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1.发明授权Thermosetting mixtures of polyimide beta-amino crotonic acid derivative and polyamine which are stable on storage 失效聚酰亚胺β-氨基巴豆酸衍生物和多胺稳定储存的热固性混合物
公开(公告)号：US4161580A
公开(公告)日：1979-07-17
申请号：US879283
申请日：1978-02-21
申请人： Theobald Haug , Jurg Keifer , Peter Ruf , Andre Schmitter
发明人： Theobald Haug , Jurg Keifer , Peter Ruf , Andre Schmitter
CPC分类号： C08G73/121
摘要： Mixtures which can be cured to give moulded materials having technically valuable mechanical and dielectric properties, characterized that they contain(a) polyimides of maleic acid or citraconic acid,(b) derivatives of .beta.-amino-crotonic acid, and optionally(c) polyamines.
摘要翻译： 可以固化的混合物以得到具有技术上有价值的机械和介电性质的模塑材料，其特征在于它们含有（A）马来酸或柠檬酸的聚酰胺，（B）β-亚氨基酸的衍生物和选择性（C）聚氨酯 。
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2.发明授权Thermosetting mixtures which are stable on storage from polyimide and .beta . 失效在聚酰亚胺和{62-氨基 - 巴豆酸存储下稳定的热固性混合物
公开(公告)号：US4089845A
公开(公告)日：1978-05-16
申请号：US588529
申请日：1975-06-19
申请人： Theobald Haug , Jurg Kiefer , Peter Ruf , Andre Schmitter
发明人： Theobald Haug , Jurg Kiefer , Peter Ruf , Andre Schmitter
IPC分类号： C08F20/00 , C08F22/36 , C08F26/00 , C08F26/02 , C08G73/00 , C08G73/12 , C08J5/24 , C08J9/04 , C08G69/08
CPC分类号： C08G73/121
摘要： Mixtures which can be cured to give moulded materials having technically valuable mechanical and dielectric properties, characterized that they contain(a) polyimides of maleic acid or citraconic acid,(b) derivatives of .beta.-amino-crotonic acid, and optionally(c) polyamines.
摘要翻译： 可以固化的混合物以得到具有技术上有价值的机械和介电性质的模塑材料，其特征在于它们含有（A）马来酸或柠檬酸的聚酰胺，（B）β-亚氨基酸的衍生物和选择性（C）聚氨酯 。
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3.发明授权Process for the manufacture of polyaddition products containing imide groups by reaction of polymaleimides with polyhydric phenols using amine catalyst 失效通过使用胺催化剂与多元醇反应制备含有聚酰亚胺的聚酰亚胺的聚合产物的方法
公开(公告)号：US4038251A
公开(公告)日：1977-07-26
申请号：US534105
申请日：1974-12-18
申请人： Imre Forgo , Bruno Schreiber , Alfred Renner , Theobald Haug , Andre Schmitter
发明人： Imre Forgo , Bruno Schreiber , Alfred Renner , Theobald Haug , Andre Schmitter
CPC分类号： C08G73/127 , C08G73/12 , C08G73/125
摘要： According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polyhydric phenols in the presence of basic compounds. The preferred embodiment (A) relates to the use of catalysts as basic compounds. In particular, tertiary, secondary or mixed tertiary-secondary amines can be used. A further embodiment (B) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.The invention can be utilized particularly in the fields of surface protection, the electrical industry, laminating processes and the manufacture of foamed plastics, and in the building industry.
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4.发明授权Mixtures, containing polyimides, which can be converted to heat-resistant foamed plastics 失效含有聚合物的混合物，可转化为耐热泡沫塑料
公开(公告)号：US3950279A
公开(公告)日：1976-04-13
申请号：US540923
申请日：1975-01-14
申请人： Theobald Haug , Andre Schmitter
发明人： Theobald Haug , Andre Schmitter
IPC分类号： C08G73/00 , C08G73/06 , C08G73/12 , C08J9/04 , C08J9/06 , C08F22/40 , C08F30/02 , C08F122/40 , C08F222/40
CPC分类号： C08J9/06 , C08G73/12 , C08J2379/08
摘要： A mixture which can be converted to a heat-resistant foamed plastic and which contains a polyimide of an unsaturated dicarboxylic acid, an azomethine, a solid blowing agent, and optionally a polyamine. On warming, the mixture gives a foamed plastic of high heat resistance and good resistance to chemicals.
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5.发明授权Mixtures containing prepolymers, which can be converted to heat-resistant foamed plastics 失效含有预聚物的混合物，可以转化成耐热发泡塑料
公开(公告)号：US3947385A
公开(公告)日：1976-03-30
申请号：US540026
申请日：1975-01-10
申请人： Andre Schmitter , Jurg Kiefer , Theobald Haug
发明人： Andre Schmitter , Jurg Kiefer , Theobald Haug
IPC分类号： C08J9/04 , C08G73/12 , C08J9/06 , C08F22/40 , C08F30/02 , C08F122/40 , C08F222/40
CPC分类号： C08J9/06 , C08G73/121 , C08J2379/08 , Y10S521/909
摘要： A mixture which can be converted to a heat-resistant foamed plastic and which contains a solid blowing agent, a thermoplastic prepolymer of a polyimide of an unsaturated acid, an azomethine and a polyamine. On warming, the mixture gives a foamed plastic of high heat resistance and good resistance to chemicals.
摘要翻译： 可以转化为耐热泡沫塑料并含有固体发泡剂的混合物，不饱和酸的聚酰亚胺的热塑性预聚物，偶氮甲碱和多胺。 在加热时，混合物产生高耐热性和耐化学品的泡沫塑料。
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公开(公告)号：US4963300A
公开(公告)日：1990-10-16
申请号：US279747
申请日：1988-12-05
申请人： Kurt Meier , Theobald Haug , Wolfgang Scharf
发明人： Kurt Meier , Theobald Haug , Wolfgang Scharf
CPC分类号： C08G59/68 , H05K1/0326 , Y10T442/3577 , Y10T442/3585 , Y10T442/3691
摘要： A process for the preparation of a laminate including the steps(i) preparation of a layer by bringing into contact a fibrous substrate with a curable mixture containing an epoxy resin having on average at least two 1,2-epoxide groups per molecule or a mixture of these epoxy resins and a compound of the formula I ##STR1## or a mixture of these compounds, in which a and b are independent of one another 1 or 2, R.sup.1 is a .pi.-arene, R.sup.2 is a .pi.-arene or an indenyl- or cyclopentadienyl anion, X.sup.- is an anion [LQ.sub.m ].sup.- or an anion of a partly fluorinated or perfluorinated aliphatic or aromatic sulfonic acid, L is P, As or Sb, Q is fluorine or some of the Q substituents may also be hydroxyl groups, and m corresponds to a value which exceeds the valence of L by unity,(ii) preparation of a laminated sequence from at least two layered materials which are to be bonded together(iii) compression moulding of the said laminate sequence at elevated temperature.
摘要翻译： 一种用于制备层压体的方法，包括以下步骤：（i）通过使纤维基材与含有每分子平均具有至少两个1,2-环氧基的环氧树脂或混合物的可固化混合物接触来制备层 的这些环氧树脂和式I化合物[R1（FeIIR2）a] ab（+）ab。[X]（ - ）（I）或这些化合物的混合物，其中a和b彼此独立 1或2，R 1是一个仲芳基，R 2是一个或多个茚基 - 或环戊二烯阴离子，X-是阴离子[LQm] - 或部分氟化或全氟化的脂族或芳族磺酸的阴离子，L 是P，As或Sb，Q是氟或Q取代基中的一些也可以是羟基，m对应于超过L的化合价的一个数值，（ii）从至少两层分层 要结合在一起的材料（iii）在升高的温度下对所述层压体序列进行压缩成型。
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7.发明授权Heat-curable epoxy resin mixtures containing imide compounds and condensation products of phenols, amines and aldehydes or ketones 失效含有酰亚胺化合物和酚类，胺类和醛类或酮类的缩合产物的热固性环氧树脂混合物
公开(公告)号：US4552935A
公开(公告)日：1985-11-12
申请号：US568845
申请日：1984-01-06
IPC分类号： C08G59/00 , C08G14/06 , C08G59/40 , C08G59/56 , C08G59/62 , C08L63/00 , C08L61/00 , C08G8/32
CPC分类号： C08G59/623 , C08G14/06 , C08G59/4042 , C08L63/00
摘要： Heat-curable mixtures containing (a) epoxy compounds having on average more than one 1,2-epoxy group per molecule, (b) monoimides or polyimides of specific unsaturated dicarboxylic acids of the formula I ##STR1## wherein A is an x-valent aromatic or aliphatic radical, R.sup.1 is hydrogen or methyl, and x is 1, 2 or 3, and (c) products of condensing specific phenols, specific amines and aldehydes or ketones in an acid medium.The novel curable mixtures have a long shelf life and give rise to moulded materials which are highly resistant to chemicals and resistant to boiling water.
摘要翻译： 包含（a）每分子平均具有多于一个1,2-环氧基的环氧化合物的热固化性混合物，（b）式I的特定不饱和二羧酸的单酰亚胺或聚酰亚胺其中A是 x价芳族或脂族基，R1是氢或甲基，x是1,2或3，和（c）在酸性介质中缩合特异性酚，特定胺和醛或酮的产物。 新型可固化混合物具有长的保存期限，并产生耐化学品和耐沸水的成型材料。
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8.发明授权Flexible base materials, their preparation and their use for printed circuits 失效柔性基材，其制备方法及其在印刷电路中的应用
公开(公告)号：US4503285A
公开(公告)日：1985-03-05
申请号：US612996
申请日：1984-05-21
申请人： Roland Darms , Theobald Haug , Harry Beyeler
发明人： Roland Darms , Theobald Haug , Harry Beyeler
CPC分类号： H05K1/0346 , Y10T428/31681 , Y10T428/31721 , Y10T428/31725
摘要： Flexible base materials consisting of a metal foil and a film, firmly adhering thereto without an interlayer, of a polyamide/polyimide block copolymer of the formula I, or of a polyamide/polyimide copolymer prepared from a polyamide acid block of the formula IVa or Va and a dicarboxylic acid dichloride of the formula XI and a diamine of the formula XII.The individual symbols are defined in claim 1.The base materials according to the invention are suitable for the preparation of flexible printed circuits.
摘要翻译： 由金属箔和膜组成的柔性基材，其中没有中间层牢固地粘附在其上，具有式I的聚酰胺/聚酰亚胺嵌段共聚物或由式IVa或Va的聚酰胺酸嵌段制备的聚酰胺/聚酰亚胺共聚物 和式XI的二羧酸二氯化物和式XII的二胺。 各个符号在权利要求1中限定。根据本发明的基础材料适用于制备柔性印刷电路。
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9.发明授权Meat-curable mixture, which are stable on storage, of epoxide resin, 3-aminocrotonic acid derivatives and maleimide compound 失效对于环氧树脂，3-氨基巴豆酸衍生物和马来酰亚胺化合物，其在贮存时稳定的可固化混合物
公开(公告)号：US4424336A
公开(公告)日：1984-01-03
申请号：US418875
申请日：1982-09-16
申请人： Theobald Haug
发明人： Theobald Haug
CPC分类号： C08G59/52 , C08G59/4014 , C08G59/54
摘要： Heat-curable mixtures of one or more epoxide compounds, which, on average, have more than one epoxide group in the molecule, and one or more .beta.-aminocrotonic acid derivatives, such as .beta.-aminocrotononitrile, .beta.-aminocrotonamide or .beta.-aminocrotonic acid esters, and also, if desired, a polyamine or polycarboxylic acid anhydride or a malenimide. The novel curable mixtures are distinguished by outstanding stability on storage, can be processed easily and give moulded materials with good mechanical properties.
摘要翻译： 一种或多种环氧化合物的热固化混合物，其平均在分子中具有多于一个的环氧基团，以及一种或多种β-氨基巴豆酸衍生物，例如β-氨基巴豆腈，β-氨基巴豆酰胺或β-氨基巴豆酸 酯，如果需要，还可以使用多胺或多羧酸酐或马来酰亚胺。 新型可固化混合物的特征在于在储存时具有突出的稳定性，可以容易地加工，并赋予具有良好机械性能的模制材料。
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10.发明授权Heat-curable mixtures, which are stable on storage, of epoxide compounds .beta.-aminocrotonic acid derivatives and polyamine 失效环氧化合物β-氨基巴豆酸衍生物和多胺的储存稳定的可热固化混合物
公开(公告)号：US4360655A
公开(公告)日：1982-11-23
申请号：US268922
申请日：1981-06-01
申请人： Theobald Haug
发明人： Theobald Haug
CPC分类号： C08G59/52 , C08G59/4014 , C08G59/54
摘要： Heat-curable mixtures of one or more epoxide compounds, which, on average, have more than one epoxide group in the molecule, and one or more .beta.-aminocrotonic acid derivatives, such as .beta.-aminocrotononitrile, .beta.-aminocrotonamide or .beta.-aminocrotonic acid esters, and also, if desired, a polyamine or polycarboxylic acid anhydride or a maleimide. The novel curable mixtures are distinguished by outstanding stability on storage, can be processed easily and give moulded materials with good mechanical properties.
摘要翻译： 一种或多种环氧化合物的热固化混合物，其平均在分子中具有多于一个的环氧基团，以及一种或多种β-氨基巴豆酸衍生物，例如β-氨基巴豆腈，β-氨基巴豆酰胺或β-氨基巴豆酸 酯，如果需要，还可以使用聚胺或多元羧酸酐或马来酰亚胺。 新型可固化混合物的特征在于在储存时具有突出的稳定性，可以容易地加工，并赋予具有良好机械性能的模制材料。
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