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公开(公告)号：US20100240522A1
公开(公告)日：2010-09-23
申请号：US12382737
申请日：2009-03-23
申请人： Tomoyuki Inui , Masayuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
发明人： Tomoyuki Inui , Masayuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
CPC分类号： B01J37/0201 , B01J21/16 , B01J23/652 , B01J23/89 , B01J23/8913 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J37/18 , C10G29/205 , C10G45/10 , C10G47/14
摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.
摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。
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公开(公告)号：US08785340B2
公开(公告)日：2014-07-22
申请号：US13278130
申请日：2011-10-20
申请人： Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed , Masayuki Inui
发明人： Tomoyuki Inui , Takuma Kimura , Mohammad Abdullah Al-Saleh , Halim Hamid Redhwi , Mohammad Ashraf Ali , Shakeel Ahmed
CPC分类号： B01J37/0201 , B01J21/16 , B01J23/652 , B01J23/89 , B01J23/8913 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J37/0205 , B01J37/18 , C10G29/205 , C10G45/10 , C10G47/14
摘要： The catalyst exhibiting hydrogen spillover effect relates to the composition of a catalyst exhibiting hydrogen spillover effect and to a process for preparing the catalyst. The catalyst has a reduced transition base metal of Group VIB or Group VIIIB, such as cobalt, nickel, molybdenum or tungsten, supported on a high porous carrier, such as saponite, the base metal being ion-exchanged with at least one precious metal of Group VIIIB. The process includes the steps of loading the base metal onto the support, reducing the base metal, preferably with H2 at 600° C., and thereafter ion-exchanging the precious metal with the base metal. Preferred examples of the catalyst include a saponite support loaded with about 10-20 wt % cobalt and about 0.1-1 wt % precious metal. The catalyst is optimized for reactions that occur in commercial processes at about 360-400° C., such as in hydrocracking.
摘要翻译： 表现出氢气溢出效应的催化剂涉及显示氢气溢出效应的催化剂的组成和制备催化剂的方法。 该催化剂具有负载在诸如皂石的高多孔载体上的VIB族或VIIIB族的钌基过渡金属，例如钴，镍，钼或钨，贱金属与至少一种贵金属离子交换 第VIIIB组。 该方法包括以下步骤：将贱金属加载到载体上，优选在600℃下用H 2还原贱金属，然后将贵金属与贱金属进行离子交换。 催化剂的优选实例包括负载有约10-20重量％钴和约0.1-1重量％贵金属的皂石载体。 该催化剂针对在约360-400℃的商业过程中发生的反应进行优化，例如在加氢裂化中。
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公开(公告)号：US20110011728A1
公开(公告)日：2011-01-20
申请号：US12458551
申请日：2009-07-15
CPC分类号： C10G15/08 , B01J19/082 , B01J19/088 , B01J2219/0869 , B01J2219/0871 , B01J2219/0877 , B01J2219/0894 , G05D23/22
摘要： The system and method for conversion of molecular weights of fluids includes an elongate metallic pipe. A fluid is caused to flow through the pipe. A center electrode is mounted within the pipe coaxially with the pipe axis and the flow direction, the electrode being insulated from the pipe wall. The center electrode and the pipe wall are connected to the terminals of a voltage source to create an electric field extending radially between the center electrode and the pipe wall. A source of gamma radiation positioned either within the center electrode or external to the pipe directs gamma rays transverse to the direction of fluid flow. The combined radiation and electric field disrupts chemical bonds, creating ionization zones and resulting in the formation of lower-molecular-weight compounds. Optionally, a magnetic field may be superimposed in the direction of fluid flow.
摘要翻译： 用于转化流体分子量的系统和方法包括细长金属管。 使流体流过管道。 中心电极与管轴线和流动方向同轴地安装在管内，电极与管壁绝缘。 中心电极和管壁连接到电压源的端子，以产生在中心电极和管壁之间径向延伸的电场。 定位在中心电极内部或外部的伽马辐射源引导横向于流体流动方向的γ射线。 组合的辐射和电场破坏化学键，产生电离带并导致形成较低分子量的化合物。 可选地，可以在流体流动的方向上叠加磁场。
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公开(公告)号：US20110011727A1
公开(公告)日：2011-01-20
申请号：US12458550
申请日：2009-07-15
CPC分类号： C10G15/08 , B01J19/082 , B01J19/088 , B01J2219/0852 , B01J2219/0854 , B01J2219/0877 , B01J2219/0894 , B01J2219/1923
摘要： The system and method for conversion of molecular weights of fluids includes an elongate metallic pipe. A liquid, e.g., a hydrocarbon liquid, is caused to flow through the pipe. A center electrode is mounted within the pipe coaxially with the pipe axis and the flow direction, the electrode being insulated from the pipe wall. The center electrode and the pipe wall are connected to the terminals of a voltage source to create an electric field extending radially between the center electrode and the pipe wall. A source of gamma radiation positioned either within the center electrode or external to the pipe directs gamma rays transverse to the direction of fluid flow. The combined radiation and electric field disrupts carbon-sulfur, carbon-hydrogen, and carbon-carbon bonds, creating ionization zones and resulting in the formation of lower molecular weight compounds. Optionally, a magnetic field may be superimposed in the direction of fluid flow.
摘要翻译： 用于转化流体分子量的系统和方法包括细长金属管。 使液体，例如烃液体流过管道。 中心电极与管轴线和流动方向同轴地安装在管内，电极与管壁绝缘。 中心电极和管壁连接到电压源的端子，以产生在中心电极和管壁之间径向延伸的电场。 定位在中心电极内部或外部的伽马辐射源引导横向于流体流动方向的γ射线。 组合的辐射和电场破坏碳 - 硫，碳 - 氢和碳 - 碳键，产生电离带并导致形成较低分子量的化合物。 可选地，可以在流体流动的方向上叠加磁场。
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