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1.发明授权Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition 失效未凝胶化的聚环氧化物 - 聚氧亚烷基多胺树脂，其水分散体及其在阳离子电沉积中的应用
公开(公告)号：US4432850A
公开(公告)日：1984-02-21
申请号：US420463
申请日：1982-09-20
CPC分类号： C09D5/443 , C08L63/00 , Y10T428/31529 , Y10T428/31678
摘要： Ungelled resins, aqueous dispersions of cationic resins, coating compositions, and electrodeposition using the resinous coating compositions are disclosed. The resins are formed from reacting polyepoxides with polyoxyalkylenepolyamines. The aqueous dispersons are prepared by at least partially neutralizing the resins to provide cationic groups and dispersing the cationic resins in aqueous medium. When added to cationic electrodepositable coating compositions, such as high throwpower compositions, the ungelled cationic resins provide better appearing, more flexible and water-resistant electrodeposited coatings.
摘要翻译： 公开了未胶凝树脂，阳离子树脂的水性分散体，涂料组合物和使用树脂涂料组合物的电沉积。 树脂由聚环氧化物与聚氧亚烷基多胺反应形成。 水分散体通过至少部分中和树脂以提供阳离子基团并将阳离子树脂分散在水性介质中来制备。 当添加到阳离子可电沉积涂料组合物（例如高挥发性组合物）中时，非凝胶阳离子树脂提供更好的出现，更柔性和防水的电沉积涂料。
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2.发明授权Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition 失效未凝胶化的聚环氧化物 - 聚氧亚烷基多胺树脂，其水分散体及其在阳离子电沉积中的应用
公开(公告)号：US4423166A
公开(公告)日：1983-12-27
申请号：US420552
申请日：1982-09-20
CPC分类号： C09D5/443 , C08L63/00 , Y10S524/901
摘要： Ungelled resins, aqueous dispersions of cationic resins, coating compositions, and electrodeposition using the resinous coating compositions are disclosed. The resins are formed from reacting polyepoxides with polyoxyalkylenepolyamines. The aqueous dispersions are prepared by at least partially neutralizing the resins to provide cationic groups and dispersing the cationic resins in aqueous medium. When added to cationic electrodepositable coating compositions, such as high throwpower compositions, the ungelled cationic resins provide better appearing, more flexible and water-resistant electrodeposited coatings.
摘要翻译： 公开了未胶凝树脂，阳离子树脂的水性分散体，涂料组合物和使用树脂涂料组合物的电沉积。 树脂由聚环氧化物与聚氧亚烷基多胺反应形成。 水分散体通过至少部分中和树脂以提供阳离子基团并将阳离子树脂分散在水性介质中来制备。 当添加到阳离子可电沉积涂料组合物中，例如高挥发性组合物时，未凝胶化的阳离子树脂提供更好的出现，更柔性和耐水性的电沉积涂料。
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3.发明授权Ungelled polyepoxide-polyoxyalkylenepolyamine resins, aqueous dispersions thereof, and their use in cationic electrodeposition 失效未凝胶化的聚环氧化物 - 聚氧亚烷基多胺树脂，其水分散体及其在阳离子电沉积中的应用
公开(公告)号：US4420574A
公开(公告)日：1983-12-13
申请号：US420551
申请日：1982-09-20
CPC分类号： C09D5/443 , C08L63/00 , Y10S524/901
摘要： Ungelled resins, aqueous dispersions of cationic resins, coating compositions, and electrodeposition using the resinous coating compositions are disclosed. The resins are formed from reacting polyepoxides with polyoxyalkylenepolyamines. The aqueous dispersions are prepared by at least partially neutralizing the resins to provide cationic groups and dispersing the cationic resins in aqueous medium. When added to cationic electrode-positable coating compositions, such as high throwpower compositions, the ungelled cationic resins provide better appearing, more flexible and water-resistant electrodeposited coatings.
摘要翻译： 公开了未胶凝树脂，阳离子树脂的水性分散体，涂料组合物和使用树脂涂料组合物的电沉积。 树脂由聚环氧化物与聚氧亚烷基多胺反应形成。 水分散体通过至少部分中和树脂以提供阳离子基团并将阳离子树脂分散在水性介质中来制备。 当添加到阳离子电极可涂覆的涂料组合物中，例如高抛光组合物时，未凝胶化的阳离子树脂提供更好的出现，更柔性和防水的电沉积涂料。
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4.发明申请公开(公告)号：US20090042033A1
公开(公告)日：2009-02-12
申请号：US12254072
申请日：2008-10-20
申请人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, JR. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
发明人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, JR. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
IPC分类号： C08F283/02 , C08G64/30 , B32B15/08
CPC分类号： C09D5/4419 , C08G59/56 , Y10T428/31507 , Y10T428/31529
摘要： The present invention provides a film-forming composition. The composition includes a reaction product of:a) a polyamine containing a primary amino group and a secondary amino group; andb) an acyclic carbonate.Also provided is a method of preparing a film-forming composition and an article coated with such compositions.
摘要翻译： 本发明提供一种成膜组合物。 该组合物包括：a）含有伯氨基和仲氨基的多胺的反应产物; 和b）无环碳酸酯。 还提供了制备成膜组合物的方法和用这种组合物涂覆的制品。
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5.发明授权Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition 失效阳离子树脂和封端的多异氰酸酯固化剂适用于电沉积
公开(公告)号：US5760107A
公开(公告)日：1998-06-02
申请号：US724343
申请日：1996-10-01
申请人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
发明人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
IPC分类号： C09D163/00 , C08G18/08 , C08G18/32 , C08G18/42 , C08G18/58 , C08G18/64 , C08G18/80 , C09D5/08 , C09D5/44 , C09D175/04 , C09D175/12 , C08L63/00 , C08L63/02
CPC分类号： C08G18/3256 , C08G18/0814 , C08G18/0823 , C08G18/4294 , C08G18/581 , C08G18/584 , C08G18/6407 , C08G18/643 , C08G18/80 , C08G18/8009 , C08G18/8048 , C08G18/8064 , C09D5/4434 , C09D5/4453 , C09D5/4457
摘要： An electrodepositable composition is provided comprising: (A) a non-gelled cationic resin which is derived from a polyepoxide and which contains in the resin molecule cationic salt groups and active hydrogen groups selected from aliphatic hydroxyl and primary and secondary amino; and present as a separate component (B) a fully capped polyisocyanate curing agent containing substantially no free isocyanate groups. The electrodepositable composition contains from about 0.02 to 1.0 milliequivalents phenolic hydroxyl groups per gram of resin solids, and from about 0.1 to 2.0 milliequivalents beta-hydroxy ester groups per gram of resin solids. The composition provides excellent corrosion resistance when electrodeposited over steel substrates, and does not require lead in the formulation nor the use of a conventional chrome rinse for the steel substrate pretreatment before electrodeposition.
摘要翻译： 提供了一种可电沉积的组合物，其包含：（A）衍生自聚环氧化物的非胶凝阳离子树脂，其在树脂分子中含有阳离子盐基团和选自脂族羟基和伯和仲氨基的活性氢基团; 并且作为单独的组分（B）存在基本上不含游离异氰酸酯基团的完全封端的多异氰酸酯固化剂。 可电沉积组合物每克树脂固体含有约0.02-1.0毫当量酚羟基，每克树脂固体含约0.1-2.0毫当量β-羟基酯基。 当电沉积在钢基材上时，该组合物提供优异的耐腐蚀性，并且在电沉积之前不需要配方中的铅，也不使用常规的铬漂洗用于钢基材预处理。
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6.发明授权Method of making a cyclic guanidine from a guanidinium salt and a weak acid and coating compositions containing the same 有权从胍盐和弱酸制备环状胍的方法以及含有它们的涂料组合物公开(公告)号：US08148490B2
公开(公告)日：2012-04-03
申请号：US12720996
申请日：2010-03-10
申请人： Gregory J. McCollum , Charles R. Hickenboth , Richard F. Karabin , Thomas C. Moriarity , Steven R. Zawacky
发明人： Gregory J. McCollum , Charles R. Hickenboth , Richard F. Karabin , Thomas C. Moriarity , Steven R. Zawacky
IPC分类号： C08G59/00 , C07D471/00 , C07D293/00
CPC分类号： C08G59/4021 , C07D487/04 , C08G59/686 , C09D163/00
摘要： The present invention is directed to a method for preparing a cyclic guanidine comprising reacting (i) a guanidinium, (ii) a polyamine, and (iii) a weak acid. The present invention is also directed to a coating composition comprising the cyclic guanidine.
摘要翻译： 本发明涉及一种制备环状胍的方法，其包括使（ⅰ）胍，（ⅱ）多胺和（ⅲ）弱酸反应。 本发明还涉及包含环状胍的涂料组合物。
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7.发明申请METHOD OF MAKING A CYCLIC GUANIDINE FROM DICYANDIAMIDE AND COATING COMPOSITIONS CONTAINING SAME 有权制备来自二酰亚胺的环状官能团和含有它的涂料组合物的方法公开(公告)号：US20110224403A1
公开(公告)日：2011-09-15
申请号：US12720971
申请日：2010-03-10
申请人： Steven R. Zawacky , Charles R. Hickenboth , Richard F. Karabin , Gregory J. McCollum , Thomas C. Moriarity
发明人： Steven R. Zawacky , Charles R. Hickenboth , Richard F. Karabin , Gregory J. McCollum , Thomas C. Moriarity
IPC分类号： C08G59/00 , C07D471/04
CPC分类号： C07D471/04 , C07D487/04 , C08G59/4021 , C08G59/50 , C09D5/4461 , C09D5/4488
摘要： The present invention is directed to a method for preparing a cyclic guanidine comprising reacting (i) a cyanamide, (ii) a polyamine, and (iii) a weak acid. The present invention is also directed to a coating composition comprising the cyclic guanidine.
摘要翻译： 本发明涉及一种制备环状胍的方法，包括使（ⅰ）氰胺，（ⅱ）多胺和（ⅲ）弱酸反应。 本发明还涉及包含环状胍的涂料组合物。
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8.发明授权公开(公告)号：US07670500B2
公开(公告)日：2010-03-02
申请号：US12254072
申请日：2008-10-20
申请人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, Jr. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
发明人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, Jr. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
CPC分类号： C09D5/4419 , C08G59/56 , Y10T428/31507 , Y10T428/31529
摘要： The present invention provides a film-forming composition. The composition includes a reaction product of: a) a polyamine containing a primary amino group and a secondary amino group; and b) an acyclic carbonate. Also provided is a method of preparing a film-forming composition and an article coated with such compositions.
摘要翻译： 本发明提供一种成膜组合物。 该组合物包括：a）含有伯氨基和仲氨基的多胺的反应产物; 和b）无环碳酸酯。 还提供了制备成膜组合物的方法和用这种组合物涂覆的制品。
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公开(公告)号：US07459504B2
公开(公告)日：2008-12-02
申请号：US11101803
申请日：2005-04-08
申请人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, Jr. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
发明人： Venkatachalam Eswarakrishnan , Gregory J. McCollum , Matthew Scott , Geoffrey R. Webster, Jr. , Judith A. Orzechowski , Kevin J. Dufford , David Robert Fenn , Alan J. Kaylo , Thomas C. Moriarity
CPC分类号： C09D5/4419 , C08G59/56 , Y10T428/31507 , Y10T428/31529
摘要： The present invention provides a film-forming composition. The composition includes a reaction product of: a) a polyamine containing a primary amino group and a secondary amino group; and b) an acyclic carbonate. Also provided is a method of preparing a film-forming composition and an article coated with such compositions.
摘要翻译： 本发明提供一种成膜组合物。 该组合物包括：a）含有伯氨基和仲氨基的多胺的反应产物; 和b）无环碳酸酯。 还提供了制备成膜组合物的方法和用这种组合物涂覆的制品。
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10.发明授权Cationic resin and capped polyisocyanate curing agent suitable for use in electrodeposition 失效阳离子树脂和封端的多异氰酸酯固化剂适用于电沉积
公开(公告)号：US5582704A
公开(公告)日：1996-12-10
申请号：US334712
申请日：1994-11-04
申请人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
发明人： Joseph T. Valko , Philippe Faucher , Richard F. Karabin , Thomas C. Moriarity , V. Eswarakrishnan , Ellor J. Van Buskirk , Gregory J. McCollum , Raphael O. Kollah
IPC分类号： C09D163/00 , C08G18/08 , C08G18/32 , C08G18/42 , C08G18/58 , C08G18/64 , C08G18/80 , C09D5/08 , C09D5/44 , C09D175/04 , C09D175/12 , C25D13/04
CPC分类号： C08G18/3256 , C08G18/0814 , C08G18/0823 , C08G18/4294 , C08G18/581 , C08G18/584 , C08G18/6407 , C08G18/643 , C08G18/80 , C08G18/8009 , C08G18/8048 , C08G18/8064 , C09D5/4434 , C09D5/4453 , C09D5/4457
摘要： An electrodepositable composition is provided comprising:(A) a non-gelled cationic resin which is derived from a polyepoxide and which contains in the resin molecule cationic salt groups and active hydrogen groups selected from aliphatic hydroxyl and primary and secondary amino; and present as a separate component(B) a fully capped polyisocyanate curing agent containing substantially no free isocyanate groups, The electrodepositable composition contains from about 0.02 to 1.0 milliequivalents phenolic hydroxyl groups per gram of resin solids, and from about 0.1 to 2.0 milliequivalents beta-hydroxy ester groups per gram of resin solids. The composition provides excellent corrosion resistance when electrodeposited over steel substrates, and does not require lead in the formulation nor the use of a conventional chrome rinse for the steel substrate pretreatment before electrodeposition.
摘要翻译： 提供了一种可电沉积的组合物，其包含：（A）衍生自聚环氧化物的非胶凝阳离子树脂，其在树脂分子中含有阳离子盐基团和选自脂族羟基和伯和仲氨基的活性氢基团; 并且作为单独的组分（B）存在基本上不含游离异氰酸酯基团的完全封端的多异氰酸酯固化剂。该可电沉积组合物每克树脂固体含有约0.02-1.0毫当量酚羟基，和约0.1-2.0毫当量β- 羟基酯基团/克树脂固体。 当电沉积在钢基材上时，该组合物提供优异的耐腐蚀性，并且在电沉积之前不需要配方中的铅，也不使用常规的铬漂洗用于钢基材预处理。
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