摘要:
Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.
摘要:
Thermosetting reactive systems, comprising(a) at least one epoxide resin,(b) at least one isocyanate resin,(c) a reaction accelerator of the formula I ##STR1## in which R.sup.1 is --(CR.sup.4 R.sup.5).sub.n - with n=2-24, phenylene or naphthylene which is unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.1-C.sub.4 alkoxy or C.sub.3 -C.sub.8 dialkylaminoalkyl, or a radical of the formulae ##STR2## R.sup.2 and R.sup.3 independently of one another are C.sub.1-C.sub.12 alkyl, phenyl or naphthyl which are unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.1 -C.sub.4 alkoxy, or also C.sub.7 -C.sub.13 aralkyl, or in which R.sup.2 and R.sup.3, together with the N atom to which they are linked, form a 5-membered, 6-membered or 7-membered heterocyclic ring, and R.sup.4 and R.sup.5 independently of one another are hydrogen or C.sub.1 -C.sub.8 alkyl, and(d) if appropriate, a filler and/or further additives conventional in industry,have a long pot life and excellent heat-aging resistance.
摘要:
Heat-curable mixtures comprising(a) 10-90% by weight of at least one compound of formula I ##STR1## (b) 90-10% by weight of at least one compound of formula II ##STR2## and, based on the sum of (a)+(b), (c) 0-30% by weight of at least one compound which is able to react with component (b),in which formulae above n, m, R, R', R.sub.1, R.sub.2 and R.sub.3 are as define in claim 1, are suitable for the preparation of moulded articles such as prepregs and composites, coatings and bonds.
摘要翻译:(a)10-90重量%的至少一种式I化合物(I)(b)90-10重量%的至少一种式II化合物(II) ),并且基于(a)+(b),(c)0-30重量%的至少一种能够与组分(b)反应的化合物的总和,其中在n,m,R R 1,R 2,R 2和R 3如权利要求1中所定义,适用于制备模塑制品,如预浸料和复合材料,涂料和粘合剂。
摘要:
Polymers formed from anhydrides of the formula I ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or methyl.The novel polymers are suitable for use as curing agents for polyepoxide compounds.
摘要:
Imides of formula I ##STR1## wherein R.sup.1 and R.sup.2 are independently hydrogen or methyl, R.sup.3 is a direct bond, alkylene, oxaalkylene, cycloalkylene, arylene or arylene-T-arylene where T is methylene or isopropylidene, and R.sup.4 alkyl, cycloalkyl, aryl, benzyl or alkaryl are suitable as catalysts for the crosslinking of specific unsaturated imides.
摘要:
Novel tetraglycidyl ethers of the formula ##STR1## wherein X is a group ##STR2## R is hydrogen or methyl, and n is an integer from 2 to 4. The novel tetraglycidyl ethers can be used in curable mixtures, together with a curing agent for epoxide resins, in particular for the protection of surfaces.
摘要:
New bis-imides and tris-imides of the formula ##STR1## in which A and A' denote aromatic radicals which are optionally substituted or interrupted by an oxygen atom, an alkylene group or a sulphonyl group, Z denotes a radical of the formulae ##STR2## D denotes an oxygen atom or sulphur atom, m denotes the number 1 or 0 and n denotes the number 2 or 3, are obtained by cyclizing dicarboxylic acid monoamide compounds of the formula ##STR3## WITH ELIMINATION OF WATER. The bis-imides and tris-imides, mixed with azomethines and optionally with curing catalysts, can be used for the manufacture of moulded materials having technically very valuable mechanical and dielectric properties.
摘要:
According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polycarboxylic acids in the presence of basic compounds. The preferred embodiment (C) relates to the use of catalysts as basic compounds. In particular, tertiary amines, secondary amines or mixed tertiary-secondary amines can be used. A further embodiment (D) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.The invention can be utilized particularly in the fields of surface protection, the electrical industry, laminating processes, and the manufacture of foamed plastics, and in the building industry.
摘要:
The cross-linked macromolecular polyethers containing ionic bonds are obtained by reacting polyhydric phenols which contain amino groups (Mannich bases) on the one hand with compounds which contain on average more than one epoxide group per molecule, and on the other hand with organic compounds which contain at least 2 halogen atoms. The reaction is on the one hand a polyaddition, and on the other a polyquaternization. The adducts manufactured in this way have a reduced tendency to take on a static charge and can be used with advantage in the textile and paper sectors.
摘要:
New bis-imides and tris-imides of the formula ##EQU1## in which A and A' denote aromatic radicals which are optionally substituted or interrupted by an oxygen atom, an alkylene group or a sulphonyl group, Z denotes a radical of the formulae ##EQU2## D denotes an oxygen atom or sulphur atom, m denotes the number 1 or 0 and n denotes the number 2 or 3, are obtained by cyclizing dicarboxylic acid monoamide compounds of the formula ##EQU3## WITH ELIMINATION OF WATER. The bis-imides and tris-imides, mixed with azomethines and optionally with curing catalysts, can be used for the manufacture of moulded materials having technically very valuable mechanical and dielectric properties.
摘要翻译:式(O-A')3-n O(D = mP ANGLE | C(OAN ANGLE ANGLE Z)n C PARALLEL O)的新型双酰亚胺和三酰亚胺其中A和A'表示任选的芳族基团 被氧原子,亚烷基或磺酰基取代或中断,Z表示式H2C H3C | | ANGLE ANGLE HC HC CC并行平行| | HC C H2C C,| ANGLE |角度H3C H3C D表示 氧原子或硫原子,m表示数1或0,n表示数2或3,通过使式(O-A')3-n(D = mP ANGLE(OA- NH-CO-Z-COOH)n消除水分。