"> Avermectins and Avermectin Monosacharides Substituted in the 4'-and 4
    1.
    发明申请
    Avermectins and Avermectin Monosacharides Substituted in the 4'-and 4" Position Having Pesticidal Properties 有权
    在4'和4“位置具有农药性质的阿维菌素和阿维菌素单糖

    公开(公告)号:US20080194498A1

    公开(公告)日:2008-08-14

    申请号:US10568715

    申请日:2004-08-27

    IPC分类号: A01N43/90 C07H17/08 A01P17/00

    CPC分类号: A01N43/90 C07H19/01

    摘要: Described is a compound of the formula (1) wherein the bond between carbon atoms 22 and 23 is a single or double bond; m is 0 or 1; R1, is C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl; and either (A) R2 is —N(R3)R4, and (1) X is 0, wherein R3 is, for instance, hydrogen, unsubstituted or mono- to pentasubstituted C1-C12alkyl, and R4 is, for instance, mono- to pentasubstituted C1-C12alkyl, unsubstituted or mono- to pentasubstituted C3-C12cycloalkyl; or (2) X is S, wherein R3 is, for instance, hydrogen, unsubstituted or mono- to pentasubstituted C1-C12alkyl, and R4 is, for instance, hydrogen, unsubstituted or mono- to pentasubstituted C1-C12alkyl; or (3) X is 0 or S, wherein R3 and R4 together are, for instance, a three- to seven membered alkylene or a four- to seven-membered alkenylene bridge; or (B) R2 is OR5, X is 0 or S, wherein R5 is, for instance, C1-C12alkyl, mono- to pentasubstituted C1-C12alkyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof, in each case in free form or in salt form; such a compound demonstrates pesticidal activity.

    摘要翻译: 描述了式(1)的化合物,其中碳原子22和23之间的键是单键或双键; m为0或1; R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 3 -C 12烷基,C 3 -C 12烷基,C 3 -C 12烷基, >环烷基或C 2 -C 12 - 烯基; (A)R 2是-N(R 3)R 4,和(1)X是0,其中R 3是例如氢,未取代的或一至五取代的C 1 -C 12烷基,R 4是氢, 是例如一至五取代的C 1 -C 12烷基,未取代或单取代或五取代的C 3 -C 12烷基, 12环烷基; 或(2)X是S,其中R 3是例如氢,未取代的或一至五取代的C 1 -C 12 - 烷基和R 4是例如氢,未取代的或一至五取代的C 1 -C 12烷基; 或(3)X为0或S,其中R 3和R 4一起为例如三至七元亚烷基或四至七元亚烷基, 多元亚烯基桥; 或(B)R 2是OR 5,X是0或S,其中R 5是例如C 1 C 1 -C 12烷基,一至五取代C 1 -C 12烷基; 或者如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体在每种情况下都是游离形式或盐形式; 这种化合物显示出杀虫活性。

    Avermectin B1 and avermectin B1 monosaccharide derivatives having an alkoxymethyl substituent in the 4″-or 4′-position
    2.
    发明授权
    Avermectin B1 and avermectin B1 monosaccharide derivatives having an alkoxymethyl substituent in the 4″-or 4′-position 有权
    在4“ - 或4”位具有烷氧基甲基取代基的阿维菌素B1和除虫菌素B1单糖衍生物

    公开(公告)号:US08263566B2

    公开(公告)日:2012-09-11

    申请号:US13117292

    申请日:2011-05-27

    IPC分类号: A61K31/70 C07H17/04

    CPC分类号: C07H17/08 A61K31/7042

    摘要: What is described are a compound of the formula wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —NO2, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8-Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12-alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12-haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)—Z—R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.

    摘要翻译: 描述的是下式的化合物,其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片基 - ,C 3 -C 8 - 环烯基的取代基取代; C 3 -C 8卤代环烷基,C 1 -C 12烷氧基,C 1 -C 6烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8环烷氧基,C 1 -C 12卤代烷氧基,C 1 -C 12烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基, 卤代环烷基磺酰基,-NR4R6,-X-C(= Y)-R4,-X-C(= Y)-Z-R4,-P(= O)(OC1-C6-烷基)2,芳基,杂环基,芳氧基, 芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式; 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。

    Avermectin B1 and avermectin B1 monosaccharide derivatives having an alkoxymethyl substituent in the 4″-or 4′-position
    3.
    发明授权
    Avermectin B1 and avermectin B1 monosaccharide derivatives having an alkoxymethyl substituent in the 4″-or 4′-position 有权
    在4“ - 或4”位具有烷氧基甲基取代基的阿维菌素B1和除虫菌素B1单糖衍生物

    公开(公告)号:US08017589B2

    公开(公告)日:2011-09-13

    申请号:US12768280

    申请日:2010-04-27

    IPC分类号: A61K31/70 C07H17/04

    CPC分类号: C07H17/08 A61K31/7042

    摘要: What is described are a compound of the formula wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —NO2, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8-Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12-alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12-haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)—Z—R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.

    摘要翻译: 描述的是下式的化合物,其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片基 - ,C 3 -C 8 - 环烯基的取代基取代; C 3 -C 8卤代环烷基,C 1 -C 12烷氧基,C 1 -C 6烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8环烷氧基,C 1 -C 12卤代烷氧基,C 1 -C 12烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基, 卤代环烷基磺酰基,-NR4R6,-X-C(= Y)-R4,-X-C(= Y)-Z-R4,-P(= O)(OC1-C6-烷基)2,芳基,杂环基,芳氧基, 芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式; 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。

    "> AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4
    4.
    发明申请
    AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4"-OR 4'-POSITION 有权
    在4“-OR 4'-位置具有烷氧基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物

    公开(公告)号:US20100210574A1

    公开(公告)日:2010-08-19

    申请号:US12768280

    申请日:2010-04-27

    IPC分类号: A01N43/16 C07H17/08 A01P17/00

    CPC分类号: C07H17/08 A61K31/7042

    摘要: What is described are a compound of the formula wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —NO2, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8-Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12-alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12-haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)—Z—R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.

    摘要翻译: 描述的是下式的化合物,其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片基 - ,C 3 -C 8 - 环烯基的取代基取代; C 3 -C 8卤代环烷基,C 1 -C 12烷氧基,C 1 -C 6烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8环烷氧基,C 1 -C 12卤代烷氧基,C 1 -C 12烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基, 卤代环烷基磺酰基,-NR4R6,-X-C(= Y)-R4,-X-C(= Y)-Z-R4,-P(= O)(OC1-C6-烷基)2,芳基,杂环基,芳氧基, 芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式; 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。

    Avermectin and avemectin monosaccharide derivatives substituted in the 4″- or 4′-position having pesticidal properties
    5.
    发明授权
    Avermectin and avemectin monosaccharide derivatives substituted in the 4″- or 4′-position having pesticidal properties 有权
    在4“或4”位取代的具有杀虫性的阿维菌素和阿维菌素单糖衍生物

    公开(公告)号:US07632820B2

    公开(公告)日:2009-12-15

    申请号:US10543638

    申请日:2004-01-30

    CPC分类号: A01N43/90 C07H17/08

    摘要: Disclosed are compounds of the formulain which n is 0 or 1; X—Y is —CH═CH— or —CH2—CH2—; Z is —C(═O)—, —C(═S)— or —SO2—; R1 is C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl; and R2 is R3-Z-, R3—O-Z-, R4 or -Z-N(R6)(R7); Q is O or —N—R5; R3 and R4 are for example H, C1C12alkyl, C2-C12alkenyl, C2-C12alkynyl, C3-C12zcycloalkyl, C5-C12cycloalkenyl, aryl or heterocyclyl; R5 is for example H, C1-C8alkyl, hydroxy-C1-C8alkyl, C3-C8cycloalkyl, C2-C8alkenyl, C2-C8alkynyl, phenyl or benzyl; R6 and R7 are for example, H, unsubstituted or mono- to pentasubstituted C1-C12alkyl, unsubstituted or mono- to pentasubstituted C2-C12alkenyl or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof, in each case in free form or in salt form, are useful as pesticides.

    摘要翻译: 公开了n为0或1的甲醛化合物; X-Y是-CH-CH-或-CH 2 -CH 2 - ; Z是-C(-O) - , - C(-S) - 或-SO 2 - ; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R2为R3-Z-,R3-O-Z-,R4或-Z-N(R6)(R7); Q是O或-N-R5; R 3和R 4例如是H,C 1 -C 12烷基,C 2 -C 12烯基,C 2 -C 12炔基,C 3 -C 12环烷基,C 5 -C 12环烯基,芳基或杂环基; R5是例如H,C1-C8烷基,羟基-C1-C8烷基,C3-C8环烷基,C2-C8链烯基,C2-C8炔基,苯基或苄基; R 6和R 7为例如未取代的或未被取代的一价或五价取代的C 1 -C 12烷基,未被取代的或一至五取代的C 2 -C 12链烯基或(如果合适的话)E / Z异构体,E / Z异构体混合物和/或其互变异构体, 在每种情况下以游离形式或盐形式,都可用作农药。

    "> Avermectin and avemectin monosaccharide derivatives substituted in the 4
    6.
    发明申请
    Avermectin and avemectin monosaccharide derivatives substituted in the 4"-or 4'-position having pesticidal properties 有权
    在4“ - 或4”位取代的具有杀虫性的阿维菌素和阿维菌素单糖衍生物

    公开(公告)号:US20060166824A1

    公开(公告)日:2006-07-27

    申请号:US10543638

    申请日:2004-01-30

    IPC分类号: A01N43/04 A61K31/7048

    CPC分类号: A01N43/90 C07H17/08

    摘要: Disclosed are compounds of the formula in which n is 0 or 1; X—Y is —CH═CH— or —CH2—CH2—; Z is —C(═O)—, —C(═S)— or —S02—; R1 is C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl; and R2 is R3-Z-, R3—O-Z-, R4 or -Z-N(R6)(R7); Q is O or —N—R5; R3 and R4 are for example H, C1C12alkyl, C2-C12alkenyl, C2-C12alkynyl, C3-C12zcycloalkyl, C5-C12cycloalkenyl, aryl or heterocyclyl; R5 is for example H, C1-C8alkyl, hydroxy-C1-C8alkyl, C3-C8cycloalkyl, C2-C8alkenyl, C2-C8alkynyl, phenyl or benzyl; R6 and R7 are for example, H, unsubstituted or mono- to pentasubstituted C1-C12alkyl, unsubstituted or mono- to pentasubstituted C2-C12alkenyl or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof, in each case in free form or in salt form, are useful as pesticides.

    摘要翻译: 公开了下式的化合物,其中n为0或1; X-Y是-CH-CH-或-CH 2 -CH 2 - 。 Z是-C(-O) - , - C(-S) - 或-SO 2 - 。 R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 1 -C 12烷基,C 3 -C 12烷基, 环烷基或C 2 -C 12 - 烯基; 和R 2是R 3 -Z-,R 3 -OZ-,R 4或-ZN( R 6)(R 7); Q是O或-N-R 5; R 3和R 4是例如H,C 1 -C 12烷基,C 2, C 1 -C 12亚烷基,C 2 -C 12炔基,C 3 -C 12链烯基,C 2 -C 12亚炔基,C 3 -C 12亚烷基, 12个环烷基,C 5 -C 12环烯基,芳基或杂环基; R 5是例如H,C 1 -C 8烷基,羟基-C 1 -C 3 C 1 -C 8烷基,C 3 -C 8环烷基,C 2 -C 8链烯基,C 1 -C 8烷基, C 2 -C 8炔基,苯基或苄基; R 6和R 7是例如H,未取代的或一至五取代的C 1 -C 12 - 烷基,未取代的或一至五取代的C 2 -C 12链烯基,或者如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体, 在每种情况下以游离形式或盐形式,都可用作农药。

    Avermectin and avermectin monosaccharide derivatives substituted in the 4″-or 4′-position having pesticidal properties
    7.
    发明授权
    Avermectin and avermectin monosaccharide derivatives substituted in the 4″-or 4′-position having pesticidal properties 有权
    在4“ - 或4”位取代的具有杀虫性的阿维菌素和阿维菌素单糖衍生物

    公开(公告)号:US07678740B2

    公开(公告)日:2010-03-16

    申请号:US10543637

    申请日:2004-01-30

    CPC分类号: A01N43/90 C07H17/08

    摘要: What is described are a compound of the formula (I) Wherein U is —N(R2)OR3 or —N+(O−)═C(RE)RZ); n is 0 or 1; X—Y is —CH═CH— or —CH2—CH2—; R1 is C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl; R2 and R3 are, for example; independently from each other, —Q, —C(═O)—Z—Q or —CN; RZ and RE are, independently from each other, —Q, —C(═O)—Z—Q or —CN; or RZ and RE together are a three- to seven membered alkylene or alkenylene bridge, which is unsubstituted or mono- to tri-substituted; Z is a bond, O or —NR4—; Q is H, C1-C12alkyl, C2-C12alkenyl, C2-C12alkynyl, C3-C12-Cycloalkyl, C5-C12-cycloalkenyl, aryl, or heterocyclyl, which are unsubstituted or mono- to pentasubstituted; R4 is for example H, C1-C8alkyl, hydroxy-C1-C8alkyl, C3-C8cycloalkyl or C2-C8alkenyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.

    摘要翻译: 描述的是式(I)的化合物,其中U是-N(R 2)OR 3或-N +(O-)= C(RE)R Z); n为0或1; X-Y是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R2和R3例如是: 独立地为-Q,-C(= O)-Z-Q或-CN; RZ和RE彼此独立地为-Q,-C(= O)-Z-Q或-CN; 或RZ和RE一起是三至七元的亚烷基或亚烯基桥,其是未取代的或一至三取代的; Z是O或-NR4-键; Q是未被取代或被一取代或五取代的H,C 1 -C 12烷基,C 2 -C 12烯基,C 2 -C 12炔基,C 3 -C 12环烷基,C 5 -C 12 - 环烯基,芳基或杂环基, R4是例如H,C1-C8烷基,羟基-C1-C8烷基,C3-C8环烷基或C2-C8链烯基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。

    Avermectin b1 monosaccharide derivatives
    8.
    发明申请
    Avermectin b1 monosaccharide derivatives 有权
    阿维菌素b1单糖衍生物

    公开(公告)号:US20060229263A1

    公开(公告)日:2006-10-12

    申请号:US10560390

    申请日:2004-06-15

    IPC分类号: A01N43/04 C07H17/08

    CPC分类号: C07H19/01 C07H17/08

    摘要: A compound of formula (I) wherein the bond between carbon atoms 22 and 23 may be a single or a double bond; R1 is C1-C12alkyl, C3-C8cycloalkyl, or C2-C12alkenyl; R2 and R3 are, for example, independently of each other hydrogen, C1-C12alkyl, C3-C12cycloalkyl, C2-C12alkenyl, C2-C12alkynyl, aryl or heteroaryl; and, where applicable, to E/Z isomers, mixtures of E/Z isomers, diastereomers and/or tautomers, in each case in free form or in salt form; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers; and a method of controlling pests using those compositions are described.

    摘要翻译: 式(I)的化合物,其中碳原子22和23之间的键可以是单键或双键; R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 1 -C 12烷基,C 3 -C 12烷基, 环烷基或C 2 -C 12 - 烯基; R 2和R 3是例如彼此独立的氢,C 1 -C 12烷基 C 3 -C 12环烷基,C 2 -C 12链烯基,C 2 -C 12环烷基,C 2 -C 12亚烷基, 炔基,芳基或杂芳基; 在适用的情况下,E / Z异构体,E / Z异构体,非对映异构体和/或互变异构体的混合物,在每种情况下为游离形式或盐形式; 其中活性成分选自那些化合物及其互变异构体的杀虫组合物; 并描述了使用这些组合物来控制害虫的方法。

    Avermectin B1 monosaccharide derivatives
    9.
    发明授权
    Avermectin B1 monosaccharide derivatives 有权
    阿维菌素B1单糖衍生物

    公开(公告)号:US07521429B2

    公开(公告)日:2009-04-21

    申请号:US10560390

    申请日:2004-06-15

    IPC分类号: A61K31/70 C07H17/08

    CPC分类号: C07H19/01 C07H17/08

    摘要: A compound of formula (I) wherein the bond between carbon atoms 22 and 23 may be a single or a double bond; R1 is C1-C12alkyl, C3-C8cycloalkyl, or C2-C12alkenyl; R2 and R3 are, for example, independently of each other hydrogen, C1-C12alkyl, C3-C12cycloalkyl, C2-C12alkenyl, C2-C12alkynyl, aryl or heteroaryl; and, where applicable, to E/Z isomers, mixtures of E/Z isomers, diastereomers and/or tautomers, in each case in free form or in salt form; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers; and a method of controlling pests using those compositions are described.

    摘要翻译: 式(I)的化合物,其中碳原子22和23之间的键可以是单键或双键; R1是C1-C12烷基,C3-C8环烷基或C2-C12链烯基; R 2和R 3例如彼此独立地为氢,C 1 -C 12烷基,C 3 -C 12环烷基,C 2 -C 12烯基,C 2 -C 12炔基,芳基或杂芳基; 在适用的情况下,E / Z异构体,E / Z异构体,非对映异构体和/或互变异构体的混合物,在每种情况下为游离形式或盐形式; 其中活性成分选自那些化合物及其互变异构体的杀虫组合物; 并描述了使用这些组合物来控制害虫的方法。

    "> AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4
    10.
    发明申请
    AVERMECTIN B1 AND AVERMECTIN B1 MONOSACCHARIDE DERIVATIVES HAVING AN ALKOXYMETHYL SUBSTITUENT IN THE 4"-OR 4'-POSITION 有权
    在4“-OR 4'-位置具有烷氧基取代基的AVERMECTIN B1和AVERMECTIN B1单糖衍生物

    公开(公告)号:US20110230429A1

    公开(公告)日:2011-09-22

    申请号:US13117292

    申请日:2011-05-27

    IPC分类号: A01N43/22 C07H17/08 A01P7/00

    CPC分类号: C07H17/08 A61K31/7042

    摘要: What is described are a compound of the formula wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —NO2, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8-Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12-alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12-haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)—Z—R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.

    摘要翻译: 描述的是下式的化合物,其中n是0或1; A-B是-CH = CH-或-CH 2 -CH 2 - ; R1是C1-C12-烷基,C3-C8-环烷基或C2-C12-烯基; R2是例如C1-C12-烷基,C2-C12-烯基或C2-C12-炔基; 其任选被一至五个选自OH,卤素,CN,-N 3,-NO 2,C 3 -C 8 - 环烷基,降冰片基 - ,C 3 -C 8 - 环烯基的取代基取代; C 3 -C 8卤代环烷基,C 1 -C 12烷氧基,C 1 -C 6烷氧基-C 1 -C 6 - 烷氧基,C 3 -C 8环烷氧基,C 1 -C 12卤代烷氧基,C 1 -C 12烷硫基,C 3 -C 8环烷硫基, C 1 -C 12烷基亚磺酰基,C 3 -C 8环烷基亚磺酰基,C 1 -C 12卤代烷基亚磺酰基,C 3 -C 8卤代环烷基亚磺酰基,C 1 -C 12烷基磺酰基,C 3 -C 8环烷基磺酰基,C 1 -C 12卤代烷基磺酰基, 卤代环烷基磺酰基,-NR4R6,-X-C(= Y)-R4,-X-C(= Y)-Z-R4,-P(= O)(OC1-C6-烷基)2,芳基,杂环基,芳氧基, 芳硫基和杂环氧基; R3是例如任选取代的H,C 1 -C 12 - 烷基或C 1 -C 12 - 烷基,并且在适用的情况下,E / Z异构体,E / Z异构体和/或互变异构体的混合物,在每种情况下为游离形式或 盐形式; 一种制备和使用这些化合物及其互变异构体的方法; 活性化合物选自这些化合物及其互变异构体的农药; 以及制备这些化合物和组合物的方法,以及这些化合物和组合物的用途。