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1.发明申请METHOD FOR PRODUCING 1-ALKOXY-2-METHYL-1-OXOPROPAN-2-YL (METH)ACRYLATE 审中-公开1-烷氧基-2-甲基-1-氧杂戊-2-炔（甲基）丙烯酸酯的制备方法公开(公告)号：US20120232222A1
公开(公告)日：2012-09-13
申请号：US13497631
申请日：2010-09-07
申请人： Thorben Schütz , Joachim Knebel , Guenther Graeff , Ruediger Carloff , Roger Recktenwald , Volker Herzog
发明人： Thorben Schütz , Joachim Knebel , Guenther Graeff , Ruediger Carloff , Roger Recktenwald , Volker Herzog
IPC分类号： C08F8/14
CPC分类号： C07C69/67 , C07C67/03 , C08F220/26 , C07C69/734
摘要： The invention provides a process for preparing 1-alkoxy-2-methyl-1-oxopropan-2-yl(meth)acrylate, e.g. 1-methoxy-2-methyl-1-oxopropan-2-yl(meth)acrylate, by transesterifying alkyl α-hydroxyisobutyrates. Copolymerization of such monomers in the preparation of poly(meth)acrylate-based moulding materials improves the heat distortion resistance thereof.
摘要翻译： 本发明提供了制备1-甲氧基-2-甲基-1-氧代丙-2-基（甲基）丙烯酸酯的方法。 1-甲氧基-2-甲基-1-氧代丙-2-基（甲基）丙烯酸酯，通过酯交换α-羟基异丁酸烷基酯。 在制备聚（甲基）丙烯酸酯基成型材料时，这些单体的共聚提高了其耐热变形性。
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公开(公告)号：US20080300373A1
公开(公告)日：2008-12-04
申请号：US12093744
申请日：2006-10-11
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
摘要： The invention relates to a process for purifying (meth)acrylates.
摘要翻译： 本发明涉及纯化（甲基）丙烯酸酯的方法。
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3.发明授权Process for the preparation of (meth)acrylates of tetra- or polyhydric alcohols 失效制备四元醇或多元醇的（甲基）丙烯酸酯的方法公开(公告)号：US07521578B2
公开(公告)日：2009-04-21
申请号：US11995406
申请日：2006-08-16
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
IPC分类号： C07C67/30
摘要： Process for the preparation of acrylic and methacrylic acid esters by transesterification of (meth)acrylic acid esters of the formula I: where R1 is H or CH3 and R2 is an alkyl radical having 1 to 40 carbon atoms, with alkanols which have four or more esterifiable hydroxyl groups, characterized in that 0.01 to 10% by weight, based on the total reaction mixture, of lithium amide catalysts are used as transesterification catalyst.
摘要翻译： 通过式（I）的（甲基）丙烯酸酯的酯交换反应制备丙烯酸和甲基丙烯酸酯的方法：其中R 1是H或CH 3，R 2是具有1至40个碳原子的烷基，其中烷基醇具有四个或更多个 酯化羟基，其特征在于使用基于总反应混合物的0.01至10重量％的氨基化锂催化剂作为酯交换催化剂。
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公开(公告)号：US09340484B2
公开(公告)日：2016-05-17
申请号：US14351667
申请日：2012-11-20
发明人： Joachim Knebel , Thorben Schuetz , Guenther Graeff , Thomas Ohl
CPC分类号： C07C67/04 , C07C2602/42 , C07C2603/68 , C07C69/54
摘要： Process for preparing bicyclic or tricyclic (meth)acrylates by reacting (meth)acrylic acid with a bicyclic or tricyclic hydrocarbon which contains at least one double bond using montmorillonite as catalyst.
摘要翻译： 通过使用蒙脱石作为催化剂使（甲基）丙烯酸与含有至少一个双键的双环或三环烃反应制备双环或三环（甲基）丙烯酸酯的方法。
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公开(公告)号：US07750179B2
公开(公告)日：2010-07-06
申请号：US12093744
申请日：2006-10-11
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
IPC分类号： C07C67/48
摘要： The invention relates to a process for purifying (meth)acrylates.
摘要翻译： 本发明涉及纯化（甲基）丙烯酸酯的方法。
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6.发明申请Process for the Preparation of (Meth)Acrylates of Tetra-Or Polyhydric Alcohols 失效四 - 或多元醇（甲基）丙烯酸酯的制备方法公开(公告)号：US20080194861A1
公开(公告)日：2008-08-14
申请号：US11995406
申请日：2006-08-16
申请人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
发明人： Bardo Schmitt , Joachim Knebel , Guenther Graeff
IPC分类号： C07C69/54
摘要： Process for the preparation of acrylic and methacrylic acid esters by transesterification of (meth)acrylic acid esters of the formula I: where R1 is H or CH3 and R2 is an alkyl radical having 1 to 40 carbon atoms, with alkanols which have four or more esterifiable hydroxyl groups, characterized in that 0.01 to 10% by weight, based on the total reaction mixture, of lithium amide catalysts are used as transesterification catalyst.
摘要翻译： 通过式（I）的（甲基）丙烯酸酯的酯交换制备丙烯酸和甲基丙烯酸酯的方法：其中R 1是H或CH 3，R > 2是具有1至40个碳原子的烷基，其中链烷醇具有四个或更多个可酯化的羟基，其特征在于基于总反应混合物的氨基甲酸锂催化剂为0.01至10重量％ 用作酯交换催化剂。
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公开(公告)号：US08288583B2
公开(公告)日：2012-10-16
申请号：US12306019
申请日：2007-06-01
申请人： Uwe Boehmke , Klaus Schimossek , Detlef Bloos , Michael Neusius , Stephan Massoth , Guenther Graeff , Alexander Dardin , Matthias Fischer , Volker Stephan
发明人： Uwe Boehmke , Klaus Schimossek , Detlef Bloos , Michael Neusius , Stephan Massoth , Guenther Graeff , Alexander Dardin , Matthias Fischer , Volker Stephan
IPC分类号： C07C67/02
摘要： The present invention relates to processes for preparing carboxylic acid derivatives, comprising the reaction of at least one carboxylic acid and/or of a carboxylic acid derivative with at least one alcohol and/or an amine in the presence of a metal-containing catalyst, wherein, after the reaction has ended, the metal-containing catalyst is contacted with water and a superabsorbent, the contacting of the catalyst with the water leading to hydrolysis of the catalyst. The present invention further relates to the use of superabsorbents for removing a metal-containing catalyst from a mixture after hydrolysis of the catalyst.
摘要翻译： 本发明涉及制备羧酸衍生物的方法，包括在含金属的催化剂存在下使至少一种羧酸和/或羧酸衍生物与至少一种醇和/或胺反应，其中 在反应结束后，含金属的催化剂与水和超吸收剂接触，催化剂与水的接触导致催化剂的水解。 本发明还涉及超吸收剂在催化剂水解后从混合物中除去含金属催化剂的用途。
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