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公开(公告)号:US4235799A
公开(公告)日:1980-11-25
申请号:US30028
申请日:1979-04-16
IPC分类号: C07C29/151 , C07C29/154 , C07C31/06
CPC分类号: C07C29/154 , C07C29/1512 , C07C29/1516
摘要: Methanol is produced by passing a mixture of hydrogen and one or more carbon oxides into contact with at least two beds (converters) of catalyst arranged in series, the beds of catalyst being operated at increasing temperature levels in the direction of flow of the mixture. The mixture is then cooled by indirect heat-exchange and passed into contact with at least one further bed of catalyst.
摘要翻译: 通过使氢气和一种或多种碳氧化物的混合物通过与串联布置的催化剂的至少两个床(转化器)接触来生产甲醇,催化剂床在混合物流动方向上以升高的温度水平操作。 然后将混合物通过间接热交换进行冷却,并与至少另外一个催化剂床接触。
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公开(公告)号:US4996031A
公开(公告)日:1991-02-26
申请号:US407931
申请日:1989-09-15
申请人: James P. Spooner , Alvin B. Stiles
发明人: James P. Spooner , Alvin B. Stiles
摘要: A catalyst undercoat (wash-coat) material comprising a plurality of stable, highly porous, co-precipitated agglomerated microcrystalline comprised of integral admixture of alumina and at least one lanthanide. The co-precipitated material may be converted to a slurry and used as an undercoat or wash-coat atop a prefabricated low surface area support. Alternatively, the co-precipitated material may be compressed or extruded into various geometric forms and these can be used as a support and as such serve both as the support and the undercoat.
摘要翻译: 催化剂底涂层(洗涂层)材料,其包含多个稳定的,高度多孔的,共沉淀的附聚微晶,其包含氧化铝和至少一种镧系元素的整体混合物。 共沉淀材料可以转化成浆料并用作预制的低表面积载体顶部的底涂层或洗涂层。 或者,共沉淀材料可以被压缩或挤压成各种几何形式,并且它们可以用作载体并且因此用作载体和底涂层。
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公开(公告)号:US4945079A
公开(公告)日:1990-07-31
申请号:US712873
申请日:1985-03-18
申请人: Lee A. Pedersen , Alvin B. Stiles
发明人: Lee A. Pedersen , Alvin B. Stiles
IPC分类号: B01J23/883
CPC分类号: B01J23/883
摘要: A catalyst comprising alumina having greater than 0.4 cc/g pore volume in the range 30 to 200 Angstroms pore diameter and catalytically effective amounts of Ni and Mo.A catalyst comprising gamma alumina, but essentially no eta alumina; further containing catalytically effective amounts of Ni and Mo.The method of making a catalyst having Ni and Mo on a substrate, comprising first depositing the Ni on the substrate and then the Mo.
摘要翻译: 一种包含氧化铝的催化剂,其具有大于0.4cc / g孔体积的范围为30-200纳米孔径和催化有效量的Ni和Mo。一种包含γ氧化铝但基本上不含有氧化铝的催化剂; 进一步含有催化有效量的Ni和Mo。在衬底上制备具有Ni和Mo的催化剂的方法,包括首先在衬底上沉积Ni,然后将Mo沉积在Mo上。
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4.
公开(公告)号:US5362463A
公开(公告)日:1994-11-08
申请号:US935207
申请日:1992-08-26
申请人: Alvin B. Stiles , Charles C. Hong
发明人: Alvin B. Stiles , Charles C. Hong
CPC分类号: B01D53/9481 , B01D53/0454 , B01D53/8631 , F23J15/027
摘要: A process for removing NOX from combustion gases by adsorption includes the step of desorbing the NOX when the adsorbent is saturated to create an effluent. The effluent is mixed with a reducing gas and passed over a reduction catalyst which reduces the NOX to water and elemental nitrogen. The resultant harmless gas is discharged to the atmosphere.
摘要翻译: 通过吸附从燃烧气体中除去NO x的方法包括当吸附剂饱和以产生流出物时解吸NOX的步骤。 将流出物与还原气体混合并通过还原催化剂,将还原催化剂还原成水和元素氮。 所产生的无害气体排放到大气中。
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公开(公告)号:US4562174A
公开(公告)日:1985-12-31
申请号:US612633
申请日:1984-05-21
申请人: Alvin B. Stiles
发明人: Alvin B. Stiles
IPC分类号: B01J23/80 , C07C29/154 , B01J23/72 , B01J23/78 , B01J23/84
CPC分类号: B01J23/80 , C07C29/154 , Y02P20/52
摘要: The inclusion of salts of rubidium or cesium or mixtures thereof in a catalyst comprised of copper and zinc oxides and optionally manganese oxide or manganese and cobalt oxides and a stabilizer such as chromic, ceric, magnesium or aluminum oxides results in higher yields of C.sub.1 to C.sub.6 alkanols and lower production of hydrocarbons in the effluent from the catalytic reaction environment. The reactant gases passing over the catalyst comprises hydrogen and carbon monoxide and optionally carbon dioxide if economically advantageous.
摘要翻译: 将包含铷或铯盐或其混合物的盐包括在由铜和锌氧化物以及任选的氧化锰或锰和钴氧化物以及稳定剂如铬,铈,镁或氧化铝组成的催化剂中,导致C1至C6的较高产率 链烷醇和来自催化反应环境的流出物中较低的烃类生产。 如果经济上有利的话,通过催化剂的反应气体包括氢气和一氧化碳,以及任选的二氧化碳。
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公开(公告)号:US4138430A
公开(公告)日:1979-02-06
申请号:US837632
申请日:1977-09-28
申请人: Alvin B. Stiles , David C. England
发明人: Alvin B. Stiles , David C. England
IPC分类号: C07C47/22 , B01J21/00 , C07B61/00 , C07C45/00 , C07C45/35 , C07C45/37 , C07C45/38 , C07C57/055 , C07C67/00 , C07C120/00 , C07C120/14 , C07C121/32
CPC分类号: C07C253/24 , C07C45/35 , C07C45/38 , Y02P20/52
摘要: Acrylic products are produced in high yields by a catalytic process in which a vaporous mixture of 1-propanol and oxygen are contacted in rapid sequence with (1) a dehydration catalyst and (2) an oxidation catalyst.
摘要翻译: 通过催化方法以高产率生产丙烯酸产品,其中1-丙醇和氧气的气态混合物与(1)脱水催化剂和(2)氧化催化剂快速接触。
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公开(公告)号:US4131616A
公开(公告)日:1978-12-26
申请号:US482574
申请日:1974-06-24
申请人: Alvin B. Stiles
发明人: Alvin B. Stiles
IPC分类号: B01J23/86 , B01J37/03 , C07B61/00 , C07C1/00 , C07C1/02 , C07C9/04 , C07C67/00 , C10K3/02 , C10K3/04 , C07C27/06
CPC分类号: C10K3/04 , B01J23/866 , B01J37/03 , C07C1/02 , C07C2523/26 , C07C2523/755 , C07C2523/86
摘要: An improved nickel chromite catalyst useful for methanation is prepared by pre-reducing the hexavalent chromium component thereof to trivalent form, while maintaining the nickel component in unreduced oxide form.
摘要翻译: 通过将六价铬组分预还原成三价形式,同时保持镍组分为未还原氧化物形式,可制备用于甲烷化的改进的镍铬铁合金催化剂。
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公开(公告)号:US5176888A
公开(公告)日:1993-01-05
申请号:US694085
申请日:1991-05-01
申请人: Alvin B. Stiles
发明人: Alvin B. Stiles
IPC分类号: B01D53/86
CPC分类号: B01D53/8637
摘要: The process of this invention will remove acid rain precursors, sulfur oxides (SOX) and nitrogen oxides (NOX) by catalytically reducing the NOX to water and elemental nitrogen and the SOX to either H.sub.2 S or elemental sulfur as desired. The process employs specific catalysts in the heteropoly acid or salt group and the spinel or inverse spinel group. The process conditions achieve an oxygen-free environment and reduction is effected with stoichiometric to 100% excess above stoichiometric H.sub.2 or H.sub.2 and CO as reducing gas. Temperatures can be 200.degree. to 900.degree. C. with the lower temperature range being favored space velocity can be 2000 to 20,000 and still achieve 95+% abatement. The only product of the reaction which must be disposed of is saleable elemental sulfur.
摘要翻译: 根据需要,本发明的方法将通过将NO x还原成水和元素氮,将SO X还原成H 2 S或元素硫来除去酸雨前体,硫氧化物(SOX)和氮氧化物(NOX)。 该方法在杂多酸或盐基和尖晶石或反尖晶石组中使用特定的催化剂。 工艺条件达到无氧环境,并以化学计量比100%超过化学计量的H 2或H 2和CO作为还原气体进行还原。 温度可以在200〜900℃,较低的温度范围有利于空速可达2000〜20,000,仍能达到95±%的减排。 必须处理的反应的唯一产物是可释放的元素硫。
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公开(公告)号:US5176814A
公开(公告)日:1993-01-05
申请号:US701430
申请日:1991-05-15
CPC分类号: C01B3/22 , C10G11/00 , F02B51/02 , F02C7/16 , Y02T10/126 , Y02T50/675
摘要: A heat source, may be on a high speed vehicle, may be cooled by transferring thermal energy from the heat source to an endothermic fuel decomposition catalyst in order to heat the catalyst to a temperature sufficient to crack or dissociate at least a portion of an endothermic fuel stream. The endothermic fuel is selected from the group consisting of normal paraffinic hydrocarbons and methanol. The heated endothermic fuel decomposition catalyst is contacted with the endothermic fuel stream at a liquid hourly space velocity of at least about 10 hr.sup.-1 to cause the endothermic fuel stream to crack or dissociate into a reaction product stream.
摘要翻译: 可以在高速车辆上的热源可以通过将热能从热源传递到吸热燃料分解催化剂来冷却,以便将催化剂加热到足以使吸热的至少一部分裂化或解离的温度 燃料流。 吸热燃料选自正常链烷烃和甲醇。 加热的吸热燃料分解催化剂以至少约10hr-1的液时空速与吸热燃料流接触,引起吸热燃料流裂解或解离成反应产物流。
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公开(公告)号:US4868150A
公开(公告)日:1989-09-19
申请号:US136279
申请日:1987-12-22
申请人: James P. Spooner , Alvin B. Stiles
发明人: James P. Spooner , Alvin B. Stiles
摘要: A catalyst undercoat (wash-coat) material comprising a plurality of stable, highly porous, co-precipitated agglomerated microcrystallites comprised of integral admixture of alumina and at least one lanthanide. The co-precipitated material may be converted to a slurry and used as an undercoat or wash-coat atop a prefabricated low surface area support. Alternatively, the co-precipitated material may be compressed or extruded into various geometric forms and these can be used as a support and as such serve both as the support and the undercoat.
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