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公开(公告)号：US20110171465A1
公开(公告)日：2011-07-14
申请号：US13069447
申请日：2011-03-23
申请人： Teruhiko YASUDA , Hitoshi Shimoma , Hisashi Sato
发明人： Teruhiko YASUDA , Hitoshi Shimoma , Hisashi Sato
IPC分类号： B32B27/08
CPC分类号： C08G18/718 , B32B7/12 , B32B27/36 , B32B2405/00 , B32B2457/14 , C08G18/10 , C08G18/42 , C08G18/44 , C08G18/4825 , C08G18/4866 , C08G18/755 , C08G63/695 , C08G63/91 , C08G64/0266 , C08G64/42 , C08G65/336 , C09J7/22 , C09J7/35 , C09J167/00 , C09J169/00 , C09J171/02 , C09J175/04 , C09J2205/114 , C09J2467/00 , C09J2469/00 , C09J2471/00 , C09J2483/00 , Y10T428/2852 , Y10T428/2896 , C08G18/289
摘要： To provide an adhesive laminate with which an adhesive deposit does not result even when a polyester-type substrate layer is used.An adhesive laminate comprising a polyester-type substrate layer and an adherence substance layer, wherein one surface of the polyester-type substrate layer is a treated surface subjected to adhesion-facilitating treatment, the adherence substance layer is in contact with the treated surface, and the adherence substance layer is a layer obtained by curing a curable composition containing the following silyl group-containing polymer (S). The silyl group-containing polymer (S) is a silyl group-containing polymer having a polyether chain, a polyester chain and/or a polycarbonate chain in its main chain and having a hydrolyzable silyl group at its molecular terminal.
摘要翻译： 为了提供即使当使用聚酯型基材层时也不会产生粘合剂沉积的粘合剂层压体。 一种粘合剂层压体，其包含聚酯型基材层和粘附物质层，其中所述聚酯型基材层的一个表面是经过易粘合处理的处理表面，所述粘附物质层与所处理的表面接触， 粘附物质层是通过固化含有以下含甲硅烷基的聚合物（S）的固化性组合物而得到的层。 含甲硅烷基的聚合物（S）是其主链中具有聚醚链，聚酯链和/或聚碳酸酯链的含甲硅烷基的聚合物，其分子末端具有可水解的甲硅烷基。
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公开(公告)号：US20110111222A1
公开(公告)日：2011-05-12
申请号：US13005639
申请日：2011-01-13
申请人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
发明人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
CPC分类号： C09J167/00 , C08G65/336 , C09J7/38 , C09J171/02 , C09J201/10 , C09J2467/00 , C09J2471/00 , Y10T428/2852
摘要： To provide an adherence substance which has a low viscosity and good coatability, can be made solvent free, is less likely to undergo an increase in the adhesive strength with time and has good adhesion to an adherend while the adhesive strength is low, is excellent in removability and has a good wettability.An adherence substance which is obtainable by curing a curable composition comprising a silyl group-containing polymer (S) represented by the formula (1) and which has a peel adhesive strength of at most 8 N/25 mm: in the formula (1), R1 represents a t-valent residue derived from a (mono)polyol; Q represents a bivalent group formed by a reaction of a terminal group selected from a hydroxy group, an amino group, an isocyanate group, an allyl group, an acryloyl group and a methacryloyl group, with a specific silyl compound; R3 represents a monovalent organic group; X represents a hydroxy group or a hydrolyzable group; Y represents a bivalent group containing an ester linkage or a bivalent group containing an ether linkage; a represents an integer of from 1 to 3; r represents an integer of from 1 to 1,000; and t represents an integer of from 1 to 8.
摘要翻译： 为了提供具有低粘度和良好涂布性的粘附物质，可以制成无溶剂，不太可能随着时间而增加粘合强度，并且在粘合强度低的同时对被粘物具有良好的粘附性，优异的 可去除性好，润湿性好。 通过使式（1）中含有由式（1）表示的含有甲硅烷基的聚合物（S），剥离粘合强度为8N / 25mm以下的固化性组合物固化而得到的粘附物质， ，R1表示衍生自（单）多元醇的t价残基; Q表示通过选自羟基，氨基，异氰酸酯基，烯丙基，丙烯酰基和甲基丙烯酰基的末端基与特定甲硅烷基化合物的反应形成的二价基团; R3表示一价有机基团; X表示羟基或可水解基团; Y表示含有酯键的二价基团或含有醚键的二价基团; a表示1〜3的整数， r表示1〜1000的整数， t表示1〜8的整数。
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公开(公告)号：US08648162B2
公开(公告)日：2014-02-11
申请号：US13038573
申请日：2011-03-02
申请人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
发明人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
IPC分类号： C08G18/38 , C08G18/10 , C08L75/04 , C09J175/00 , C09J175/04
CPC分类号： C09J175/08 , C08G18/10 , C08G18/4866 , C08G18/755 , C08G18/7621 , C08G2170/40 , C09J7/38 , C09J2475/00 , Y10T428/2848 , Y10T428/2896 , C08G18/289 , C08G18/718
摘要： To provide an adherence substance which has a low viscosity and good coatability, can be made solvent free, has a low adhesive strength, of which increase with time is small, has good adhesion to a substrate, has excellent adhesion to an adherend and excellent removability, and has a good wettability. An adherence substance which is obtained by curing a curable composition comprising a silyl group-containing polymer (S) obtained by introducing a hydrolyzable silyl group to a molecular terminal of a polyurethane prepolymer obtained by reacting a polyol compound with a polyisocyanate compound, and which has a peel adhesive strength of at most 8N/25 mm.
摘要翻译： 为了提供具有低粘度和良好涂布性的粘附物质，可以无溶剂，粘合强度低，随着时间的推移而增加，对基材具有良好的粘合性，对被粘物具有优异的粘附性和优异的可除去性 ，并具有良好的润湿性。 通过使包含通过使多羟基化合物与多异氰酸酯化合物反应得到的聚氨酯预聚物的分子末端引入水解性甲硅烷基而得到的含有甲硅烷基的聚合物（S）的固化性组合物固化而获得的粘附物质， 剥离粘合强度最大为8N / 25mm。
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公开(公告)号：US20110151250A1
公开(公告)日：2011-06-23
申请号：US13038573
申请日：2011-03-02
申请人： Teruhiko YASUDA , Hitoshi Shimoma , Hisashi Sato
发明人： Teruhiko YASUDA , Hitoshi Shimoma , Hisashi Sato
IPC分类号： B32B7/12 , C09J7/02 , C09J175/04 , C09J175/08 , C09J183/00
CPC分类号： C09J175/08 , C08G18/10 , C08G18/4866 , C08G18/755 , C08G18/7621 , C08G2170/40 , C09J7/38 , C09J2475/00 , Y10T428/2848 , Y10T428/2896 , C08G18/289 , C08G18/718
摘要： To provide an adherence substance which has a low viscosity and good coatability, can be made solvent free, has a low adhesive strength, of which increase with time is small, has good adhesion to a substrate, has excellent adhesion to an adherend and excellent removability, and has a good wettability.An adherence substance which is obtained by curing a curable composition comprising a silyl group-containing polymer (S) obtained by introducing a hydrolyzable silyl group to a molecular terminal of a polyurethane prepolymer obtained by reacting a polyol compound with a polyisocyanate compound, and which has a peel adhesive strength of at most 8N/25 mm.
摘要翻译： 为了提供具有低粘度和良好涂布性的粘附物质，可以无溶剂，粘合强度低，随着时间的推移而增加，对基材具有良好的粘合性，对被粘物具有优异的粘附性和优异的可除去性 ，并具有良好的润湿性。 通过使包含通过使多羟基化合物与多异氰酸酯化合物反应得到的聚氨酯预聚物的分子末端引入水解性甲硅烷基而得到的含有甲硅烷基的聚合物（S）的固化性组合物固化而获得的粘附物质， 剥离粘合强度最大为8N / 25mm。
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公开(公告)号：US20100015443A1
公开(公告)日：2010-01-21
申请号：US12571480
申请日：2009-10-01
申请人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
发明人： Teruhiko Yasuda , Hitoshi Shimoma , Hisashi Sato
CPC分类号： C09J183/08 , C08G65/2609 , C08G65/2663 , C08G65/33351 , C08G65/336 , C08L2205/05 , C09J7/38 , C09J171/02 , C09J2483/00 , H01L21/6835 , H01L2221/6834 , Y10T428/2896
摘要： To provide an adherence substance which has a low viscosity and good coatability, can be made solvent free, has good adhesion to an adherend and at the same time has excellent removability, can suppress peel electrostatic charge and is excellent in high speed peeling performance.An adherence substance which is obtainable by curing a curable composition comprising a silyl group-containing polymer (S) represented by the following formula (1): in the formula (1), R1 represents a t-valent residue obtained by removing all hydroxy groups from a compound having t pieces of hydroxy groups in the molecule; R2 represents a bivalent organic group; R3 represents a monovalent organic group having from 1 to 20 carbon atoms; X is a hydroxy group or a hydrolyzable group; Y represents a bivalent group represented by the following formula (A) or a bivalent group represented by the following formula (B); a represents an integer of from 1 to 3; r represents an integer of from 1 to 1,000; t represents an integer of from 1 to 8; in the formula (A), R4 represents an alkylene group having from 2 to 8 carbon atoms; and in the formula (B), R5 represents an alkylene group having from 2 to 4 carbon atoms.
摘要翻译： 为了提供具有低粘度和良好涂布性的粘附物质，可以无溶剂，对被粘物具有良好的粘附性，同时具有优异的可除去性，可以抑制剥离静电荷，并且具有优异的高速剥离性能。 通过固化由下述式（1）表示的含甲硅烷基的聚合物（S）的固化性组合物可以得到的粘附物质：在式（1）中，R 1表示通过除去所有羟基得到的t价残基 分子中具有t个羟基的化合物; R2表示二价有机基团; R3表示碳原子数1〜20的1价有机基团。 X是羟基或可水解基团; Y表示由下式（A）表示的二价基团或由下式（B）表示的二价基团。 a表示1〜3的整数， r表示1〜1000的整数， t表示1〜8的整数， 在式（A）中，R 4表示具有2至8个碳原子的亚烷基; 在式（B）中，R 5表示碳原子数2〜4的亚烷基。
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公开(公告)号：US20120135241A1
公开(公告)日：2012-05-31
申请号：US13365599
申请日：2012-02-03
CPC分类号： B32B7/12 , G06F3/041 , G06F2203/04103 , Y10T428/31507 , Y10T428/31598 , Y10T428/31663
摘要： To provide a touch panel having a surface protective film laminated on a touch pad via an adherence substance layer having a low adhesive strength and excellent removability, having a good holding power, and having an adhesive strength with a small increase with time.A touch panel comprising a display module 1, a touch pad 2 laminated on a display screen of the display module 1 and a surface protective film 3 laminated on the viewer side of the touch pad 2, wherein between the surface protective film 3 and the touch pad 2, a first adherence substance layer 11 obtained by curing a first curable composition containing a silyl group-containing polymer (S) is interposed. The silyl group-containing polymer (S) is a polymer having a polyether chain, a polyester chain and/or a polycarbonate chain in its main chain and having a hydrolyzable silyl group at its molecular terminal.
摘要翻译： 为了提供一种具有层压在触摸板上的表面保护膜的触摸面板，其通过具有低粘合强度和优异的可移除性的粘附物质层，具有良好的保持力，并且具有随时间增加的粘合强度。 一种触摸面板，包括显示模块1，层叠在显示模块1的显示屏上的触摸板2和层压在触摸板2的观察者侧上的表面保护膜3，其中在表面保护膜3和触摸 衬垫2插入通过固化含有含甲硅烷基的聚合物（S）的第一可固化组合物获得的第一粘附物质层11。 含甲硅烷基的聚合物（S）是其主链中具有聚醚链，聚酯链和/或聚碳酸酯链的分子末端具有可水解甲硅烷基的聚合物。
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公开(公告)号：US20090012258A1
公开(公告)日：2009-01-08
申请号：US11730325
申请日：2007-03-30
申请人： Hitoshi Shimoma , Kota Hamasaki , Makito Nakamura , Hisashi Sato , Hiroshi Wada
发明人： Hitoshi Shimoma , Kota Hamasaki , Makito Nakamura , Hisashi Sato , Hiroshi Wada
IPC分类号： C08G18/18
CPC分类号： C08G18/3275 , C08G18/10 , C08G18/2805 , C08G18/2815 , C08G18/3206 , C08G18/3278 , C08G18/3281 , C08G18/42 , C08G18/44 , C08G18/48 , C08G18/4825 , C08G18/4833 , C08G18/4854 , C08G2170/40 , C09J175/02 , C09J175/04 , C09J175/06 , C09J175/08
摘要： A process for producing a urethane resin having a low viscosity and usable as a wide range of pressure-sensitive adhesives ranging from a strong-tack region to a slight-tack region, and a pressure-sensitive adhesive are provided. The process for producing a urethane resin comprises reacting a polyol with a polyisocyanate compound in such a proportion that isocyanate groups are in excess to thereby obtain an isocyanate-group-terminated prepolymer, thereafter reacting the isocyanate-group-terminated prepolymer with a chain extender, and reacting the resultant polymer with a chain terminator, wherein the chain extender has three or more functional groups reactive with an isocyanate group, wherein one of the functional groups is a primary amino group or a secondary amino group, another is a primary hydroxyl group, and the remaining functional group(s) are a secondary hydroxyl group or a tertiary hydroxyl group. The pressure-sensitive adhesive comprises the urethane resin obtained.
摘要翻译： 提供了一种制造具有低粘度且可用作范围广泛的压敏粘合剂范围从强粘性区域到轻微粘性区域的聚氨酯树脂的方法和压敏粘合剂。 制备聚氨酯树脂的方法包括使多异氰酸酯化合物以异氰酸酯基过量的比例反应，从而得到异氰酸酯基封端的预聚物，然后使异氰酸酯基封端的预聚物与扩链剂反应， 并使所得聚合物与链终止剂反应，其中扩链剂具有三个或更多个与异氰酸酯基反应的官能团，其中一个官能团是伯氨基或仲氨基，另一个是伯羟基， 剩余的官能团是仲羟基或叔羟基。 所述压敏粘合剂包括获得的聚氨酯树脂。
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公开(公告)号：US07834104B2
公开(公告)日：2010-11-16
申请号：US12189268
申请日：2008-08-11
CPC分类号： C09J175/04 , C08G18/10 , C08G18/3281 , C08G2170/40 , C08G18/3206 , C08G18/8022
摘要： An object of the invention is to provide a process for urethane resin production in which the molecular weight of the urethane resin can be easily controlled regardless of the kind of polyisocyanate compound and which can yield a urethane resin for use as a removable pressure-sensitive adhesive usable in extensive applications ranging from a strong-tack region to a slight-tack region. The process for urethane resin production of the invention is a process for producing a urethane resin which comprises reacting a polyol with a first polyisocyanate compound in such a proportion that isocyanate groups are present in excess to thereby obtain an isocyanate-group-terminated prepolymer, subsequently reacting the isocyanate-group-terminated prepolymer with a chain extender, and further reacting the resultant polymer with a chain terminator, wherein the chain extender comprises a polyfunctional compound (X) having three or more functional groups reactive with an isocyanate group, wherein two of the functional groups of the polyfunctional compound (X) are primary hydroxyl groups and the remaining functional group(s) is secondary hydroxyl or tertiary hydroxyl group(s).
摘要翻译： 本发明的目的是提供一种聚氨酯树脂生产方法，其中可以容易地控制聚氨酯树脂的分子量，而不管多异氰酸酯化合物的种类如何，并且可以产生用作可去除的压敏粘合剂的聚氨酯树脂 可用于从强粘性区域到轻微粘性区域的广泛应用。 本发明的聚氨酯树脂生产方法是一种制备聚氨酯树脂的方法，其包括使多元醇与第一多异氰酸酯化合物以过量存在的异氰酸酯基团的比例反应，随后得到异氰酸酯基封端的预聚物 使异氰酸酯基封端的预聚物与扩链剂反应，并进一步使所得聚合物与链终止剂反应，其中扩链剂包含具有三个或更多个与异氰酸酯基团反应的官能团的多官能化合物（X），其中两个 多官能化合物（X）的官能团是伯羟基，剩余的官能团是仲羟基或叔羟基。
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公开(公告)号：US20080312386A1
公开(公告)日：2008-12-18
申请号：US12189268
申请日：2008-08-11
CPC分类号： C09J175/04 , C08G18/10 , C08G18/3281 , C08G2170/40 , C08G18/3206 , C08G18/8022
摘要： An object of the invention is to provide a process for urethane resin production in which the molecular weight of the urethane resin can be easily controlled regardless of the kind of polyisocyanate compound and which can yield a urethane resin for use as a removable pressure-sensitive adhesive usable in extensive applications ranging from a strong-tack region to a slight-tack region. The process for urethane resin production of the invention is a process for producing a urethane resin which comprises reacting a polyol with a first polyisocyanate compound in such a proportion that isocyanate groups are present in excess to thereby obtain an isocyanate-group-terminated prepolymer, subsequently reacting the isocyanate-group-terminated prepolymer with a chain extender, and further reacting the resultant polymer with a chain terminator, wherein the chain extender comprises a polyfunctional compound (X) having three or more functional groups reactive with an isocyanate group, wherein two of the functional groups of the polyfunctional compound (X) are primary hydroxyl groups and the remaining functional group(s) is secondary hydroxyl or tertiary hydroxyl group(s).
摘要翻译： 本发明的目的是提供一种聚氨酯树脂生产方法，其中可以容易地控制聚氨酯树脂的分子量，而不管多异氰酸酯化合物的种类如何，并且可以产生用作可去除的压敏粘合剂的聚氨酯树脂 可用于从强粘性区域到轻微粘性区域的广泛应用。 本发明的聚氨酯树脂生产方法是一种制备聚氨酯树脂的方法，其包括使多元醇与第一多异氰酸酯化合物以过量存在的异氰酸酯基团的比例反应，随后得到异氰酸酯基封端的预聚物 使异氰酸酯基封端的预聚物与扩链剂反应，并进一步使所得聚合物与链终止剂反应，其中扩链剂包含具有三个或更多个与异氰酸酯基团反应的官能团的多官能化合物（X），其中两个 多官能化合物（X）的官能团是伯羟基，剩余的官能团是仲羟基或叔羟基。
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10.发明申请Thermosetting polyurethane elastomer composition, polyurethane elastomer and method for its production 审中-公开热固性聚氨酯弹性体组合物，聚氨酯弹性体及其生产方法公开(公告)号：US20050033007A1
公开(公告)日：2005-02-10
申请号：US10934507
申请日：2004-09-07
申请人： Joichi Saito , Hitoshi Shimoma
发明人： Joichi Saito , Hitoshi Shimoma
CPC分类号： C08G18/4804 , C08G18/10 , C08G18/4854 , C08G18/4866 , C08G18/6674
摘要： Provided is a polyurethane elastomer with a low hardness, a high strength and a high elongation. The polyurethane elastomer is obtained by reacting and curing an isocyanate-terminated prepolymer (i) obtained by reacting a polyoxyalkylene polyol having an average number of hydroxyl groups of over 2, a total degree of unsaturation of less than 0.05 meq/g and a number-average molecular weight of from 4000 to 20000, with a polyisocyanate compound, and a curing agent (ii) containing as curing components a polyoxytetramethylene polyol (a) and a chain extender (b) having two active-hydrogen-containing groups and having a number-average molecular weight of not more than 500.
摘要翻译： 提供了具有低硬度，高强度和高伸长率的聚氨酯弹性体。 通过使具有平均羟基数超过2的聚氧化烯多元醇，总不饱和度小于0.05meq / g的数均分子量的异氰酸酯封端的预聚物（i）反应并固化，得到聚氨酯弹性体， 平均分子量为4000〜20000的多异氰酸酯化合物和含有作为固化成分的固化剂（ii）的聚氧四亚甲基多元醇（a）和具有两个含活性氢基团的扩链剂（b） 平均分子量不超过500。
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