possible to reduce shear stress applied to an interface between the electrolyte layer (121) and the hydrogen-permeable metal layer (122) due to the thermal expansion. It is possible to suppress separation of the electrolyte layer (121) from the hydrogen-permeable metal layer (122) and occurrence of a crack in the electrolyte layer (121).
摘要:
A method of manufacturing a hydrogen separation membrane with a carrier is characterized by including a first step of providing, between the hydrogen separation membrane and the carrier that supports the hydrogen separation membrane, a low-hardness metal membrane having a hardness that is lower than the hardness of the hydrogen separation membrane, and a second step of joining the hydrogen separation membrane, the low-hardness metal membrane, and the carrier by a cold joining method. In this case, it is possible to suppress the deformation of the hydrogen separation membrane, the low-hardness metal membrane, and the carrier and, as a result, it is possible to prevent damaging of the hydrogen separation membrane. The adhesion of the contact between the hydrogen separation membrane and the carrier is also improved. The result is that it is not necessary to increase the severity of the cold joining conditions.