公开(公告)号：US20080004412A1

公开(公告)日：2008-01-03

申请号：US11667680

申请日：2005-11-16

申请人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tooru Tanaka ,  Tetsunori Shinozaki

发明人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tooru Tanaka ,  Tetsunori Shinozaki

IPC分类号： C08F10/14 ,  C07C2/02 ,  C08F4/16

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

摘要翻译： 本发明提供一种制备α-烯烃聚合物的方法，其包括在包含固体钛催化剂组分的烯烃聚合催化剂存在下聚合或共聚（a）C 3或更高级的α-烯烃 （I），其含有钛，镁，卤素和具有两个或多个醚键的特定结构的化合物和具有高催化活性的有机金属催化剂组分（II）。 在该方法中，特别是即使在（共）聚合（a）较高级烯烃中，也不需要脱矿质。 使用本发明的催化剂进行聚合得到的4-甲基-1-戊烯类聚合物的立构规整度，透明性，耐热性，脱模性优异，特别适用于脱模膜。

公开(公告)号：US20100324239A1

公开(公告)日：2010-12-23

申请号：US12851901

申请日：2010-08-06

申请人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

发明人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

IPC分类号： C08F4/50 ,  B01J31/26

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

摘要翻译： 本发明提供了一种制备α-烯烃聚合物的方法，其包括在包含含有钛，镁，镁的固体钛催化剂组分（I）的烯烃聚合催化剂的存在下聚合或共聚（a）C3或更高级的α-烯烃， 卤素和具有两个或更多个醚键的特定结构的化合物和具有高催化活性的有机金属催化剂组分（II）。 在该方法中，特别是即使在（共）聚合（a）较高级烯烃中，也不需要脱矿质。 使用本发明的催化剂进行聚合得到的4-甲基-1-戊烯类聚合物的立构规整度，透明性，耐热性，脱模性优异，特别适用于脱模膜。

公开(公告)号：US08629075B2

公开(公告)日：2014-01-14

申请号：US12851901

申请日：2010-08-06

申请人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

发明人： Tetsuhiro Matsumoto ,  Toshiyuki Tsutsui ,  Kisu Ro ,  Kourei Kuroiwa ,  Takushi Nagata ,  Atsushi Shibahara ,  Tatsuya Nakamura ,  Tetsunori Shinozaki

IPC分类号： C08F4/50 ,  B01J31/26

CPC分类号： C08F10/00 ,  C08F210/14 ,  C08F2500/26 ,  C08J5/18 ,  C08J2323/20 ,  C08F4/651 ,  C08F2500/15

摘要： The present invention provides a process for producing an α-olefin polymer comprising polymerizing or copolymerizing (a) C3 or higher α-olefin(s) in the presence of an olefin polymerization catalyst comprising solid titanium catalyst component (I) containing titanium, magnesium, halogen, and a compound with a specific structure having two or more ether linkages and organometallic catalyst component (II) with high catalytic activity. In this process, particularly even in (co)polymerizing (a) higher olefin(s), demineralization is unnecessary. A 4-methyl-1-pentene-based polymer obtained by polymerization using the catalyst of the present invention is excellent in tacticity, transparency, heat resistance, and releasability, and the polymer is particularly suitable for a release film.

摘要翻译： 本发明提供一种制备α-烯烃聚合物的方法，其包括在包含含有钛，镁，镁的固体钛催化剂组分（I）的烯烃聚合催化剂的存在下聚合或共聚（a）C3或更高级的α-烯烃， 卤素和具有两个或更多个醚键的特定结构的化合物和具有高催化活性的有机金属催化剂组分（II）。 在该方法中，特别是即使在（共）聚合（a）较高级烯烃中，也不需要脱矿质。 使用本发明的催化剂进行聚合得到的4-甲基-1-戊烯类聚合物的立构规整度，透明性，耐热性，脱模性优异，特别适用于脱模膜。

公开(公告)号：US20090069515A1

公开(公告)日：2009-03-12

申请号：US11795504

申请日：2006-01-19

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/76 ,  B01J31/04

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的固体钛催化剂组分（I）的特征在于它含有钛，镁，卤素和由下式（1）表示的环酯化合物（a）：其中n是5至10的整数 ; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个不是氢原子。 当使用该固体钛催化剂组分（I）时，可以生产具有宽分子量分布的烯烃聚合物。

公开(公告)号：US07649062B2

公开(公告)日：2010-01-19

申请号：US11878740

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/42

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： A solid titanium catalyst component (I) of the present invention is characterized in that it contains titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom. When using this solid titanium catalyst component (I), an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的固体钛催化剂组分（I）的特征在于它含有钛，镁，卤素和由下式（1）表示的环酯化合物（a）：其中n是5至10的整数 ; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个不是氢原子。 当使用该固体钛催化剂组分（I）时，可以生产具有宽分子量分布的烯烃聚合物。

公开(公告)号：US20080125555A1

公开(公告)日：2008-05-29

申请号：US11878739

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/72 ,  B01J31/12

CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is not a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R 2和R 3各自独立地为COOR 1或R 2，R 2和R 2中的至少一个为R ^{3 是COOR 1; 单键（不包括C a a 键和C a 环状骨架中R 3为R的情况）可以用双键代替; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 和多个R各自独立地为氢原子或取代基，但R中的至少一个不为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。}

公开(公告)号：US07875350B2

公开(公告)日：2011-01-25

申请号：US11878610

申请日：2007-07-25

申请人： Tetsuhiro Matsumoto ,  Tetsunori Shinozaki ,  Yasushi Nakayama ,  Kunihiko Mizumoto ,  Satoshi Akiyama ,  Toshiyuki Tsutsui

发明人： Tetsuhiro Matsumoto ,  Tetsunori Shinozaki ,  Yasushi Nakayama ,  Kunihiko Mizumoto ,  Satoshi Akiyama ,  Toshiyuki Tsutsui

IPC分类号： C08F4/10 ,  C08F4/12 ,  C08F4/16

CPC分类号： C08F110/02 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/651 ,  C08F2500/17 ,  C08F2500/24

摘要： Ethylene polymer particles having an intrinsic viscosity [η] of 5 dl/g to 30 dl/g, a degree of crystallinity of as high as 80% or more, and a specific shape on the surface of the particles. The ethylene polymer particles can be obtained by carrying out polymerization of olefins including ethylene using an olefin polymerization catalyst containing a solid titanium catalyst component including magnesium, halogen and titanium under specific conditions. The ethylene polymer particles obtained by a solid phase method, such as solid phase drawing molding, are capable of providing a molded article with high strength.

摘要翻译： 特性粘度[e egr]为5dl / g〜30dl / g，结晶度高达80％以上的乙烯聚合物粒子，以及粒子表面的特定形状。 乙烯聚合物颗粒可以通过在特定条件下使用包含镁，卤素和钛的固体钛催化剂组分的烯烃聚合催化剂进行包括乙烯在内的烯烃的聚合来获得。 通过固相法，例如固相拉伸成型得到的乙烯聚合物粒子能够提供高强度的成型品。

公开(公告)号：US20080090081A1

公开(公告)日：2008-04-17

申请号：US11878610

申请日：2007-07-25

申请人： Tetsuhiro Matsumoto ,  Tetsunori Shinozaki ,  Yasushi Nakayama ,  Kunihiko Mizumoto ,  Satoshi Akiyama ,  Toshiyuki Tsutsui

发明人： Tetsuhiro Matsumoto ,  Tetsunori Shinozaki ,  Yasushi Nakayama ,  Kunihiko Mizumoto ,  Satoshi Akiyama ,  Toshiyuki Tsutsui

IPC分类号： C08F10/02 ,  C08F4/42

CPC分类号： C08F110/02 ,  C08F10/00 ,  Y10T428/2982 ,  C08F4/651 ,  C08F2500/17 ,  C08F2500/24

摘要： The present invention provides ethylene polymer particles obtained by a solid phase method such as solid phase drawing molding and capable of providing a molded article with high strength. The ethylene polymer particles have an intrinsic viscosity [η] of 5 dl/g to 30 dl/g, a degree of crystallinity of as high as 80% or more, and a specific shape on the surface of the particles. The ethylene polymer particles can be obtained, for example, by carrying out polymerization of olefins including ethylene using an olefin polymerization catalyst containing a solid titanium catalyst component including magnesium, halogen and titanium under specific conditions.

摘要翻译： 本发明提供了通过固相拉伸成型等固相法得到的乙烯聚合物粒子，能够提供高强度的成型品。 乙烯聚合物颗粒的特性粘度η为5dl / g至30dl / g，结晶度高达80％以上，并且颗粒表面的特定形状。 乙烯聚合物颗粒可以例如通过在特定条件下使用包含含有镁，卤素和钛的固体钛催化剂组分的烯烃聚合催化剂进行包括乙烯在内的烯烃的聚合来获得。

公开(公告)号：US07888437B2

公开(公告)日：2011-02-15

申请号：US11795505

申请日：2006-01-19

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/42

CPC分类号： B01J31/0209 ,  B01J31/0212 ,  B01J31/128 ,  B01J31/143 ,  B01J31/38 ,  C08F10/00 ,  C08F110/06 ,  C08F110/08 ,  C08F110/14 ,  C08F210/06 ,  C08F4/6543 ,  C08F4/651 ,  C08F2500/04 ,  C08F2500/18 ,  C08F210/16 ,  C08F4/6465

摘要： The process for producing an olefin polymer according to the present invention is characterized in that it comprises polymerizing an olefin having 3 or more carbon atoms in the presence of a catalyst for olefin polymerization containing a solid titanium catalyst component (I) which contains titanium, magnesium, halogen, and a cyclic ester compound (a) specified by the following formula (1): wherein n is an integer of 5 to 10, R2 and R3 are each independently COOR1 or a hydrogen atom, and at least one of R2 and R3 is COOR1; and R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms, and a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is a hydrogen atom) in the cyclic backbone may be replaced with a double bond, and an organometallic compound catalyst component (II), at an internal pressure of the polymerization vessel which is 0.25 times or more as high as the saturation vapor pressure of the olefin at a polymerization temperature. According to this process, an olefin polymer having a broad molecular weight distribution can be prepared.

摘要翻译： 本发明的烯烃聚合物的制造方法的特征在于，在含有含有钛，镁的固体钛催化剂成分（I）的烯烃聚合催化剂存在下，聚合具有3个以上碳原子的烯烃 ，卤素和下述式（1）所示的环状酯化合物（a）：其中n为5〜10的整数，R2和R3各自独立地为COOR1或氢原子，R2和R3中的至少一个 是COOR1; 并且R 1各自独立地为具有1至20个碳原子的单价烃基，并且环状主链中的单键（不包括Ca-Ca键，在R3为氢原子的情况下为Ca-Cb键）可以被替换 （II），在聚合反应器的内压下，在聚合温度下为烯烃的饱和蒸气压的0.25倍以上。 根据该方法，可以制备具有宽分子量分布的烯烃聚合物。

公开(公告)号：US07888438B2

公开(公告)日：2011-02-15

申请号：US11878739

申请日：2007-07-26

申请人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

发明人： Kazuhisa Matsunaga ,  Hisao Hashida ,  Toshiyuki Tsutsui ,  Kunio Yamamoto ,  Atsushi Shibahara ,  Tetsunori Shinozaki

IPC分类号： C08F4/42

CPC分类号： C08F10/00 ,  C08F4/651 ,  C08F4/6543

摘要： A catalyst for olefin polymerization of the present invention includes a solid titanium catalyst component (I) including titanium, magnesium, halogen, and a cyclic ester compound (a) represented by the following formula (1): wherein n is an integer of 5 to 10; R2 and R3 are each independently COOR1 or R, and at least one of R2 and R3 is COOR1; a single bond (excluding Ca—Ca bonds, and a Ca—Cb bond in the case where R3 is R) in the cyclic backbone may be replaced with a double bond; a plurality of R1's are each independently a monovalent hydrocarbon group having 1 to 20 carbon atoms; and a plurality of R's are each independently a hydrogen atom or a substituent, but at least one of R's is a hydrogen atom, and an organometal compound catalyst component (II). When this catalyst for olefin polymerization is used, an olefin polymer having a broad molecular weight distribution can be produced.

摘要翻译： 本发明的烯烃聚合用催化剂包括由下述通式（1）表示的钛，镁，卤素和环状酯化合物（a）的固体钛催化剂成分（I）：其中n为5〜 10; R2和R3各自独立地是COOR1或R，R2和R3中的至少一个是COOR1; 环状骨架中的单键（不包括Ca-Ca键，在R3为R的情况下为Ca-Cb键）可以被双键取代; 多个R 1各自独立地为具有1〜20个碳原子的一价烃基; 并且多个R各自独立地为氢原子或取代基，但R中的至少一个为氢原子，和有机金属化合物催化剂成分（II）。 当使用用于烯烃聚合的催化剂时，可以生产具有宽分子量分布的烯烃聚合物。