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    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation
    3.
    发明授权
    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
    介孔金属硅酸盐分子筛的催化应用及其制备方法

    公开(公告)号：US06193943B1

    公开(公告)日：2001-02-27

    申请号：US08797718

    申请日：1997-02-11

    申请人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    发明人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    IPC分类号： C01B3338

    CPC分类号： B01J21/04 ,  B01J21/066 ,  B01J23/14 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/046 ,  B01J29/049 ,  B01J29/89 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/036 ,  C01B33/20 ,  C01B37/00 ,  C01B37/005 ,  C01B37/02 ,  C07C46/06 ,  C07C46/08

    摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X·I+ templating pathway (Pathway 3) and mild reaction conditions. These new mesoporous metallosilicate molecular sieves exhibit exceptional catalytic activity for peroxide hydroxylation of benzene and oxidation of substituted aromatics with kinetic diameters that are too large (larger than 6 Å) to access the pore structure of the conventional microporous transition metal-substituted molecular sieves such as titano- and vanadosilicates.

    摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合 同时通过简单的溶剂萃取提供中性模板的简便回收。 中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。 此外，已经使用介导的S + X.I +模板途径（途径3）和温和的反应条件制备了类似于MCM-41的六方晶过渡金属取代的催化剂。这些新的介孔金属硅酸盐分子筛显示出极好的催化活性 苯的过氧化羟基化和具有太大（大于6）的动力学直径的取代芳族化合物的氧化，以进入常规的微孔过渡金属取代的分子筛如钛和钒硅酸盐的孔结构。

    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation
    4.
    发明授权
    Catalytic applications of mesoporous metallosilicate molecular sieves and methods for their preparation 失效
    介孔金属硅酸盐分子筛的催化应用及其制备方法

    公开(公告)号：US06391278B1

    公开(公告)日：2002-05-21

    申请号：US09246739

    申请日：1999-02-08

    申请人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    发明人： Thomas J. Pinnavaia ,  Peter T. Tanev ,  Wenzhong Zhang ,  Jialiang Wang ,  Malama Chibwe

    IPC分类号： C01B3344

    CPC分类号： B01J21/04 ,  B01J21/066 ,  B01J23/14 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/046 ,  B01J29/049 ,  B01J29/89 ,  B01J35/1061 ,  B01J37/03 ,  B01J37/036 ,  C01B33/20 ,  C01B37/00 ,  C01B37/005 ,  C01B37/02 ,  C07C46/06 ,  C07C46/08

    摘要： A neutral templating route to mesoporous molecular sieves based on H-bonding and self-assembly between neutral primary amine or diamine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal and lamellar mesoporous silicas with site isolated transition metal centers. This templating approach allows for the preparation of hexagonal or hexagonal-like mesoporous oxidation catalysts with large framework wall thickness of at least about 17 Å, small elementary particle size (≦400 Å), and unique combinations of framework-confined mesopores and textural mesopores while at the same time providing for facile recovery of the neutral template by simple solvent extraction. The templating of neutral metallosilicate precursors (I°) with neutral diamine surfactants (S°—S°) affords thermally stable pillared lamellar metallosilicates exhibiting complementary framework-confined microporosity and textural mesoporosity while at the same time also providing for template recovery by solvent extraction. In addition, a hexagonal transition metal-substituted catalysts, analogous to MCM-41, have been prepared using the mediated S+X−I+ templating pathway (Pathway 3) and mild reaction conditions.

    摘要翻译： 已经使用了基于中性伯胺或二胺表面活性剂（S°）和中性无机前体（I°）之间的H键和自组装的介孔分子筛的中性模板化途径来制备具有位置分离转移的六方晶系和层状介孔二氧化硅 金属中心。 该模板方法允许制备具有至少约17埃的大框架壁厚度，小的基本粒度（<= 400）的六边形或六边形样介孔氧化催化剂，以及框架约束的中孔和结构中孔的独特组合 同时通过简单的溶剂萃取提供中性模板的简便回收。 中性金属硅酸盐前体（I°）与中性二胺表面活性剂（S°-S°）的模板提供了表现出互补的框架限制的微孔性和结构中等孔隙度的热稳定的柱状金属硅酸盐，同时也提供了通过溶剂萃取的模板回收。 此外，使用介导的S + X-I +模板途径（途径3）和温和的反应条件，已经制备了类似于MCM-41的六方晶过渡金属取代的催化剂。

    Ultrastable porous aluminosilicate structures
    7.
    发明授权
    Ultrastable porous aluminosilicate structures 有权
    超声波多孔铝硅酸盐结构

    公开(公告)号：US06746659B2

    公开(公告)日：2004-06-08

    申请号：US09792017

    申请日：2001-02-21

    申请人： Thomas J. Pinnavaia ,  Wenzhong Zhang ,  Yu Liu

    发明人： Thomas J. Pinnavaia ,  Wenzhong Zhang ,  Yu Liu

    IPC分类号： C01B3700

    CPC分类号： B01J29/005 ,  B01J29/0308 ,  B01J29/041 ,  B01J29/084 ,  B01J29/40 ,  B01J29/7007 ,  B01J2229/36 ,  B01J2229/62 ,  C01B33/38 ,  C01B39/04 ,  C01B39/48 ,  C10G11/05 ,  C10G47/16

    摘要： Mesoporous hexagonal, cubic, lamellar, wormhole, or cellular foam aluminosilicates, gallosilicates and titanosilicates derived from protozeolitic seeds using an ionic structure directing agent are described. The silicon and aluminum, gallium or titanium centers in the structures are stable so that the framework of the structure does not collapse when heated in the presence of water or water vapor (steam). The steam stable compositions can be used as catalysts for hydrocarbon conversions, including the fluidized bed catalytic cracking and the hydrocracking of petroleum oils, and other reactions of organic compounds.

    摘要翻译： 描述了使用离子结构导向剂衍生自原生球藻种子的介孔六方晶，立方，层状，虫洞或泡沫硅铝酸盐，硅酸盐硅酸盐和钛硅酸盐。 结构中的硅和铝，镓或钛中心是稳定的，使得当在水或水蒸气（蒸汽）存在下加热时，结构的框架不会塌陷。 蒸汽稳定组合物可用作烃转化的催化剂，包括流化床催化裂化和石油加氢裂化，以及有机化合物的其它反应。

    Ultra-stable lamellar mesoporous silica compositions and process for the prepration thereof
    10.
    发明授权
    Ultra-stable lamellar mesoporous silica compositions and process for the prepration thereof 失效
    超稳定层状介孔二氧化硅组合物及其制备方法

    公开(公告)号：US06528034B1

    公开(公告)日：2003-03-04

    申请号：US09436839

    申请日：1999-11-09

    申请人： Thomas J. Pinnavaia ,  Seong-Su Kim ,  Wenzhong Zhang

    发明人： Thomas J. Pinnavaia ,  Seong-Su Kim ,  Wenzhong Zhang

    IPC分类号： C01B3316

    CPC分类号： C01B37/02 ,  Y10T428/2993

    摘要： Novel lamellar mesoporous silica compositions which can contain functional inorganic elements and organic functional groups as part of the lamellar silica framework structure are described. The compositions are prepared using gemini amine surfactants as templates or structure directing agents. The compositions have novel high temperature and hydrothermal stability and unique fundamental particle structures.

    摘要翻译： 描述了可以包含功能性无机元素和作为层状二氧化硅骨架结构的一部分的有机官能团的新型层状介孔二氧化硅组合物。 使用双子胺表面活性剂作为模板或结构导向剂制备组合物。 该组合物具有新颖的高温和水热稳定性和独特的基本颗粒结构。