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    Thermally stabilized butadiene resins containing a hindered phenolic acrylate or methacrylate
    7.
    发明授权
    Thermally stabilized butadiene resins containing a hindered phenolic acrylate or methacrylate 失效
    含有受阻酚丙烯酸酯或甲基丙烯酸酯的热稳定丁二烯树脂

    公开(公告)号：US4774274A

    公开(公告)日：1988-09-27

    申请号：US64461

    申请日：1987-06-22

    申请人： Takeshi Takata ,  Shin-ichi Yachigo ,  Tatsuo Kaneoya ,  Haruki Okamura ,  Yukoh Takahashi

    发明人： Takeshi Takata ,  Shin-ichi Yachigo ,  Tatsuo Kaneoya ,  Haruki Okamura ,  Yukoh Takahashi

    IPC分类号： C08K5/134 ,  C08K5/10

    CPC分类号： C08K5/134

    摘要： A process for producing a bisphenol compound useful as deterioration preventor capable of stabilizing organic substances against the decompositions caused by heat, light and oxygen, represented by the following general formula: ##STR1## wherein R.sub.1 represents alkyl group having 1 to 3 carbon atoms, alkenyl group having 2 to 4 carbon atoms, phenyl group or 2-phenylethenyl group; R.sub.2 represents alkyl group having 1 to 5 carbon atoms, or cyclohexyl group; R.sub.3 represents alkyl group having 1 to 9 carbon atoms, cyclohexyl group or phenyl group; and R.sub.4 represents alkyl group having 1 to 11 carbon atoms or phenyl group, which comprises reacting a carboxylic acid represented by the following general formula: ##STR2## wherein R.sub.1 is as defined above, with a bisphenol compound represented by the following general formula: ##STR3## wherein R.sub.2, R.sub.3 and R.sub.4 are as defined above, by the use of a halogenating agent in the presence of a dehydrohalogenating agent, as well as butadiene polymer compositions containing said bisphenol compounds.

    摘要翻译： 一种生产双酚化合物的方法，该双酚化合物可用作能够稳定有机物质以抵抗由热，光和氧引起的分解引起的降解防止剂，由以下通式表示：其中R 1表示具有1至3个碳原子的烷基，烯基 具有2至4个碳原子的基团，苯基或2-苯基乙烯基; R2表示具有1至5个碳原子的烷基或环己基; R3表示具有1至9个碳原子的烷基，环己基或苯基; R 4表示具有1〜11个碳原子的烷基或苯基，其包括使由以下通式表示的羧酸与下述通式表示的双酚化合物反应：其中R 1如上定义。 其中R2，R3和R4如上定义，在脱卤化氢剂存在下使用卤化剂，以及含有所述双酚化合物的丁二烯聚合物组合物。

    Stabilizers for synthetic resins
    8.
    发明授权
    Stabilizers for synthetic resins 失效
    合成树脂稳定剂

    公开(公告)号：US4507417A

    公开(公告)日：1985-03-26

    申请号：US542518

    申请日：1983-10-17

    申请人： Tamaki Ishii ,  Shinichi Yachigo ,  Yukoh Takahashi

    发明人： Tamaki Ishii ,  Shinichi Yachigo ,  Yukoh Takahashi

    IPC分类号： C08L23/00 ,  C08K5/00 ,  C08K5/34 ,  C08K5/3477 ,  C08K5/36 ,  C08K5/372 ,  C08K5/378 ,  C08L7/00 ,  C08L21/00 ,  C08L51/00 ,  C08L51/02 ,  C08L77/00 ,  C08L101/00

    CPC分类号： C08K5/378 ,  C08K5/3477 ,  C08K5/372

    摘要： A novel stabilizing mixture composed of 1 1,3,5-tris 2-[3-(3-t-butyl-4-hydroxy-5-methyl-phenyl)-propionyloxyl] ethyl isocyanuric acid (I) and at least one sulfur-containing compound (II) selected from compounds represented by the general formulas (II-1) and (II-2): ##STR1## wherein R.sub.1 is an alkyl group having 4 to 20 carbon atoms, and ##STR2## wherein R.sub.2 is an alkyl group having 3 to 18 carbon atoms, and R.sub.3 and R.sub.4 each independently is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms, is useful as a stabilizer for synthetic resins.

    摘要翻译： 由1,3,5-三2- [3-（3-叔丁基-4-羟基-5-甲基 - 苯基） - 丙酰氧基]乙基异氰脲酸（I）和至少一种硫 （II-1）和（II-2）表示的化合物：其中R 1是具有4至20个碳原子的烷基和（II-2）其中R2是具有3至18个碳原子的烷基，R3和R4各自独立地是氢原子或具有1至6个碳原子的烷基，可用作合成树脂的稳定剂。

    Phosphorus-containing compounds, their production and their use as antioxidants
    9.
    发明授权
    Phosphorus-containing compounds, their production and their use as antioxidants 失效
    含磷化合物，其生产及其作为抗氧化剂的用途

    公开(公告)号：US4539355A

    公开(公告)日：1985-09-03

    申请号：US504782

    申请日：1983-06-16

    申请人： Yukoh Takahashi ,  Shinichi Yachigo ,  Tamaki Ishii

    发明人： Yukoh Takahashi ,  Shinichi Yachigo ,  Tamaki Ishii

    IPC分类号： C07F9/40 ,  C08K5/5333 ,  C07F9/36 ,  C08K5/53

    CPC分类号： C08K5/5333 ,  C07F9/4006

    摘要： Phosphorus-containing compounds of the formula: ##STR1## wherein R.sup.1 and R.sup.2 are each a hydrogen atom or a lower alkyl group, and R.sup.3 is a lower alkyl or phenyl group. These compounds may be used as stabilizers against the action of heat, light and oxygen for organic substances and especially polyolefin resins. These phosphorus-containing compounds may be used in conjunction with other stabilizers such phenol-type and sulfur-containing antioxidants, especially in polyolefin resin compositions to produce a polyolefin resin composition having excellent resistance to light, heat and oxygen. The present invention also relates to a method of producing the compounds of the aforementioned formula by reacting ##STR2## with a disubstituted phosphonate of the formula ##STR3## wherein R.sup.1, R.sup.2 and R.sup.3 are as defined above.

    摘要翻译： 含有下式的化合物：其中R1和R2各自为氢原子或低级烷基，R3为低级烷基或苯基。 这些化合物可以用作抗热，轻和氧作用的有机物质，特别是聚烯烃树脂的稳定剂。 这些含磷化合物可以与其它稳定剂一起使用，例如苯酚型和含硫抗氧化剂，特别是在聚烯烃树脂组合物中，以制备具有优异的耐光，耐热和耐氧的聚烯烃树脂组合物。 本发明还涉及通过使下式（II）与式（III）的二取代膦酸酯反应制备上述化合物的方法，其中R 1，R 2和R 3如上所定义。