公开(公告)号：US4999393A

公开(公告)日：1991-03-12

申请号：US306921

申请日：1989-02-06

申请人： Tohru Haruna ,  Kazunori Nishikawa

发明人： Tohru Haruna ,  Kazunori Nishikawa

IPC分类号： C07F9/6574 ,  C07F9/48 ,  C07F9/6571 ,  C08K5/53 ,  C08K5/5393 ,  C08L101/00 ,  C09K15/32

CPC分类号： C08K5/5393 ,  C07F9/65719

摘要： A cyclic phosphonite compound having the following formula (I) is disclosed and useful as a stabilizer for a synthetic resin. ##STR1## in which R1 is an alkyl, phenyl or an alkylphenyl, R2 is hydrogen or an alkyl, R3 is an alkyl, R4 is hydrogen or methyl and R1 and R2 may form an alkylene by linking each other.

摘要翻译： 公开了具有下式（I）的环状亚膦酸酯化合物，可用作合成树脂的稳定剂。 其中R1是烷基，苯基或烷基苯基，R2是氢或烷基，R3是烷基，R4是氢或甲基，R1和R2可以通过彼此连接形成亚烷基。

公开(公告)号：US4885326A

公开(公告)日：1989-12-05

申请号：US328313

申请日：1989-03-24

申请人： Tohru Haruna ,  Kazunori Nishikawa ,  Mitsuhiro Hamajima

发明人： Tohru Haruna ,  Kazunori Nishikawa ,  Mitsuhiro Hamajima

IPC分类号： C07F9/6574 ,  C08K5/13 ,  C08K5/134 ,  C08K5/52 ,  C08K5/527 ,  C08L101/00

CPC分类号： C08K5/1345 ,  C07F9/65744 ,  C08K5/527

摘要： A synthetic resin composition comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic alkylphosphite compound of 2,2'-alkylidene-bisphenol (I) and 0.001 to 10 parts by weight of beta-(3,5-dialkyl-4-hydroxyphenyl)-propionic acid ester (II) and is stabilized to light and heat.

公开(公告)号：US5238979A

公开(公告)日：1993-08-24

申请号：US493090

申请日：1990-03-12

申请人： Tohru Haruna ,  Kazunori Nishikawa

发明人： Tohru Haruna ,  Kazunori Nishikawa

IPC分类号： C08K3/00 ,  C08K5/00 ,  C08K5/34 ,  C08K5/3477 ,  C08K5/3492 ,  C08K5/52 ,  C08K5/526 ,  C08K5/527 ,  C08L23/00 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08L73/00 ,  C08L101/00

CPC分类号： C08K5/3492 ,  C08K5/527

摘要： Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and R.sub.6 is hydrogen or alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.

摘要翻译： 用于增强合成树脂在暴露于升高的温度和/或紫外线时的耐候性的稳定剂，其包含约0.001至约10重量份的具有式（I）的双酚亚磷酸酯，其中R 1是叔丁基或 叔戊基，R 2是具有1至约9个碳原子的烷基，R 3是氢或具有1至约4个碳原子的烷基，R 4是具有1至约30个碳原子的烷基; 和约0.001至约10重量份具有式II的苯酚，其中R 5为具有1至约4个碳原子的烷基; 且R 6为氢或具有1至约4个碳原子的烷基; 和包含这种稳定剂的稳定的合成树脂组合物

公开(公告)号：US5055507A

公开(公告)日：1991-10-08

申请号：US487699

申请日：1990-03-01

申请人： Tohru Haruna ,  Kazunori Nishikawa

发明人： Tohru Haruna ,  Kazunori Nishikawa

IPC分类号： C08K3/00 ,  C08K5/00 ,  C08K5/13 ,  C08K5/52 ,  C08K5/526 ,  C08K5/527 ,  C08L23/00 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00 ,  C08L73/00 ,  C08L101/00

CPC分类号： C08K5/527 ,  C08K5/13

摘要： Stabilizers for enhancing the resistance of synthetic resins to deterioration when exposed to elevated temperatures and/or ultraviolet light comprising from about 0.001 to about 10 parts by weight of a bisphenol phosphite having the formula ##STR1## wherein R.sub.1 is tertiary-butyl or tertiary-amyl, R.sub.2 is alkyl having from one to about nine carbon atoms, R.sub.3 is hydrogen or alkyl having from one to about four carbon atoms, and R.sub.4 is alkyl having from one to about thirty carbon atoms; and from about 0.001 to about 10 parts by weight of a phenol having the formula ##STR2## wherein R.sub.5 is alkyl having from one to about four carbon atoms; and stabilized synthetic resin compositions comprising such stabilizers.

摘要翻译： 用于增强合成树脂在暴露于升高的温度和/或紫外线时的耐候性的稳定剂，其包含约0.001至约10重量份的具有式（I）的双酚亚磷酸酯，其中R 1是叔丁基或 叔戊基，R 2是具有1至约9个碳原子的烷基，R 3是氢或具有1至约4个碳原子的烷基，R 4是具有1至约30个碳原子的烷基; 和约0.001至约10重量份具有式（II）的酚，其中R 5是具有1至约4个碳原子的烷基; 和包含这种稳定剂的稳定的合成树脂组合物。

公开(公告)号：US5039723A

公开(公告)日：1991-08-13

申请号：US388680

申请日：1989-07-31

申请人： Tohru Haruna ,  Kazunori Nishikawa

发明人： Tohru Haruna ,  Kazunori Nishikawa

IPC分类号： C07F9/6574 ,  C08K5/3412 ,  C08K5/3435 ,  C08K5/52 ,  C08K5/527 ,  C08L101/00

CPC分类号： C08K5/3435 ,  C08K5/527

摘要： A synthetic resin composition stabilized particularly against the deterioration caused by the action of heat and light, which comprises 100 parts by weight of a synthetic resin, 0.001 to 10 parts by weight of a cyclic phosphite compound represented by the following general formula (I) and 0.001 to 10 parts by weight of a hindered amine compound having a group represented by the following general formula (II) in its molecule: ##STR1## wherein R.sub.1 stands for a tert-butyl or tert-amyl group; R.sub.2 stands for a C.sub.1.about.9 alkyl group; R.sub.3 stands for a hydrogen atom or a C.sub.1.about.4 alkyl group and R.sub.4 stands for a C.sub.1.about.30 alkyl group.

公开(公告)号：US4894400A

公开(公告)日：1990-01-16

申请号：US229144

申请日：1988-08-05

申请人： Tohru Haruna ,  Masayuki Takahashi ,  Kazunori Nishikawa

发明人： Tohru Haruna ,  Masayuki Takahashi ,  Kazunori Nishikawa

IPC分类号： C08K5/34 ,  C07D249/18 ,  C08K5/3472 ,  C08K5/3475 ,  C08L101/00

CPC分类号： C08K5/3475

摘要： Synthetic polymer compositions comprise 100 parts by weight of a synthetic polymer and 0.001 to 5 parts by weight of a benzotriazol compound, and thus possesses improved stability.

摘要翻译： 合成聚合物组合物包含100重量份的合成聚合物和0.001至5重量份的苯并三唑化合物，因此具有改进的稳定性。

公开(公告)号：US4912156A

公开(公告)日：1990-03-27

申请号：US225054

申请日：1988-07-27

申请人： Masaki Yagi ,  Tohru Haruna ,  Takashi Takeuchi ,  Toshinori Yukino

发明人： Masaki Yagi ,  Tohru Haruna ,  Takashi Takeuchi ,  Toshinori Yukino

IPC分类号： C08L23/00 ,  C08K5/134 ,  C08K5/52 ,  C08K5/527

CPC分类号： C08K5/1345 ,  C08K5/527

摘要： A polyolefin composition comprises 100 parts by weight of a polyolefine which has been produced with use of a Ziegler catalyst and has a part or residue of the catalyst left therein, 0.005 to 1 part by weight of a phenol compound having the formula (I) and 0.005 to 1 part by weight of an organic phosphite compound having the formula (II). ##STR1## in which R is a residue group of an alcohol being monohydric, dihydric, trihydric or terahydric, R1 is methyl or tert.-butyl, R2 is an alkyl, --CH2CH2COOR3 or --COOR3, R3 being an alkyl, an aryl or an alkylaryl, and n is a number of 1 to 4.

公开(公告)号：US4107136A

公开(公告)日：1978-08-15

申请号：US729975

申请日：1976-10-06

申请人： Motonobu Minagawa ,  Yutaka Nakahara ,  Tohru Haruna

发明人： Motonobu Minagawa ,  Yutaka Nakahara ,  Tohru Haruna

IPC分类号： C08L23/00 ,  C08K5/00 ,  C08K5/10 ,  C08K5/109 ,  C08K5/375 ,  C08K5/41 ,  C08K5/51 ,  C08K5/524 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/02 ,  C08L27/00 ,  C08L51/00 ,  C08L51/02 ,  C08L55/02 ,  C08L77/00 ,  C08L101/00 ,  C08K5/52

CPC分类号： C08L23/02 ,  C08K5/10 ,  C08K5/109 ,  C08K5/375 ,  C08K5/52 ,  C08K5/524 ,  C08L23/06 ,  C08L55/02 ,  C08L2312/00

摘要： Stabilizer compositions are provided whose ingredients interact synergistically to improve the resistance to deterioration on heating of a variety of synthetic resin compositions. The interacting ingredients are (a) an organic phosphite having linked to phosphorus through oxygen at least two alkyl groups having from 6 to 20 carbon atoms and at least one organic group selected from polycyclic polyhydric phenol groups and pentaerythrityl groups, and (b) at least one carbonate ester of an ortho-substituted polyhydric phenol having in the molecule one to three benzenoid rings, two to three phenolic hydroxyl groups, and in each benzenoid ring one to two alkyl, cycloalkyl, or aralkyl groups of which at least one is positioned ortho to a phenolic hydroxyl group.Synthetic resin compositions are provided that are stabilized with the stabilizer compositions disclosed, including olefin polymers, polyamides, acrylic polymers, and vinyl halide polymers.

摘要翻译： 提供稳定剂组合物，其成分协同作用以改善耐多种合成树脂组合物的加热劣化。 相互作用的成分是（a）通过氧与至少两个具有6至20个碳原子的烷基和至少一个选自多环多羟基酚基和季戊四醇基的有机基团的氧连接的有机亚磷酸酯，和（b）至少 一个邻位取代的多元酚的碳酸酯，其在分子中具有一至三个苯环，二至三个酚羟基，并且在每个苯环中一至两个烷基，环烷基或芳烷基，其中至少一个位于邻位 到酚羟基。

公开(公告)号：US4104217A

公开(公告)日：1978-08-01

申请号：US761886

申请日：1977-01-24

申请人： William E. Leistner ,  Motonobu Minagawa ,  Yutaka Nakahara ,  Tohru Haruna

发明人： William E. Leistner ,  Motonobu Minagawa ,  Yutaka Nakahara ,  Tohru Haruna

IPC分类号： C08K5/109 ,  C08K5/134 ,  C08L23/02 ,  C07C69/00 ,  C08K5/10

CPC分类号： C08K5/134 ,  C08K5/109 ,  C08L23/02 ,  C08L23/06 ,  C08L23/10 ,  C08L23/18

摘要： This invention relates to a new class of polyhydric phenol carbonate esters and to synthetic resin stabilizer compositions comprising these esters as well as to synthetic resins stabilized with such esters and with stabilizer compositions comprising these esters along with known polymer stabilizers.

摘要翻译： 本发明涉及一类新型多元酚碳酸酯和包含这些酯的合成树脂稳定剂组合物以及由这些酯稳定的合成树脂以及包含这些酯以及已知聚合物稳定剂的稳定剂组合物。

公开(公告)号：US5112891A

公开(公告)日：1992-05-12

申请号：US573722

申请日：1990-08-28

申请人： Tohru Haruna ,  Masayuki Takahashi ,  Toshinori Yukino

发明人： Tohru Haruna ,  Masayuki Takahashi ,  Toshinori Yukino

IPC分类号： C08K5/523 ,  C08K3/00 ,  C08K5/524 ,  C08K5/527 ,  C08L69/00

CPC分类号： C08K5/527

摘要： A polycarbonate resin composition improved in heat resistance by the addition of an organic cyclic phosphite represented by the general formula: ##STR1## wherein R.sub.1 represents an alkyl group having 1 to 9 carbon atoms; R.sub.2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; and R.sub.3 represents an alkyl group having 1 to 30 carbon atoms.

摘要翻译： 通过加入由以下通式表示的有机环状亚磷酸酯改善耐热性的聚碳酸酯树脂组合物：其中R 1表示具有1至9个碳原子的烷基; R2表示氢原子或碳原子数1〜4的烷基。 R3表示碳原子数1〜30的烷基。