Aqueous ink jet ink compositions and uses
    1.
    发明授权
    Aqueous ink jet ink compositions and uses 有权
    水性喷墨油墨组合物及用途

    公开(公告)号:US09181442B2

    公开(公告)日:2015-11-10

    申请号:US14170977

    申请日:2014-02-03

    摘要: Aqueous ink jet ink compositions are used for ink jet printing colorless, colored or invisible images on receiver elements. These compositions contain a dispersion of an unsaturated natural oil and a water compatible polyurethane. The unsaturated oil dispersion is prepared from conventional surfactants or a polyurethane dispersing agent. The polyurethane is prepared from unsaturated polyol segments prepared from the unsaturated natural oils. The ink preparations are printed on media treated with agents such as metal ions known to catalyze crosslinking reactions in unsaturated oils. Such compositions are useful in various ink jet printing systems including drop on demand and continuous ink jet printing systems.

    摘要翻译: 水性喷墨油墨组合物用于在接收器元件上喷墨印刷无色,有色或不可见的图像。 这些组合物含有不饱和天然油和水相容聚氨酯的分散体。 不饱和油分散体由常规表面活性剂或聚氨酯分散剂制备。 由不饱和天然油制备的不饱和多元醇链段制备聚氨酯。 油墨制剂印刷在用诸如已知用于催化不饱和油中的交联反应的金属离子的试剂处理的介质上。 这种组合物可用于各种喷墨打印系统,包括按需喷墨和连续喷墨打印系统。

    RECIRCULATING FLUID PRINTING SYSTEM AND METHOD
    2.
    发明申请
    RECIRCULATING FLUID PRINTING SYSTEM AND METHOD 审中-公开
    循环流体印刷系统和方法

    公开(公告)号:US20120274685A1

    公开(公告)日:2012-11-01

    申请号:US13097128

    申请日:2011-04-29

    IPC分类号: B41J29/38 B41J2/18

    CPC分类号: B41J2/18 C09D11/322

    摘要: A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprises water, colorant, acrylic latex polymer, and a water dispersible polyurethane additive having an acid number greater than 50. The acrylic latex polymer provides increased optical density for printed images, and the water dispersible polyurethane additive enables the latex-containing printing fluid to be recirculated for extended periods without significant fluid destabilization or pressure build up or filter clogging. Also disclosed is method of continuous inkjet printing employing such a printing system.

    摘要翻译: 一种用于将印刷液体施加到基底上的打印系统,包括印刷液体涂抹器和向印刷器供应印刷液体的循环印刷液体供给装置,其中印刷液体包括水,着色剂,丙烯酸胶乳聚合物和水分散性聚氨酯添加剂, 大于50的酸值。丙烯酸胶乳聚合物为印刷图像提供增加的光密度,并且水分散性聚氨酯添加剂使得含乳胶的印刷液体能够长时间再循环,而没有显着的流体不稳定或压力积聚或过滤器堵塞。 还公开了采用这种印刷系统的连续喷墨印刷方法。

    Recirculating fluid printing system and method
    3.
    发明授权
    Recirculating fluid printing system and method 有权
    循环流体印刷系统及方法

    公开(公告)号:US08434857B2

    公开(公告)日:2013-05-07

    申请号:US12872018

    申请日:2010-08-31

    IPC分类号: B41J2/02

    摘要: A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive.

    摘要翻译: 一种印刷系统,用于将印刷液体施加到基材上,包括印刷液体涂抹器和将印刷液体供应给涂布器的再循环印刷液体供应装置,其中包含水的印刷液和(I)通式的水分散性聚氨酯添加剂, 其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。

    INKJET PRINTING FLUID
    4.
    发明申请
    INKJET PRINTING FLUID 审中-公开
    INKJET印刷油

    公开(公告)号:US20120277366A1

    公开(公告)日:2012-11-01

    申请号:US13097137

    申请日:2011-04-29

    IPC分类号: C09D175/04

    摘要: An inkjet printing fluid composition comprising water, colorant, acrylic latex polymer, and a water dispersible polyurethane additive having an acid number greater than 50, preferably between 50 and 150, more preferably from 60 to 100, and most preferably from 60 to 90. The invention provides inkjet printing fluid compositions, such as pigment-based inkjet printing inks, which contain an acrylic latex polymer which provides increased optical density for printed images, and a water dispersible polyurethane additive that enables the latex-containing printing fluid to be recirculated for extended periods in a recirculating printing fluid printing system without significant fluid destabilization or pressure build up or filter clogging. The invention further provides a method for printing an inkjet image comprising: I) providing an inkjet printing fluid according to the invention; and II) jetting the inkjet printing fluid in the form of ink drops onto a recording element to form a printed image.

    摘要翻译: 一种包含水,着色剂,丙烯酸胶乳聚合物和酸值大于50,优选50至150,更优选60至100,最优选60至90的水分散性聚氨酯添加剂的喷墨印刷液组合物。 本发明提供喷墨印刷液组合物,例如颜料基喷墨印刷油墨,其含有丙烯酸胶乳聚合物,其为印刷图像提供增加的光密度;以及水分散性聚氨酯添加剂,其使含胶乳的印刷液体能够再循环用于延伸 在循环印刷液体印刷系统中的周期,没有显着的流体不稳定或压力累积或过滤器堵塞。 本发明还提供一种用于印刷喷墨图像的方法,包括:I)提供根据本发明的喷墨印刷液; 和II)将墨滴形式的喷墨打印流体喷射到记录元件上以形成打印图像。

    RECIRCULATING FLUID PRINTING SYSTEM AND METHOD
    5.
    发明申请
    RECIRCULATING FLUID PRINTING SYSTEM AND METHOD 有权
    循环流体印刷系统和方法

    公开(公告)号:US20120050415A1

    公开(公告)日:2012-03-01

    申请号:US12872018

    申请日:2010-08-31

    IPC分类号: B41J2/02

    摘要: A printing system for applying a printing fluid to a substrate, comprising a printing fluid applicator and a recirculating printing fluid supply supplying printing fluid to the applicator, wherein the printing fluid comprising water and a water dispersible polyurethane additive of the general formula of (I) wherein Z is the central portion of a monomer unit that is the polymerization product of a diisocyanate; X1—Y1—X1 represents one or more soft segments wherein Y1 represents the central portion of a unit that is the polymerization product of a diamine or diol prepolymer having a molecular weight of greater than 300 Daltons; W is the central portion of one or more units containing an acid group; X2—Y2—X2 represents one or more hard segments wherein Y2 represents the central portion of a unit that is the polymerization product of a C2-C8 diol or diamine having a molecular weight of less than 250 Daltons; and X1, V and X2 can be the same or different and are an —O— or —N— atom; and further wherein the polyurethane additive has a weight average molecular weight of at least 6,000 Daltons and a sufficient number of acid groups to provide an acid number greater than 35, and the one or more X2—Y2—X2 hard segments are present at from 1 wt % to less than 13 wt % of the polyurethane additive.

    摘要翻译: 一种印刷系统,用于将印刷液体施加到基材上,包括印刷液体涂抹器和将印刷液体供应给涂布器的再循环印刷液体供应装置,其中包含水的印刷液和(I)通式的水分散性聚氨酯添加剂, 其中Z是作为二异氰酸酯的聚合产物的单体单元的中心部分; X1-Y1-X1表示一个或多个软链段,其中Y1表示作为分子量大于300道尔顿的二胺或二醇预聚物的聚合产物的单元的中心部分; W是含有酸基的一个或多个单元的中心部分; X2-Y2-X2表示一个或多个硬链段,其中Y2表示作为分子量小于250道尔顿的C2-C8二醇或二胺的聚合产物的单元的中心部分; X1,V和X2可以相同或不同,为-O-或-N-原子; 并且其中所述聚氨酯添加剂具有至少6,000道尔顿的重均分子量和足够数量的酸基以提供大于35的酸值,并且所述一个或多个X2-Y2-X2硬链段存在于1 wt%至小于13wt%的聚氨酯添加剂。

    Process of conducting epitaxial deposition as a continuation of emulsion
precipitation
    7.
    发明授权
    Process of conducting epitaxial deposition as a continuation of emulsion precipitation 失效
    导电外延沉积的过程是乳液沉淀的延续

    公开(公告)号:US6100019A

    公开(公告)日:2000-08-08

    申请号:US292436

    申请日:1999-04-15

    CPC分类号: G03C1/0051

    摘要: A process is disclosed of conducting in a single reaction vessel selective site high chloride epitaxy deposition as a continuation of host high bromide {1111} tabular grain emulsion precipitation. A host tabular grain emulsion is precipitated accounting for 0.05 to 1.5 moles of silver per liter of dispersing medium. Any iodide at the major faces of the tabular grains is uniformly distributed and any iodide in a surface region of the grains amounts to less than 7 mole, based on silver in the surface region. Until epitaxy is formed, pH is held in the range of 3 to 8. Gelatino-peptizer in an amount of 1 to 40 grams per Ag mole is added to the emulsion. Chloride ion in a range of from 0.03 to 0.15 mole per liter is dispersed in the emulsion. pBr is held in the range of from 3.0 to 3.8 until epitaxy is formed. Iodide ion in a concentration of from 5.times.10.sup.-6 to 1.times.10.sup.-4 mole per square meter of grain surface area is uniformly adsorbed to the major surfaces of the tabular grains.

    摘要翻译: 公开了在单个反应容器选择性位置进行高氯化物外延沉积作为主体高溴酸盐(1111)片状颗粒乳液沉淀的延续的方法。 沉淀出主体片状颗粒乳剂,每升分散介质为0.05至1.5摩尔的银。 在片状颗粒的主面上的任何碘化物均匀分布,并且基于表面区域中的银,颗粒的表面区域中的任何碘化物均小于7摩尔。 直到形成外延,pH值保持在3至8的范围内。每摩尔Ag摩尔量为1至40克的明胶胶溶剂加到乳液中。 在0.03至0.15摩尔/升范围内的氯离子分散在乳液中。 pBr保持在3.0至3.8的范围内,直到形成外延。 浓度为5×10-6至1×10-4摩尔每平方米晶粒表面积的碘离子均匀地吸附到片状颗粒的主表面。

    Process for the preparation of silver halide emulsions containing
dispersed clumps of fine grains
    8.
    发明授权
    Process for the preparation of silver halide emulsions containing dispersed clumps of fine grains 失效
    制备含有分散的细颗粒团的卤化银乳剂的方法

    公开(公告)号:US5976778A

    公开(公告)日:1999-11-02

    申请号:US179700

    申请日:1998-10-27

    摘要: A process of preparing a radiation-sensitive silver halide emulsion is disclosed in which the silver halide grains form dispersed clumps. A population of fine silver halide grains is precipitated at higher concentrations than previously taught for preparing this type of an emulsion by employing a peptizer limited in amount, limited in methionine content, or both. Following formation of the grains, they are aggregated into clumps by the addition of a surfactant, optionally assisted by the adding iodide, increasing pH or both. The grain clumps are stabilized against further aggregation by adding a high methionine peptizer and optionally assisted by the precipitation of additional silver halide.

    摘要翻译: 公开了制备辐射敏感卤化银乳剂的方法,其中卤化银颗粒形成分散的团块。 通过使用受限于蛋氨酸含量限制的胶溶剂或两者,使用比以前通过制备这种类型的乳液所教导的浓度更高的浓度的细卤化银颗粒群沉淀。 在形成颗粒后,通过加入表面活性剂将它们聚集成团,任选地通过加入碘化物,增加pH或两者来辅助。 通过添加高甲硫氨酸胶溶剂并任选通过沉淀额外的卤化银来帮助颗粒团稳定,防止进一步聚集。

    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS
    10.
    发明申请
    PRECURSOR DIELECTRIC COMPOSITION WITH THIOSULFATE-CONTAINING POLYMERS 有权
    含有含硫聚合物聚合物的前驱体电介质组合物

    公开(公告)号:US20150364688A1

    公开(公告)日:2015-12-17

    申请号:US14301385

    申请日:2014-06-11

    IPC分类号: H01L51/00

    摘要: A precursor dielectric composition comprises: (1) a photocurable or thermally curable thiosulfate-containing polymer that has a Tg of at least 50° C. and comprises: an organic polymer backbone comprising (a) recurring units comprising pendant thiosulfate groups; and organic charge balancing cations, (2) optionally, an electron-accepting photosensitizer component, and (3) one or more organic solvents in which the photocurable or thermally curable thiosulfate-containing polymer is dissolved or dispersed. These precursor dielectric compositions can be applied to various substrates and eventually cured to form dielectric compositions or layers for various types of electronic devices.

    摘要翻译: 前体电介质组合物包含:(1)Tg至少为50℃的可光固化或可热固化的含硫代硫酸盐的聚合物,包括:有机聚合物主链,其包含(a)包含硫代硫酸盐基团的重复单元; 和有机电荷平衡阳离子,(2)任选的电子接受光敏剂组分,和(3)其中溶解或分散有可光固化或可热固化的含硫代硫酸盐的聚合物的一种或多种有机溶剂。 这些前体介电组合物可以施加到各种基底上,并且最终固化以形成用于各种类型的电子器件的电介质组合物或层。