Avermectin b1 monosaccharide derivatives
    1.
    发明申请
    Avermectin b1 monosaccharide derivatives 有权
    阿维菌素b1单糖衍生物

    公开(公告)号:US20060229263A1

    公开(公告)日:2006-10-12

    申请号:US10560390

    申请日:2004-06-15

    IPC分类号: A01N43/04 C07H17/08

    CPC分类号: C07H19/01 C07H17/08

    摘要: A compound of formula (I) wherein the bond between carbon atoms 22 and 23 may be a single or a double bond; R1 is C1-C12alkyl, C3-C8cycloalkyl, or C2-C12alkenyl; R2 and R3 are, for example, independently of each other hydrogen, C1-C12alkyl, C3-C12cycloalkyl, C2-C12alkenyl, C2-C12alkynyl, aryl or heteroaryl; and, where applicable, to E/Z isomers, mixtures of E/Z isomers, diastereomers and/or tautomers, in each case in free form or in salt form; pesticidal compositions in which the active ingredient has been selected from those compounds and their tautomers; and a method of controlling pests using those compositions are described.

    摘要翻译: 式(I)的化合物,其中碳原子22和23之间的键可以是单键或双键; R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 1 -C 12烷基,C 3 -C 12烷基, 环烷基或C 2 -C 12 - 烯基; R 2和R 3是例如彼此独立的氢,C 1 -C 12烷基 C 3 -C 12环烷基,C 2 -C 12链烯基,C 2 -C 12环烷基,C 2 -C 12亚烷基, 炔基,芳基或杂芳基; 在适用的情况下,E / Z异构体,E / Z异构体,非对映异构体和/或互变异构体的混合物,在每种情况下为游离形式或盐形式; 其中活性成分选自那些化合物及其互变异构体的杀虫组合物; 并描述了使用这些组合物来控制害虫的方法。

    "> Avermectins substituted in the 4
    2.
    发明申请
    Avermectins substituted in the 4" and 4'-positions having pesticidal properties 有权
    在4“和4”位取代的阿维菌素具有杀虫特性

    公开(公告)号:US20060154879A1

    公开(公告)日:2006-07-13

    申请号:US10544274

    申请日:2004-02-03

    IPC分类号: A01N43/04 C07H17/08

    CPC分类号: C07H17/08

    摘要: What is described are a compound of the formula (I) Wherein A-B is —CH═CH— or —CH2—CH2—; n is 0 or 1; R1, is C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl; R2 and R3 for instance are either, (i) independently from each other for instance -Q, —C(═Y)-Q, or —C(═Y)—O-Q; or (ii) together form with the nitrogen atom to which they are bound a three- to seven-membered ring, (iii) together are ═C(R4)R5; R4 and R5 are, independently from each other, for instance -Q, —C(═Y)-Q, or —C(═Y)—O-Q; Y is O or S; Q is for instance H or unsubstituted or mono- to pentasubstituted C1-C12alkyl; or, if appropriate, an E/Z isomer, E/Z isomer mixture and/or tautomer thereof; a process for preparing these compounds, their isomers and tautomers and the use of these compounds, their isomers and tautomers; pesticidal compositions whose active compound is selected from these compounds and their tautomers; intermediates for the preparation of the said compounds of the formula (I), methods for the preparation of the compounds of the formula (I), and a method for controlling pests using these compositions.

    摘要翻译: 描述的是式(I)的化合物,其中A-B是-CH-CH-或-CH 2 -CH 2 - 。 n为0或1; R 1是C 1 -C 12烷基,C 3 -C 8烷基,C 3 -C 12烷基,C 3 -C 12烷基,C 3 -C 12烷基, >环烷基或C 2 -C 12 - 烯基; 例如,R 2和R 3是(i)彼此独立地例如-Q,-C(-Y)-Q或-C( - Y)-OQ; 或(ii)与其结合的氮原子一起形成三至七元环,(iii)一起为-C(R 4)R 5 >; R 4和R 5各自独立地为例如-Q,-C(-Y)-Q或-C(-Y)-O-Q; Y为O或S; Q是例如H或未被取代或单取代或未取代的C 1 -C 12烷基; 或者,如果合适的话,E / Z异构体,E / Z异构体混合物和/或其互变异构体; 制备这些化合物,其异构体和互变异构体的方法以及这些化合物,其异构体和互变异构体的用途; 活性化合物选自这些化合物及其互变异构体的杀虫组合物; 用于制备所述式(I)化合物的中间体,式(I)化合物的制备方法和使用这些组合物来控制害虫的方法。

    "> Avermectin b1 and avermectin b1 monosaccharide derivatives having an alkoxymethyl substitutent in the 4

    公开(公告)号:US20060148729A1

    公开(公告)日:2006-07-06

    申请号:US10539274

    申请日:2003-12-19

    IPC分类号: A01N43/04 C07H17/08

    CPC分类号: C07H17/08 A61K31/7042

    摘要: What is described are a compound of the formula (I): wherein n is 0 or 1; A-B is —CH═CH— or —CH2—CH2—; R1 is C1-C12-alkyl, C3-C8-cycloalkyl or C2-C12-alkenyl; R2 is for example C1-C12-alkyl, C2-C12-alkenyl or C2-C12-alkinyl; which are optionally substituted with one to five substituents selected from the group consisting of OH, halogen, CN, —N3, —N02, C3-C8-Cycloalkyl, norbornylenyl-, C3-C8Cycloalkenyl; C3-C8-halocycloalkyl, C1-C12-alkoxy, C1-C6-alkoxy-C1-C6-alkoxy, C3-C8-cycloalkoxy, C1-C12-haloalkoxy, C1-C12-alkylthio, C3-C8-cycloalkylthio, C1-C12-haloalkylthio, C1-C12 alkylsulfinyl, C3-C8-cycloalkylsulfinyl, C1-C12-haloalkylsulfinyl, C3-C8-halocycloalkylsulfinyl, C1-C12-alkylsulfonyl, C3-C8-cycloalkylsulfonyl, C1-C12haloalkylsulfonyl, C3-C8-halocycloalkylsulfonyl, —NR4R6, —X—C(═Y)—R4, —X—C(═Y)-Z-R4, —P(═O)(OC1-C6-alkyl)2, aryl, heterocyclyl, aryloxy, arylthio and heterocyclyloxy; R3 is for example H, C1-C12-alkyl or C1-C12-alkyl which is optionally substituted and, where applicable, to E/Z isomers, mixtures of E/Z isomers and/or tautomers, in each case in free form or in salt form; a process for preparing and using these compounds and their tautomers; pesticides whose active compound is selected from these compounds and their tautomers; and a process for preparing these compounds and compositions, and the use of these compounds and compositions.

    "> Avermectin And Avermectin Monosaccharide Substituted In The 4
    4.
    发明申请
    Avermectin And Avermectin Monosaccharide Substituted In The 4"- And 4" Position Respectively 有权
    阿维菌素和阿维菌素单糖在4“和4”位置分别取代

    公开(公告)号:US20080051353A1

    公开(公告)日:2008-02-28

    申请号:US10599671

    申请日:2005-03-09

    CPC分类号: A01N43/90 C07H19/01

    摘要: A compound of the formula (I) wherein the bond between carbon atoms 22 and 23 indicated with a broken line is a single or double bond, m is 0 or 1, R1 represents a C1-C12alkyl, C3-C8cycloalkyl or C2-C12alkenyl group, R2 represents a hydrocarbyl group or a substituted hydrocarbyl group, and R3 and R4 represent, independently of each other, hydrogen or a chemical constituent, or either R2 and R3 together or R3 and R4 together represent a three- to seven-membered alkylene or a four- to seven-membered alkenylene bridge, for each of which at least one, preferably a CH2 group may be replaced by O, S or NR6 where R6 represents hydrogen or a hydrocarbyl group or a substituted hydrocarbyl group; or, if appropriate, an E/Z isomer and/or tautomer of the compound of formula (I), in each case in free form or in salt form.

    摘要翻译: 式(I)的化合物,其中用虚线表示的碳原子22和23之间的键是单键或双键,m是0或1,R 1表示C 1〜 C 1 -C 12烷基,C 3 -C 8 - 环烷基或C 2 -C 3烷基, R 12是链烯基,R 2表示烃基或取代的烃基,R 3和R 4代表 独立地是氢或化学成分,或R 2和R 3一起或R 3和R 4 一起代表三至七元亚烷基或四至七元亚烯基桥,其中至少一个,优选CH 2基团可以被O ,S或NR 6,其中R 6表示氢或烃基或取代的烃基; 或者如果合适的话,式(I)化合物的E / Z异构体和/或互变异构体在各种情况下都是游离形式或盐形式。

    Chemical compounds
    5.
    发明授权
    Chemical compounds 失效
    化合物

    公开(公告)号:US08524896B2

    公开(公告)日:2013-09-03

    申请号:US12921000

    申请日:2009-03-02

    摘要: A compound of the formula (I) where, for example, W, X and Y are each CH; R1 and R6 together with the adjacent nitrogen forms a 3 to 10-membered saturated ring, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms and/or heteroatom groups as ring members, independently of one another, selected from the group consisting of sulfur, CO, SO, SO2 and N—R7 and/or the ring may carry 1, 2 or 3 radicals, independently of one another, each selected, for example, from the group consisting of halogen, cyano, nitro, amino, and C1-C6-alkyl. R2 is, for example, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and R7 is for example, R10C(═O), C1-C6 alkyl or C1-C6-haloalkyl; and/or salts thereof; and their use as pesticidal agents.

    摘要翻译: 式(I)的化合物,其中例如W,X和Y各自为CH; R1和R6与相邻的氮一起形成3至10元饱和环,其中除了氮和碳环成员之外,环可以独立地包含1,2或3个杂原子和/或杂原子基团作为环成员 彼此相互选择,选自硫,CO,SO,SO 2和N-R 7和/或环可以彼此独立地携带1,2或3个基团,每个选自例如 的卤素,氰基,硝基,氨基和C 1 -C 6 - 烷基。 R 2是例如卤素,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6 - 烷氧基,C 1 -C 6 - 卤代烷氧基或C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基, R 10 C(= O),C 1 -C 6烷基或C 1 -C 6 - 卤代烷基; 和/或其盐; 并将其用作杀虫剂。

    CHEMICAL COMPOUNDS
    6.
    发明申请
    CHEMICAL COMPOUNDS 失效
    化学化合物

    公开(公告)号:US20110009261A1

    公开(公告)日:2011-01-13

    申请号:US12921000

    申请日:2009-03-02

    摘要: A compound of the formula (I) where, for example, W, X and Y are each CH; R1 and R6 together with the adjacent nitrogen forms a 3 to 10-membered saturated ring, wherein the ring may contain, in addition to the nitrogen and carbon ring members, 1, 2 or 3 heteroatoms and/or heteroatom groups as ring members, independently of one another, selected from the group consisting of sulfur, CO, SO, SO2 and N—R7 and/or the ring may carry 1, 2 or 3 radicals, independently of one another, each selected, for example, from the group consisting of halogen, cyano, nitro, amino, and C1-C6-alkyl. R2 is, for example, halogen, C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy or C1-C6-alkoxy-C1-C6-alkoxy, and R7 is for example, R10C(═O), C1-C6 alkyl or C1-C6-haloalkyl; and/or salts thereof; and their use as pesticidal agents.

    摘要翻译: 式(I)的化合物,其中例如W,X和Y各自为CH; R1和R6与相邻的氮一起形成3至10元饱和环,其中除了氮和碳环成员之外,环可以独立地包含1,2或3个杂原子和/或杂原子基团作为环成员 彼此相互选择,选自硫,CO,SO,SO 2和N-R 7和/或环可以彼此独立地携带1,2或3个基团,每个选自例如 的卤素,氰基,硝基,氨基和C 1 -C 6 - 烷基。 R 2是例如卤素,C 1 -C 6烷基,C 1 -C 6卤代烷基,C 1 -C 6 - 烷氧基,C 1 -C 6 - 卤代烷氧基或C 1 -C 6 - 烷氧基-C 1 -C 6 - 烷氧基, R 10 C(= O),C 1 -C 6烷基或C 1 -C 6 - 卤代烷基; 和/或其盐; 并将其用作杀虫剂。