Biphosphites
    1.
    发明授权
    Biphosphites 失效
    二亚磷酸酯

    公开(公告)号:US5308902A

    公开(公告)日:1994-05-03

    申请号:US882993

    申请日:1992-05-14

    摘要: Biphosphites of formula I ##STR1## wherein m is 0, 1 or 2,n is 1 to 4 or 6,R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different, and A is the radical of an at least n-hydric alcohol or phenol, which radical is attached to the P atom or atoms through the alcoholic or phenolic O atom or atoms, obtainable by reacting a compound of formula II ##STR2## wherein m is 0, 1 or 2, R.sub.1 is hydrogen or C.sub.1 -C.sub.4 alkyl and, if m=2, the radicals R.sub.1 are identical or different and R.sub.2 ' is phenyl, C.sub.1 -C.sub.12 alkylphenyl or C.sub.1 -C.sub.4 alkyl, with a polyether polyol or polyether/ester polyol, the hydroxy functions of said polyether polyol or polyether/ester polyol being partially or completely esterified with the ##STR3## are suitable for use as stabilizers, especially processing stabilizers, for organic polymers, preferably PVC resins, high density polyethylene and propylene.

    摘要翻译: 式I的亚磷酸酯其中m为0,1或2,n为1至4或6,R 1为氢或C 1 -C 4烷基,如果m = 2,基团R 1相同或不同,并且 A是至少n-羟基醇或苯酚的基团,其基团通过醇或酚O原子或原子连接到P原子或原子上,可通过使式II的化合物(II)与式 m为0,1或2,R1为氢或C1-C4烷基,如果m = 2,基团R1相同或不同,R2'为苯基,C1-C12烷基苯基或C1-C4烷基,与聚醚多元醇或聚醚/ 酯多元醇,所述聚醚多元醇或聚醚/酯多元醇的羟基官能团与“IMAGE”部分或完全酯化,适用于有机聚合物,优选PVC树脂,高密度聚乙烯和丙烯的稳定剂,特别是加工稳定剂。

    Thermosetting reactive systems
    2.
    发明授权
    Thermosetting reactive systems 失效
    热固性反应体系

    公开(公告)号:US4906722A

    公开(公告)日:1990-03-06

    申请号:US273774

    申请日:1988-11-21

    摘要: Thermosetting reactive systems, comprising(a) at least one epoxide resin,(b) at least one isocyanate resin,(c) a reaction accelerator of the formula I ##STR1## in which R.sup.1 is --(CR.sup.4 R.sup.5).sub.n - with n=2-24, phenylene or naphthylene which is unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 -alkyl, C.sub.1-C.sub.4 alkoxy or C.sub.3 -C.sub.8 dialkylaminoalkyl, or a radical of the formulae ##STR2## R.sup.2 and R.sup.3 independently of one another are C.sub.1-C.sub.12 alkyl, phenyl or naphthyl which are unsubstituted or mono- or poly-substituted by halogen, nitro, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.1 -C.sub.4 alkoxy, or also C.sub.7 -C.sub.13 aralkyl, or in which R.sup.2 and R.sup.3, together with the N atom to which they are linked, form a 5-membered, 6-membered or 7-membered heterocyclic ring, and R.sup.4 and R.sup.5 independently of one another are hydrogen or C.sub.1 -C.sub.8 alkyl, and(d) if appropriate, a filler and/or further additives conventional in industry,have a long pot life and excellent heat-aging resistance.

    摘要翻译: 热固性反应体系,包含(a)至少一种环氧树脂,(b)至少一种异氰酸酯树脂,(c)式Ⅰ的反应促进剂,其中R1是 - (CR4R5)n-,其中n = 2-24,未被取代或被卤素,硝基,C 1 -C 4 - 烷基,C 1 -C 4烷氧基或C 3 -C 8二烷基氨基烷基单取代或多取代的亚苯基或亚萘基,或下式的基团:< IMAGE> + TR R 2和R 3彼此独立地是未被取代的或被卤素,硝基,C 1 -C 4烷基或C 1 -C 4烷氧基单取代或多取代的C 1 -C 12烷基,苯基或萘基,或者也可以是C 7 -C 13烷基,或 其中R 2和R 3与它们连接的N原子一起形成5元,6元或7元杂环,并且R 4和R 5彼此独立地是氢或C 1 -C 8烷基,和( d)如果合适,工业中常规的填料和/或其它添加剂具有长的适用期和优异的耐热老化性。

    Novel tetraglycidyl ethers
    6.
    发明授权
    Novel tetraglycidyl ethers 失效
    新型四缩水甘油醚

    公开(公告)号:US4549008A

    公开(公告)日:1985-10-22

    申请号:US640281

    申请日:1984-08-13

    CPC分类号: C07D303/24 C08G59/3218

    摘要: Novel tetraglycidyl ethers of the formula ##STR1## wherein X is a group ##STR2## R is hydrogen or methyl, and n is an integer from 2 to 4. The novel tetraglycidyl ethers can be used in curable mixtures, together with a curing agent for epoxide resins, in particular for the protection of surfaces.

    摘要翻译: 式(I)的新型四缩水甘油醚,其中X是基团R是氢或甲基,n是2-4的整数。新的四缩水甘油醚可以与可固化的混合物一起使用, 用于环氧树脂的固化剂,特别是用于保护表面。

    New imides of unsaturated dicarboxylic acids, processes for their
manufacture, and their use
    7.
    发明授权
    New imides of unsaturated dicarboxylic acids, processes for their manufacture, and their use 失效
    不饱和二羧酸的新方法,其制造方法及其使用

    公开(公告)号:US4082768A

    公开(公告)日:1978-04-04

    申请号:US687791

    申请日:1976-05-19

    摘要: New bis-imides and tris-imides of the formula ##STR1## in which A and A' denote aromatic radicals which are optionally substituted or interrupted by an oxygen atom, an alkylene group or a sulphonyl group, Z denotes a radical of the formulae ##STR2## D denotes an oxygen atom or sulphur atom, m denotes the number 1 or 0 and n denotes the number 2 or 3, are obtained by cyclizing dicarboxylic acid monoamide compounds of the formula ##STR3## WITH ELIMINATION OF WATER. The bis-imides and tris-imides, mixed with azomethines and optionally with curing catalysts, can be used for the manufacture of moulded materials having technically very valuable mechanical and dielectric properties.

    Process for the manufacture of polyaddition products containing imide
groups
    8.
    发明授权
    Process for the manufacture of polyaddition products containing imide groups 失效
    制备含酰亚胺基团的加聚产物的方法

    公开(公告)号:US4076697A

    公开(公告)日:1978-02-28

    申请号:US534106

    申请日:1974-12-18

    IPC分类号: C08G73/00 C08G73/12

    摘要: According to the invention, polyaddition products containing imide groups are manufactured by reacting certain polyimides (preferably maleimides) with polycarboxylic acids in the presence of basic compounds. The preferred embodiment (C) relates to the use of catalysts as basic compounds. In particular, tertiary amines, secondary amines or mixed tertiary-secondary amines can be used. A further embodiment (D) relates to the use of primary polyamines as basic compounds. In the latter case, the polyamine participates in the polyaddition mechanism, that is to say the molecules are incorporated into the polyaddition products. In this latter case, catalysts can also be used additionally.The invention can be utilized particularly in the fields of surface protection, the electrical industry, laminating processes, and the manufacture of foamed plastics, and in the building industry.

    摘要翻译: 根据本发明,含有酰亚胺基团的加聚产物是通过在碱性化合物的存在下使某些聚酰亚胺(优选马来酰亚胺)与多元羧酸反应来制备的。 优选的实施方案(C)涉及催化剂作为碱性化合物的用途。 特别地,可以使用叔胺,仲胺或混合的叔仲胺。 另一个实施方案(D)涉及原始多胺作为碱性化合物的用途。 在后一种情况下,多胺参与加聚机理,也就是说分子被加入到加成产物中。 在后一种情况下,也可以另外使用催化剂。

    Process for the manufacture of polyethers containing ionic bonds
    9.
    发明授权
    Process for the manufacture of polyethers containing ionic bonds 失效
    制造含离子键聚醚的方法

    公开(公告)号:US4014955A

    公开(公告)日:1977-03-29

    申请号:US440632

    申请日:1974-02-07

    申请人: Alfred Renner

    发明人: Alfred Renner

    摘要: The cross-linked macromolecular polyethers containing ionic bonds are obtained by reacting polyhydric phenols which contain amino groups (Mannich bases) on the one hand with compounds which contain on average more than one epoxide group per molecule, and on the other hand with organic compounds which contain at least 2 halogen atoms. The reaction is on the one hand a polyaddition, and on the other a polyquaternization. The adducts manufactured in this way have a reduced tendency to take on a static charge and can be used with advantage in the textile and paper sectors.

    摘要翻译: 包含离子键的交联的大分子聚醚通过使含有氨基的多元酚(曼尼希碱)一方面与每分子平均含有多于一个环氧基的化合物反应而获得,另一方面与有机化合物 含有至少2个卤素原子。 反应一方面是一种加聚,另一方面是聚季铵盐化。 以这种方式制造的加合物具有降低静电荷的倾向,并且可以有利地在纺织和造纸领域中使用。

    Compositions of new imides of unsaturated dicarboxylic acids and
azomethines
    10.
    发明授权
    Compositions of new imides of unsaturated dicarboxylic acids and azomethines 失效
    新型不饱和二羧酸和偶氮甲碱的组成

    公开(公告)号:US3960812A

    公开(公告)日:1976-06-01

    申请号:US381328

    申请日:1973-07-20

    CPC分类号: C08G73/12 C07F9/5537

    摘要: New bis-imides and tris-imides of the formula ##EQU1## in which A and A' denote aromatic radicals which are optionally substituted or interrupted by an oxygen atom, an alkylene group or a sulphonyl group, Z denotes a radical of the formulae ##EQU2## D denotes an oxygen atom or sulphur atom, m denotes the number 1 or 0 and n denotes the number 2 or 3, are obtained by cyclizing dicarboxylic acid monoamide compounds of the formula ##EQU3## WITH ELIMINATION OF WATER. The bis-imides and tris-imides, mixed with azomethines and optionally with curing catalysts, can be used for the manufacture of moulded materials having technically very valuable mechanical and dielectric properties.

    摘要翻译: 式(O-A')3-n O(D = mP ANGLE | C(OAN ANGLE ANGLE Z)n C PARALLEL O)的新型双酰亚胺和三酰亚胺其中A和A'表示任选的芳族基团 被氧原子,亚烷基或磺酰基取代或中断,Z表示式H2C H3C | | ANGLE ANGLE HC HC CC并行平行| | HC C H2C C,| ANGLE |角度H3C H3C D表示 氧原子或硫原子,m表示数1或0,n表示数2或3,通过使式(O-A')3-n(D = mP ANGLE(OA- NH-CO-Z-COOH)n消除水分。