公开(公告)号：US10147888B2

公开(公告)日：2018-12-04

申请号：US13983687

申请日：2012-02-06

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kumiko Hibino ,  Kazuki Nishimura ,  Kiyoshi Ikeda

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kumiko Hibino ,  Kazuki Nishimura ,  Kiyoshi Ikeda

IPC分类号： H01L51/50 ,  H01L51/00 ,  C07D403/04 ,  C07D403/14 ,  C09K11/06 ,  H05B33/14 ,  C07D471/04 ,  C07D209/60 ,  C07D209/86 ,  C09K11/02 ,  H01L51/52

摘要： A biscarbazole derivative having a specific group, which is represented by formula (1): and an organic electroluminescence device in which a plurality of organic thin-film layers including a light emitting layer are disposed between a cathode and an anode, and at least one of the organic thin-film layers include the biscarbazole derivative. The organic electroluminescence device exhibits high emission efficiency and has a long lifetime. In formula (1), each of A1 and A2 independently represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms; each of Y1 to Y16 independently represents C(R) or a nitrogen atom; each of R groups independently represents a hydrogen atom, etc.; and each of L1 and L2 independently represents a single bond, etc.; provided that at least one of A1, A2 and R represents a substituted or unsubstituted fluoranthenyl group, etc.

公开(公告)号：US08877352B2

公开(公告)日：2014-11-04

申请号：US13091071

申请日：2011-04-20

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07D403/00 ,  H01L51/00 ,  C09B57/00 ,  C07D403/14 ,  C07D209/82 ,  H05B33/20 ,  H01L51/50

CPC分类号： H01L51/0072 ,  C07D209/82 ,  C07D401/14 ,  C07D403/14 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  H01L51/0067 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H01L51/5092 ,  H01L2251/5384 ,  H05B33/20 ,  Y10S428/917

摘要： A biscarbazole derivative of the invention is represented by a formula (1A) or (1B) below. In the formula (1A) or (1B): A1 represents a substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; A2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; X1 and X2 each are a linking group; Y1 to Y4 each represent a substituent; p and q represent an integer of 1 to 4; and r and s represent an integer of 1 to 3.

摘要翻译： 本发明的双咔唑衍生物由下式（1A）或（1B）表示。 式（1A）或（1B）中，A 1表示取代或未取代的碳原子数为1〜30的含氮杂环基， A2表示取代或未取代的碳原子数为6〜30的芳香族烃基或取代或未取代的碳原子数为1〜30的含氮杂环基， X1和X2各自是连接基团; Y1至Y4各自表示取代基; p和q表示1〜4的整数。 并且r和s表示1〜3的整数。

公开(公告)号：US08865323B2

公开(公告)日：2014-10-21

申请号：US13372954

申请日：2012-02-14

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07D401/00 ,  C07D403/00 ,  H05B33/20 ,  C07D209/82 ,  H01L51/00 ,  C09B57/00 ,  C07D403/14 ,  H01L51/50

CPC分类号： H01L51/0072 ,  C07D209/82 ,  C07D401/14 ,  C07D403/14 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  H01L51/0067 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H01L51/5092 ,  H01L2251/5384 ,  H05B33/20 ,  Y10S428/917

摘要： A biscarbazole derivative of the invention is represented by a formula (1) below. In the formula (1): A1 represents a substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; A2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; X1 and X2 each are a linking group; Y1 to Y4 each represent a substituent; p and q represent an integer of 1 to 4; and r and s represent an integer of 1 to 3.

摘要翻译： 本发明的双咔唑衍生物由下式（1）表示。 式（1）中，A1表示取代或未取代的碳原子数1〜30的含氮杂环基， A2表示取代或未取代的碳原子数为6〜30的芳香族烃基或取代或未取代的碳原子数为1〜30的含氮杂环基， X1和X2各自是连接基团; Y1至Y4各自表示取代基; p和q表示1〜4的整数。 并且r和s表示1〜3的整数。

公开(公告)号：US08652654B2

公开(公告)日：2014-02-18

申请号：US13091036

申请日：2011-04-20

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

IPC分类号： H01L51/54 ,  C09K11/06 ,  C07D403/00

CPC分类号： H01L51/0072 ,  C07D209/82 ,  C07D401/14 ,  C07D403/14 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  H01L51/0067 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H01L51/5092 ,  H01L2251/5384 ,  H05B33/20 ,  Y10S428/917

摘要： A biscarbazole derivative of the invention is represented by a formula (1) below. In the formula (1): A1 represents a substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; A2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; X1 and X2 each are a linking group; Y1 to Y4 each represent a substituent; p and q represent an integer of 1 to 4; and r and s represent an integer of 1 to 3.

公开(公告)号：US20120223295A1

公开(公告)日：2012-09-06

申请号：US13366891

申请日：2012-02-06

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Hibino ,  Kazuki Nishimura ,  Takayasu Sado

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Hibino ,  Kazuki Nishimura ,  Takayasu Sado

IPC分类号： H01L51/54 ,  C07D405/14

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C07D403/14 ,  C07D405/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0036 ,  H01L51/0054 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H05B33/14

摘要： Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.

摘要翻译： 提供了具有高电流效率和长寿命的有机电致发光器件和用于实现器件的双咔唑衍生物。 双咔唑衍生物具有特定的取代基。 有机EL器件具有多个有机薄膜层，其包括在阴极和阳极之间的发光层，并且至少一层有机薄膜层含有双咔唑衍生物。

公开(公告)号：US20120199820A1

公开(公告)日：2012-08-09

申请号：US13500109

申请日：2011-08-05

申请人： Mitsunori Ito ,  Toshinari Ogiwara ,  Kazuki Nishimura ,  Tetsuya Inoue ,  Kumiko Hibino

发明人： Mitsunori Ito ,  Toshinari Ogiwara ,  Kazuki Nishimura ,  Tetsuya Inoue ,  Kumiko Hibino

IPC分类号： H01L51/54 ,  C07C211/61 ,  C07C211/58 ,  C07C211/54

CPC分类号： C07C211/54 ,  C07C211/58 ,  C07C211/61 ,  C07C2603/24 ,  C07C2603/26 ,  C07C2603/40 ,  C07C2603/52 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0059 ,  H01L51/006 ,  H01L51/5016 ,  H01L2251/5384 ,  H05B33/14

摘要： An organic electroluminescence device includes: an anode; a cathode being opposed to the anode; and an emitting layer being provided between the anode and the cathode. The emitting layer includes a host material and a phosphorescent dopant material. The host material includes a monoamine derivative represented by a formula-(1A) below. In the formula (1A), each of Ar1, Ar2 and Ar4 is a substituted or unsubstituted aryl group or heteroaryl group, Ar3 is a substituted or unsubstituted arylene group or heteroarylene group, n is an integer of 0 to 5, Ar3 may be mutually the same or different when n is 2 or more, and at least one of Ar1, Ar2, Ar3, and Ar4 is a group derived from a fused aromatic hydrocarbon skeleton having 3 or more rings.

摘要翻译： 有机电致发光器件包括：阳极; 与阳极相对的阴极; 并且在阳极和阴极之间设置发光层。 发光层包括主体材料和磷光掺杂剂材料。 主体材料包括由下式（1A）表示的单胺衍生物。 在式（1A）中，Ar 1，Ar 2和Ar 4各自为取代或未取代的芳基或杂芳基，Ar 3为取代或未取代的亚芳基或亚杂芳基，n为0〜5的整数，Ar 3可以相互 n为2以上时，相同或不同，Ar 1，Ar 2，Ar 3，Ar 4中的至少一个为来自具有3个以上环的稠合芳香烃骨架的基团。

公开(公告)号：US20140191225A1

公开(公告)日：2014-07-10

申请号：US14237887

申请日：2012-08-15

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kazuki Nishimura ,  Kumiko Hibino

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kazuki Nishimura ,  Kumiko Hibino

IPC分类号： H01L51/00

CPC分类号： H01L51/0067 ,  C07D403/14 ,  H01L51/0059 ,  H01L51/0061 ,  H01L51/0072 ,  H01L51/0085 ,  H01L2251/308

摘要： A biscarbazole derivative is represented by the following formula (1). A1 and A2 of the following formula (1) represent an aromatic hydrocarbon group having 6 to 30 ring carbon atoms or an aromatic heterocyclic group having 1 to 30 ring carbon atoms. However, at least one of A1 and A2 represents an aromatic heterocyclic group having 1 to 30 ring carbon atoms. Y1 to Y15 represent CR or a nitrogen atom. One of Y8 to Y11 is C (carbon atom) obtained by removing R from CR. The obtained C is bonded to L3. R each independently represents a hydrogen atom, an aromatic hydrocarbon group or the like. L1 to L3 represent a single bond or a divalent linking group. When L3 is a single bond and is bonded to Y11, L1 and L2 are divalent linking groups.

摘要翻译： 双咔唑衍生物由下式（1）表示。 下式（1）的A1和A2表示碳原子数为6〜30的芳香族烃基或环碳原子数为1〜30的芳香族杂环基。 然而，A1和A2中的至少一个表示具有1至30个环碳原子的芳族杂环基。 Y1〜Y15表示CR或氮原子。 Y8〜Y11中的一个是通过从CR中除去R而得到的C（碳原子）。 所得到的C键合到L3。 R各自独立地表示氢原子，芳香族烃基等。 L1至L3表示单键或二价连接基团。 当L3是单键并且键合到Y11时，L1和L2是二价连接基团。

公开(公告)号：US20140151647A1

公开(公告)日：2014-06-05

申请号：US13705686

申请日：2012-12-05

申请人： Yumiko MIZUKI ,  Mitsunori Ito ,  Tetsuya Inoue ,  Kumiko Hibino ,  Kazuki Nishimura

发明人： Yumiko MIZUKI ,  Mitsunori Ito ,  Tetsuya Inoue ,  Kumiko Hibino ,  Kazuki Nishimura

IPC分类号： H01L51/50

CPC分类号： H01L51/5028 ,  C07D209/86 ,  H01L51/0072 ,  H01L51/5012 ,  H01L51/5016 ,  H01L2251/5384 ,  H05B33/20

摘要： An organic electroluminescence device employing a specific biscarbazole derivative having a cyano group as a first host and a compound having both a carbazole structure and a nitrogen-containing aromatic heteroring as a second host. The organic electroluminescence device has a prolonged lifetime.

摘要翻译： 使用具有氰基作为第一主体的特定二咔唑衍生物和具有咔唑结构和含氮芳香族杂环的化合物作为第二主体的有机电致发光器件。 有机电致发光器件的寿命延长。

公开(公告)号：US08803134B2

公开(公告)日：2014-08-12

申请号：US13366891

申请日：2012-02-06

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Hibino ,  Kazuki Nishimura ,  Takayasu Sado

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Tomoki Kato ,  Kumiko Hibino ,  Kazuki Nishimura ,  Takayasu Sado

IPC分类号： H01L35/24 ,  H01L51/00 ,  H01L51/05 ,  H01L51/50 ,  B82Y10/00

CPC分类号： H01L51/0072 ,  B82Y10/00 ,  C07D403/14 ,  C07D405/14 ,  C09K11/025 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1011 ,  C09K2211/1014 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  C09K2211/1088 ,  C09K2211/1092 ,  H01L51/0036 ,  H01L51/0054 ,  H01L51/0067 ,  H01L51/0073 ,  H01L51/0541 ,  H01L51/0545 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5056 ,  H05B33/14

摘要： Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.

摘要翻译： 提供了具有高电流效率和长寿命的有机电致发光器件和用于实现器件的双咔唑衍生物。 双咔唑衍生物具有特定取代基。 有机EL器件具有多个有机薄膜层，其包括在阴极和阳极之间的发光层，并且至少一层有机薄膜层含有双咔唑衍生物。

公开(公告)号：US20120138912A1

公开(公告)日：2012-06-07

申请号：US13372954

申请日：2012-02-14

申请人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

发明人： Tetsuya Inoue ,  Mitsunori Ito ,  Kei Yoshida ,  Kumiko Hibino ,  Kazuki Nishimura ,  Toshinari Ogiwara ,  Kiyoshi Ikeda

IPC分类号： H01L51/54 ,  C07D401/14 ,  C07D403/14

CPC分类号： H01L51/0072 ,  C07D209/82 ,  C07D401/14 ,  C07D403/14 ,  C09B57/00 ,  C09K11/06 ,  C09K2211/1007 ,  C09K2211/1029 ,  C09K2211/1044 ,  C09K2211/1059 ,  H01L51/0067 ,  H01L51/5012 ,  H01L51/5016 ,  H01L51/5024 ,  H01L51/5076 ,  H01L51/5092 ,  H01L2251/5384 ,  H05B33/20 ,  Y10S428/917

摘要： A biscarbazole derivative of the invention is represented by a formula (1) below. In the formula (1): A1 represents a substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; A2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or substituted or unsubstituted nitrogen-containing heterocyclic group having 1 to 30 ring carbon atoms; X1 and X2 each are a linking group; Y1 to Y4 each represent a substituent; p and q represent an integer of 1 to 4; and r and s represent an integer of 1 to 3.

摘要翻译： 本发明的双咔唑衍生物由下式（1）表示。 式（1）中，A1表示取代或未取代的碳原子数1〜30的含氮杂环基， A2表示取代或未取代的碳原子数为6〜30的芳香族烃基或取代或未取代的碳原子数为1〜30的含氮杂环基， X1和X2各自是连接基团; Y1至Y4各自表示取代基; p和q表示1〜4的整数。 并且r和s表示1〜3的整数。