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    USE OF GRAFT POLYMERS
    2.
    发明申请
    USE OF GRAFT POLYMERS 有权
    聚合物的使用

    公开(公告)号：US20070213237A1

    公开(公告)日：2007-09-13

    申请号：US11572181

    申请日：2005-06-23

    申请人： Markus Scherer ,  Klaus Hedrich ,  Alexander Dardin ,  Michael Muller ,  Thorsten Stoehr ,  Boris Eisenberg

    发明人： Markus Scherer ,  Klaus Hedrich ,  Alexander Dardin ,  Michael Muller ,  Thorsten Stoehr ,  Boris Eisenberg

    IPC分类号： C10M145/14

    CPC分类号： C10M149/10 ,  C08L51/06 ,  C10M149/02 ,  C10M161/00 ,  C10M2209/084 ,  C10M2217/02 ,  C10M2217/028 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/06 ,  C10N2230/43 ,  C10N2240/04 ,  C10N2240/08 ,  C10N2240/10

    摘要： The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.

    摘要翻译： 本发明涉及通过两步聚合获得的接枝聚合物的用途。 在第一阶段中，通过自由基聚合含有0至40重量％的一种或几种式（I）的烯键式不饱和酯化合物，其中R表示氢或甲基， SUP> 1表示包含1至5个碳原子的直链或支链烷基，R 2和R 3独立地表示氢或式-COOR基团 '，其中R'表示氢或包含1至5个碳原子的烷基，60至100重量％的一种或几种式（II）的烯属不饱和酯化合物，其中R表示氢或甲基，R 4 代表含有6至40个碳原子的直链或支链烷基，R 5和R 6独立代表氢或式-COOR'基团，其中 R'表示氢或含有6〜40个碳原子的烷基，0〜40重量％的共聚单体，百分比 年龄相对于单体组合物A）的重量。 在第二阶段中，将包含20至100重量％的至少一种包含至少一个含氮基团的单体的单体组合物B）接枝到接枝基上以减少润滑油组合物中的磨损。 所述接枝聚合物包含最多200ppm的硫，而单体组合物A）和单体组合物B）之间的重量比在99.7:0.3和80:20之间。

    Lubricating oil composition with good frictional properties
    6.
    发明授权
    Lubricating oil composition with good frictional properties 有权
    具有良好摩擦性能的润滑油组合物

    公开(公告)号：US08288327B2

    公开(公告)日：2012-10-16

    申请号：US10550764

    申请日：2004-01-24

    申请人： Alexander Dardin ,  Michael Mueller ,  Boris Eisenberg

    发明人： Alexander Dardin ,  Michael Mueller ,  Boris Eisenberg

    IPC分类号： C10M145/14 ,  C10M145/10

    CPC分类号： C10M149/06 ,  C08F293/005 ,  C10M145/14 ,  C10M151/02 ,  C10M177/00 ,  C10M2209/084 ,  C10M2217/02 ,  C10M2217/023 ,  C10M2217/024 ,  C10M2221/02 ,  C10N2230/02 ,  C10N2230/06 ,  C10N2270/00

    摘要： The invention relates to a lubricating oil composition with good frictional properties, the composition having a lubricating oil and at least one additive having friction-reducing properties. The additive with friction-reducing properties is a block copolymer having hydrophobic segments P and polar segments D. The hydrophobic segments are obtained by polymerization of monomer compositions having a) between 0 and 40 wt. %, in relation to the weight of the monomer compositions for producing the hydrophobic segments, of at least one ethylenically unsaturated ester compound of formula (I), in which R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical having between 1 and 5 carbon atoms, and R2 and R3 independently represent hydrogen or a group of formula —COOR′, in which R′ represents hydrogen or an alkyl group having between 1 and 5 carbon atoms.

    摘要翻译： 本发明涉及具有良好摩擦性能的润滑油组合物，该组合物具有润滑油和至少一种具有减摩性能的添加剂。 具有摩擦降低性质的添加剂是具有疏水性链段P和极性链段D的嵌段共聚物。疏水链段是通过聚合具有a）0至40wt。 至少一种式（I）烯键式不饱和酯化合物，其中R表示氢或甲基，R1表示直链或支链的烷基，其具有1个 和5个碳原子，R2和R3独立地表示氢或式-COOR'的基团，其中R'表示氢或具有1至5个碳原子的烷基。

    Use of graft polymers
    10.
    发明授权
    Use of graft polymers 有权
    接枝聚合物的使用

    公开(公告)号：US09080124B2

    公开(公告)日：2015-07-14

    申请号：US11572181

    申请日：2005-06-23

    申请人： Markus Scherer ,  Klaus Hedrich ,  Alexander Dardin ,  Michael Mueller ,  Torsten Stoehr ,  Boris Eisenberg

    发明人： Markus Scherer ,  Klaus Hedrich ,  Alexander Dardin ,  Michael Mueller ,  Torsten Stoehr ,  Boris Eisenberg

    IPC分类号： C10M149/10 ,  C10M149/02 ,  C08L51/06 ,  C10M161/00

    CPC分类号： C10M149/10 ,  C08L51/06 ,  C10M149/02 ,  C10M161/00 ,  C10M2209/084 ,  C10M2217/02 ,  C10M2217/028 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2230/02 ,  C10N2230/04 ,  C10N2230/06 ,  C10N2230/43 ,  C10N2240/04 ,  C10N2240/08 ,  C10N2240/10

    摘要： The invention relates to the use of graft polymers obtained by polymerization in two stages. In a first stage, at least one graft basis is produced by radically polymerizing a monomer composition A) containing 0 to 40 percent by weight of one or several ethylenically unsaturated ester compounds of formula (I), wherein R represents hydrogen or methyl, R1 represents a linear or branched alkyl radical comprising 1 to 5 carbon atoms, R2 and R3 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 1 to 5 carbon atoms, 60 to 100 percent by weight of one or several ethylenically unsaturated ester compounds of formula (II), wherein R represents hydrogen or methyl, R4 represents a linear or branched alkyl radical comprising 6 to 40 carbon atoms, R5 and R6 independently represent hydrogen or a group of formula —COOR′, wherein R′ represents hydrogen or an alkyl group comprising 6 to 40 carbon atoms, and 0 to 40 percent by weight of comonomers, the percentages being relative to the weight of monomer composition A). In a second stage, a monomer composition B) containing 20 to 100 percent by weight of at least one monomer that comprises at least one nitrogen-containing group is grafted onto the graft basis in order to reduce wear in lubricant oil compositions. Said graft polymer comprises a maximum of 200 ppm of sulfur while the weight ratio between monomer composition A) and monomer composition B) ranges between 99.7:0.3 and 80:20.

    摘要翻译： 本发明涉及通过两步聚合获得的接枝聚合物的用途。 在第一阶段中，通过自由基聚合含有0至40重量％的一种或多种式（I）的烯属不饱和酯化合物，其中R表示氢或甲基，R1表示 包含1至5个碳原子的直链或支链烷基，R2和R3独立地表示氢或式-COOR'的基团，其中R'表示氢或包含1至5个碳原子的烷基，60至100重量％ 的一种或几种式（II）的烯键式不饱和酯化合物，其中R表示氢或甲基，R4表示包含6至40个碳原子的直链或支链烷基，R5和R6独立地表示氢或式-COOR' ，其中R'表示氢或含有6至40个碳原子的烷基和0至40重量％的共聚单体，其百分数相对于单体组合物的重量 在A上）。 在第二阶段中，将包含20至100重量％的至少一种包含至少一个含氮基团的单体的单体组合物B）接枝到接枝基上以减少润滑油组合物中的磨损。 所述接枝聚合物包含最多200ppm的硫，而单体组合物A）和单体组合物B）之间的重量比在99.7:0.3和80:20之间。