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    Process for preparing protective-colloid-stabilized vinylaromatic-1,3-diene copolymers
    1.
    发明授权
    Process for preparing protective-colloid-stabilized vinylaromatic-1,3-diene copolymers 有权
    制备保护胶体稳定的乙烯基芳族-1,3-二烯共聚物的方法

    公开(公告)号：US06590022B1

    公开(公告)日：2003-07-08

    申请号：US09555591

    申请日：2000-05-21

    申请人： Thomas Bastelberger ,  Reinhard Haerzschel ,  Theo Mayer ,  Peter Weitzel ,  Peter Ball

    发明人： Thomas Bastelberger ,  Reinhard Haerzschel ,  Theo Mayer ,  Peter Weitzel ,  Peter Ball

    IPC分类号： C08F216

    CPC分类号： C08F236/10 ,  C08F2/20

    摘要： A method is provided for producing protective colloid-stabilized vinyl aromatic-1.3-diene-copolymers in the form of their aqueous polymer dispersions or in the form of a powder which can be re-dispersed in water, by emulsion-polymerizing a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of a protective colloid and optionally, drying the resulting polymer dispersions. In the method part of the protective colloid is provided straightaway and part is metered.

    摘要翻译： 提供了一种制备保护性胶体稳定的乙烯基芳族-1,3-二烯共聚物的形式，其聚合物水分散体形式或以可再分散在水中的粉末形式，通过将含有 至少一种乙烯基芳族化合物和至少一种1,3-二烯在保护胶体存在下，任选地干燥所得聚合物分散体。 在方法中，保护胶体的一部分直接提供，部分是计量的。

    Process for reducing the odor emission of aqueous vinylaromatic/1,3-diene copolymer dispersions
    2.
    发明授权
    Process for reducing the odor emission of aqueous vinylaromatic/1,3-diene copolymer dispersions 失效
    用于降低乙烯基芳族化合物/ 1,3-二烯共聚物分散体的气味排放的方法

    公开(公告)号：US06417297B1

    公开(公告)日：2002-07-09

    申请号：US09593618

    申请日：2000-06-13

    申请人： Theo Mayer ,  Peter Ball

    发明人： Theo Mayer ,  Peter Ball

    IPC分类号： C08F616

    CPC分类号： C08F6/006 ,  C08C1/04 ,  C08C4/00 ,  C08F6/003 ,  C08F212/04 ,  C09D125/10 ,  C09J125/10

    摘要： A process for reducing the odor emission of aqueous vinylaromatic/1,3-diene copolymer dispersions and of redispersion powders obtainable therefrom by drying, is by emulsion polymerization of a mixture containing at least one vinylaromatic and at least one 1,3-diene in the presence of one or more surfactant substances and optionally drying of the polymer dispersion obtained thereby. There are 0.01% to 15.0% by weight of one or more monomers of the branched or straight-chain alkyl esters having 1 to 8 C atoms in the alkyl radical of monounsaturated monocarboxylic or dicarboxylic acids and 0.01% to 15.0% by weight of one or more monomers based upon the vinyl esters of branched or straight-chain aliphatic carboxylic acids having 1 to 10 C atoms which are added in one step or in two successive steps toward the end of the polymerization, when the total content of free monomers in the aqueous copolymer dispersion is in the range from ≧0 to ≦20% by weight. It is also possible optionally to add the vinyl ester fraction as early as the beginning of or during the polymerization. The data in % by weight is based in each case on the polymer content of the dispersion.

    摘要翻译： 降低乙烯基芳族化合物/ 1,3-二烯烃共聚物分散体和通过干燥获得的再分散粉末的气味排放的方法是通过在含有至少一种乙烯基芳族化合物和至少一种1,3-二烯的混合物的乳液聚合 存在一种或多种表面活性剂物质，并任选地干燥由此获得的聚合物分散体。 在单不饱和一元羧酸或二羧酸的烷基中具有1至8个C原子的支链或直链烷基酯的一种或多种单体的0.01至15.0重量％和0.01重量％至15.0重量％ 基于具有1至10个C原子的支链或直链脂族羧酸的乙烯基酯的更多单体，其在一个步骤中或在聚合结束时的两个连续步骤中加入，当水性中的游离单体的总含量 共聚物分散体在> = 0至<= 20重量％的范围内。 也可以任选地在聚合开始或聚合期间加入乙烯基酯部分。 在每种情况下，以重量％计的数据基于分散体的聚合物含量。

    Process for reducing the odor of vinylaromatic-1,3-diene copolymer dispersions stabilized by protective colloids
    3.
    发明授权
    Process for reducing the odor of vinylaromatic-1,3-diene copolymer dispersions stabilized by protective colloids 失效
    降低由保护胶体稳定的乙烯基芳族-1,3-二烯共聚物分散体的气味的方法

    公开(公告)号：US06756454B1

    公开(公告)日：2004-06-29

    申请号：US09856190

    申请日：2001-05-17

    申请人： Theo Mayer ,  Peter Ball

    发明人： Theo Mayer ,  Peter Ball

    IPC分类号： C08F616

    CPC分类号： C08F212/04 ,  C08C1/04 ,  C08F6/006 ,  C08K5/10 ,  C08L25/10

    摘要： The invention relates to a method for reducing odor emissions of aqueous aromatic vinyl-1,3-diene-copolymer dispersions which have been stabilized with a protective colloid. The invention also relates to redispersion powders obtained by drying said dispersions. This is achieved by emulsion polymerization of a mixture containing at least one aromatic vinyl and at least one 1,3-diene in the presence of one or more protective colloids and by optionally drying the polymer dispersion obtained thereby. The invention is characterized in that 0.01 to 15.0 wt. % of one or more monomers selected from the group of branched or unbranched alkyl esters containing 1 to 8 carbon atoms in the alkyl radical of monounsaturated mono- or dicarboxylic acids are added at the end of the polymerization when the total content of the aqueous polymer dispersion containing free monomers ranges from >0 to ≦20 wt. %, whereby the given wt. % refers to the polymer content of the dispersion.

    摘要翻译： 本发明涉及一种减少用保护胶体稳定的芳族乙烯基-1,3-二烯共聚物分散体的气味排放的方法。 本发明还涉及通过干燥所述分散体获得的再分散粉末。 这是通过在一种或多种保护性胶体存在下含有至少一种芳族乙烯基和至少一种1,3-二烯的混合物进行乳液聚合，并任选地干燥由此得到的聚合物分散体来实现的。 本发明的特征在于，0.01〜15.0wt。 当单体不饱和单羧酸或二羧酸的烷基中含有1至8个碳原子的支链或非支链烷基酯中的一种或多种单体的％，当聚合物水分子的总含量 含有游离单体的范围为> 0至≤= 20wt。 ％，其中给定的wt。 ％是指分散体的聚合物含量。

    Polyvinylacetal-grafted polymers
    5.
    发明授权
    Polyvinylacetal-grafted polymers 失效
    聚乙烯缩醛接枝聚合物

    公开(公告)号：US06734246B2

    公开(公告)日：2004-05-11

    申请号：US10040675

    申请日：2001-11-09

    申请人： Hans-Peter Weitzel ,  Peter Ball ,  Peter Tschirner

    发明人： Hans-Peter Weitzel ,  Peter Ball ,  Peter Tschirner

    IPC分类号： C08F224

    CPC分类号： C08F261/12 ,  C08F8/48 ,  C08F261/04 ,  C08F8/28 ,  C08F16/06

    摘要： Polyvinylacetal-grafted polymers in the form of their aqueous dispersions or water-redispersible powders, and based on emulsion or suspension polymerized base polymers of one or more monomers from the group consisting of vinyl esters, (meth)acrylates, vinylaromatics, olefins, 1,3-dienes and vinyl halides, and optionally, further monomers copolymerizable therewith, the base polymers grafted with polyvinylacetals having from 0 to 5.0 mol % of vinyl acetate units, from 75 to 95 mol % of vinyl alcohol units and from 0.1 to 20 mol % of acetal units which are derived from aldehydes having 3 to 7 C atoms, are useful as additives in construction compositions, as binders, and as adhesives, and may be dried to form readily water-redispersible polymer powders.

    摘要翻译： 聚乙烯缩醛接枝聚合物为水分散体或水分散性粉末，并且基于一种或多种由乙烯基酯，（甲基）丙烯酸酯，乙烯基芳烃，烯烃， 3-二烯和乙烯基卤化物，以及任选的可与其共聚的其它单体，该接枝聚乙烯醇缩合物的基础聚合物具有0-5.0mol％乙酸乙烯酯单元，75-95mol％乙烯醇单元和0.1-20mol％ 的衍生自具有3至7个C原子的醛的缩醛单元可用作施用组合物中的添加剂，作为粘合剂和粘合剂，并且可以被干燥以形成易于水分再分散的聚合物粉末。

    Redispersible, dispersion-powder composition
    6.
    发明授权
    Redispersible, dispersion-powder composition 失效
    可再分散，分散粉组合物

    公开(公告)号：US6127483A

    公开(公告)日：2000-10-03

    申请号：US91296

    申请日：1998-06-15

    申请人： Hans-Peter Weitzel ,  Peter Ball ,  Reiner Figge

    发明人： Hans-Peter Weitzel ,  Peter Ball ,  Reiner Figge

    IPC分类号： C04B24/16 ,  C04B24/26 ,  C04B40/00 ,  C08L31/02 ,  C08L41/00 ,  C08L81/00 ,  C08L35/00 ,  C08F25/02

    CPC分类号： C04B40/0042 ,  C04B24/163 ,  C04B24/26 ,  C04B24/2623 ,  C04B24/2641 ,  C04B24/2688 ,  C08L31/02 ,  C04B2103/0057 ,  C08L41/00

    摘要： The invention relates to dispersion-powder compositions redispersible in water and containing (a) a vinyl ester ethylene copolymer with 50 to 90% by weight of vinyl esters of C.sub.2 to C.sub.12 carboxylic acid, 1 to 30% by weight of ethylene, 0-20% by weight of vinyl esters of .alpha.-branched monocarboxylic acids with 5 to 10 C-atoms, each in relation to the total weight of the vinyl ester ethylene copolymer, and (b) a water soluble copolymer with 20 to 80% by weight of hydrophobic, substantially water insoluble monomers, 20 to 80% by weight of water-soluble, salt-forming monomers from the group of ethylenically unsaturated sulfonic acids, and 0 to 50% by weight of ethylenically unsaturated monocarboxylic or dicarboxylic acids or the anhydrides thereof, each in relation to the total weight of the water soluble copolymer.

    摘要翻译： PCT No.PCT / EP96 / 05722 Sec。 371日期1998年6月15日第 102（e）日期1998年6月15日PCT 1996年12月19日PCT PCT。 出版物WO97 / 24400 日本1997年7月10日本发明涉及可再分散于水中的分散粉末组合物，其含有（a）乙烯基酯乙烯共聚物，其含有50〜90重量％的C2〜C12羧酸的乙烯基酯，1〜30重量％ 乙烯，0-20重量％的具有5至10个碳原子的α-支化单羧酸的乙烯基酯，各自相对于乙烯基酯乙烯共聚物的总重量，和（b）水溶性共聚物，其具有20至 80重量％的疏水性，基本上不溶于水的单体，20-80重量％的来自烯键式不饱和磺酸的水溶性成盐单体和0-50重量％的烯属不饱和一元羧酸或二羧酸 或其酸酐，各自相对于水溶性共聚物的总重量。