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公开(公告)号：US07959795B2
公开(公告)日：2011-06-14
申请号：US12220170
申请日：2008-07-22
申请人： Teh C. Ho , Garland B. Brignac , Zhiguo Hou , Michael C. Kerby , Tahmid I. Mizan , William E. Lewis
发明人： Teh C. Ho , Garland B. Brignac , Zhiguo Hou , Michael C. Kerby , Tahmid I. Mizan , William E. Lewis
IPC分类号： C10G45/02
摘要： The distillate catalytic hydrodesulfurization of hydrocarbon fuels wherein the optimum hydrogen treat gas rate to maximize desulfurization is determined and introduced into the reaction zone to maintain a controlled amount of hydrogen at the surface of the catalyst during hydrodesulfurization.
摘要翻译： 碳氢燃料的馏出物催化加氢脱硫，其中确定最佳氢处理气体速率以最大化脱硫，并将其引入反应区，以在加氢脱硫期间在催化剂表面处保持受控量的氢。
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公开(公告)号：US20100018905A1
公开(公告)日：2010-01-28
申请号：US12220170
申请日：2008-07-22
申请人： Teh C. Ho , Garland B. Brignac , Zhiguo Hou , Michael C. Kerby , Tahmid I. Mizan , William E. Lewis
发明人： Teh C. Ho , Garland B. Brignac , Zhiguo Hou , Michael C. Kerby , Tahmid I. Mizan , William E. Lewis
IPC分类号： C10G45/02
摘要： The distillate catalytic hydrodesulfurization of hydrocarbon fuels wherein the optimum hydrogen treat gas rate to maximize desulfurization is determined and introduced into the reaction zone to maintain a controlled amount of hydrogen at the surface of the catalyst during hydrodesulfurization.
摘要翻译： 碳氢燃料的馏出物催化加氢脱硫，其中确定最佳氢处理气体速率以使脱硫最大化并引入反应区，以在加氢脱硫期间在催化剂表面处保持受控量的氢。
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公开(公告)号：US07244352B2
公开(公告)日：2007-07-17
申请号：US10359860
申请日：2003-02-07
申请人： Thomas R. Halbert , Craig A. McKnight , John P. Greeley , Bruce R. Cook , Garland B. Brignac , Mark A. Greaney , Robert C. Welch
发明人： Thomas R. Halbert , Craig A. McKnight , John P. Greeley , Bruce R. Cook , Garland B. Brignac , Mark A. Greaney , Robert C. Welch
CPC分类号： C10G67/0418 , C10G67/12 , C10L1/02
摘要： A process for producing a naphtha having a decreased amount of sulfur by selective hydroprocessing a petroleum feedstream comprising cracked naphtha to reduce its sulfur content with minimum loss of octane. The reduced sulfur naphtha stream contains mercaptan sulfur reversion products that are removed preferably by use of an aqueous base solution containing a catalytically effective amount of a phase transfer catalyst.
摘要翻译： 通过选择性加氢处理包含裂化石脑油的石油原料流来制造具有减少硫含量的石脑油的方法，以最小的辛烷值损失降低其硫含量。 还原硫石脑油流含有硫醇硫还原产物，其优选通过使用含有催化有效量的相转移催化剂的碱性水溶液来除去。
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4.发明授权公开(公告)号：US06231753B1
公开(公告)日：2001-05-15
申请号：US09448961
申请日：1999-11-24
申请人： Craig A. McKnight , Thomas R. Halbert , John P. Greeley , Garland B. Brignac , Richard A. Demmin , William E. Winter, Jr. , Bruce R. Cook
发明人： Craig A. McKnight , Thomas R. Halbert , John P. Greeley , Garland B. Brignac , Richard A. Demmin , William E. Winter, Jr. , Bruce R. Cook
IPC分类号： C10G45104
CPC分类号： C10G45/08 , B01J23/85 , B01J23/882 , B01J35/0006 , C10G65/04 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2400/02
摘要： Selective and deep desulfurization of a high sulfur content mogas naphtha, with reduced product mercaptans and olefin loss, is achieved by a two stage, vapor phase hydrodesulfurization process with interstage separation of at least 80 vol. % of the H2S formed in the first stage from the first stage, partially desulfurized naphtha vapor effluent fed into the second stage. At least 70 wt. % of the sulfur is removed in the first stage and at least 80 wt. % of the remaining sulfur is removed in the second stage, to achieve a total at least 95 wt. % feed desulfurization, with no more than a 60 vol. % feed olefin loss. The second stage temperature and space velocity are preferably greater than in the first. The hydrodesulfurization catalyst preferably contains a low metal loading of Co and Mo metal catalytic components on an alumina support.
摘要翻译： 通过两级气相加氢脱硫工艺实现了具有降低产物硫醇和烯烃损失的高硫含量的沼气石脑油的选择性和深度脱硫，其中级间分离至少为80体积％。 在第一阶段的第一阶段形成的H2S的％，部分脱硫的石脑油蒸汽流出物进料到第二阶段。 至少70wt。 在第一阶段中除去硫的百分比，并且至少80wt。 在第二阶段除去剩余硫的％，以达到总计至少95wt。 ％进料脱硫，不超过60体积。 ％进料烯烃损失。 第二级温度和空间速度优选大于第一级。 加氢脱硫催化剂优选在氧化铝载体上含有Co和Mo金属催化组分的低金属负载量。
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公开(公告)号：US07576023B2
公开(公告)日：2009-08-18
申请号：US11103002
申请日：2005-04-11
CPC分类号： B01J35/10 , B01J23/882 , B01J35/002 , B01J35/1061 , C10G45/02 , C10G45/04 , C10G45/06 , C10G45/08 , C10G45/10
摘要： Naphtha is selectively hydrodesulfurized in the presence of a sulfided, treated catalyst comprising at least a Group VIB metal catalytic component, to produce sulfur-reduced naphtha with reduced olefin loss due to saturation. The catalyst is treated with hydrogen, a selectively deactivating agent which deactivates its hydrogenation activity, and a protective agent which preserves its hydrodesulfurization activity during the treatment.
摘要翻译： 在包含至少一种VIB族金属催化组分的硫化处理过的催化剂的存在下，石脑油被选择性地加氢脱硫，以产生由于饱和而使烯烃损失降低的减硫石脑油。 催化剂用氢气去除其氢化活性的选择性钝化剂，以及在处理过程中保持其加氢脱硫活性的保护剂。
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公开(公告)号：US06589418B2
公开(公告)日：2003-07-08
申请号：US10043484
申请日：2002-01-10
IPC分类号： C10G4504
CPC分类号： B01J37/20 , B01J23/882 , C10G2400/02
摘要： An improved catalyst activation process for olefinic naphtha hydrodesulfurization. This process maintains the sulfur removal activity of the catalyst while reducing the olefin saturation activity.
摘要翻译： 改进的烯烃石脑油加氢脱硫催化剂活化方法。 该方法在降低烯烃饱和活性的同时维持催化剂的除硫活性。
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7.发明授权Activating hydroprocessing catalysts using carbon monoxide and use of catalysts for hydroprocessing 有权使用一氧化碳活化加氢处理催化剂，并使用催化剂进行加氢处理公开(公告)号：US07988848B2
公开(公告)日：2011-08-02
申请号：US11386603
申请日：2006-03-22
CPC分类号： B01J37/20 , B01J23/88 , B01J23/882 , B01J23/888 , B01J23/94 , B01J37/08 , B01J37/16 , C10G45/64 , C10G49/00 , C10G49/02 , C10G49/04 , C10G49/24 , C10G49/26 , C10G2300/4018 , C10G2300/703
摘要： This invention relates to a process for activating a hydroprocessing catalyst and the use of activated catalyst for hydroprocessing. More particularly, hydroprocessing catalysts are activated in the presence of carbon monoxide. The catalysts that have been activated by CO treatment have improved activity.
摘要翻译： 本发明涉及一种激活加氢处理催化剂的方法和使用活化催化剂进行加氢处理。 更具体地说，加氢处理催化剂在一氧化碳的存在下被活化。 通过CO处理活化的催化剂具有改善的活性。
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公开(公告)号：US07612012B2
公开(公告)日：2009-11-03
申请号：US11234668
申请日：2005-09-22
IPC分类号： B01J23/44
CPC分类号： C10G45/10 , B01J23/85 , B01J31/02 , B01J37/18 , B01J37/20 , C10G45/04 , C10G45/08 , C10G2400/02
摘要： The hydrogenation activity of a heteroatom removal catalyst, having activity for both heteroatom removal and hydrogenation, is selectively suppressed by a treatment which comprises contacting the catalyst with (i) hydrogen, (ii) a selectively deactivating agent that suppresses the catalyst's hydrogenation activity, and (iii) a protective agent, such as CO, that preserves and protects the heteroatom removal activity during the treatment. This may be achieved in a reactor while it is on-line and removing heteroatoms from a hydrocarbon feed.
摘要翻译： 通过包括使催化剂与（i）氢，（ii）抑制催化剂的氢化活性的选择性钝化剂接触的处理，选择性地抑制具有除去杂原子和加氢两者的活性的杂原子除去催化剂的加氢活性，以及 （iii）在处理期间保留并保护杂原子除去活性的保护剂，例如CO。 这可以在反应器中实现，同时其在线并且从烃进料中除去杂原子。
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9.发明授权Multi-stage hydrodesulfurization of cracked naphtha streams with a stacked bed reactor 有权用层叠反应器对裂化石脑油流进行多级加氢脱硫公开(公告)号：US07297251B2
公开(公告)日：2007-11-20
申请号：US10424332
申请日：2003-04-28
申请人： Edward S. Ellis , Richard A. Demmin , John P. Greeley , Gary B. McVicker , Bruce R. Cook , Garland B. Brignac , Thomas R. Halbert
发明人： Edward S. Ellis , Richard A. Demmin , John P. Greeley , Gary B. McVicker , Bruce R. Cook , Garland B. Brignac , Thomas R. Halbert
IPC分类号： C10G45/04
CPC分类号： B01J35/10 , B01J21/04 , B01J23/85 , B01J23/882 , B01J35/0006 , B01J35/1061 , C10G2400/02
摘要： A process for the selective hydrodesulfurization of naphtha streams containing a substantial amount of olefins and organically bound sulfur. The naphtha stream is selectively hydrodesulfurized by passing it through a first reaction zone containing a bed of a first hydrodesulfurization catalyst, then passing the resulting product stream through a second reaction zone containing a bed of a second hydrodesulfurization catalyst, which second hydrodesulfurization catalyst contains a lower level of catalytic metals than the first hydrodesulfurization catalyst.
摘要翻译： 用于选择性加氢脱硫含有大量烯烃和有机结合硫的石脑油流的方法。 通过使该石脑油流过含有第一加氢脱硫催化剂床的第一反应区，然后将所得产物流通过含有第二加氢脱硫催化剂床的第二反应区，该第二反应区含有较低的 催化金属的含量高于第一加氢脱硫催化剂。
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公开(公告)号：US07220352B2
公开(公告)日：2007-05-22
申请号：US10372864
申请日：2003-02-24
IPC分类号： G10G45/02
CPC分类号： C10G45/02 , C10G2400/02
摘要： A process for the selective hydrodesulfurization of naphtha streams containing sulfur and olefins. A substantially olefins-free naphtha stream is blended with an olefins/sulfur-containing naphtha stream and hydrodesulfurized resulting in the substantial removal of sulfur without excessive olefin saturation.
摘要翻译： 含有硫和烯烃的石脑油流的选择性加氢脱硫的方法。 将基本上不含烯烃的石脑油流与烯烃/含硫石脑油流混合并进行加氢脱硫，从而实质上除去硫而没有过度的烯烃饱和。
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