公开(公告)号：US5210252A

公开(公告)日：1993-05-11

申请号：US933665

申请日：1992-08-24

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

IPC分类号： C07F7/18 ,  C08F30/08

CPC分类号： C07F7/1832

摘要： The object of the present invention is to provide a styrene type alkoxysilane compound which is useful as a silane coupling agent or a polymerizable monomer and which can easily be synthesized and is not expensive.A 3-(vinylphenyloxy)propylsilane compound represented by the following general formula: ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrocarbon group having 1 to 4 carbon atoms and n is an integer ranging from 0 to 2.

公开(公告)号：US5326895A

公开(公告)日：1994-07-05

申请号：US976845

申请日：1992-11-16

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo ,  Katsuhiro Uehara

IPC分类号： C07F7/18 ,  C07F7/14 ,  C08F30/08 ,  C07F7/08

CPC分类号： C07F7/14 ,  C07F7/1832 ,  C08F30/08

摘要： 3-(Vinylbenzyloxy)propylsilane compounds represented by the general formula, CH.sub.2 CH.PHI. CH.sub.2 OCH.sub. CH.sub.2 CH.sub.2 SiR.sup.1.sub.n (OR.sup.2).sub.3-n (wherein R.sup.1 and R.sup.2 each represent a hydrocarbon residue containing 1 to 4 carbon atoms, and n represents an integer from 0 to 2) are provided as novel styrene skeleton-containing alkoxysilane compounds which are highly useful as silane coupling agent or polymerizing monomer.

摘要翻译： 由通式CH 2 CH PHI CH 2 OCHCH 2 CH 2 SiRnn（OR 2）3-n表示的3-（乙烯基苄氧基）丙基硅烷化合物（其中R 1和R 2各自表示含有1至4个碳原子的烃基，n表示0的整数 提供作为硅烷偶联剂或聚合单体非常有用的新型含苯乙烯骨架的烷氧基硅烷化合物。

公开(公告)号：US5258537A

公开(公告)日：1993-11-02

申请号：US16289

申请日：1993-02-11

申请人： Masaki Takeuchi ,  Toshinobu Ishihara ,  Tohru Kubota ,  Mikio Endo

发明人： Masaki Takeuchi ,  Toshinobu Ishihara ,  Tohru Kubota ,  Mikio Endo

IPC分类号： B01J31/02 ,  C07B61/00 ,  C07F7/12 ,  C07F7/08

CPC分类号： C07F7/123

摘要： An organodisiloxane represented by the general formula: R.sup.1 R.sup.2 R.sup.3 SiOSiR.sup.4 R.sup.5 R.sup.6 is reacted with thionyl chloride in the presence of an ammonium salt represented by the general formula: R.sup.7 R.sup.8 R.sup.9 R.sup.10 NX wherein R.sup.1 to R.sup.5 and R.sup.10 may be the same or different and each represents a monovalent hydrocarbon group or a hydrogen atom; R.sup.7 to R.sup.9 may be the same or different and each represents a monovalent hydrocarbon group; and X represents a monovalent anion. Thus, organomonochlorosilanes represented by R.sup.1 R.sup.2 R.sup.3 SiCl and R.sup.4 R.sup.5 R.sup.6 SiCl can be obtained.

公开(公告)号：US5081260A

公开(公告)日：1992-01-14

申请号：US508570

申请日：1990-04-13

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C07F7/18 ,  C09K3/18

CPC分类号： C07F7/1824 ,  C09K3/18

摘要： 3-(2-oxo-1-pyrrolidinyl)-propylsilane compounds represented by the following general formula (I) are herein disclosed: ##STR1## wherein R.sup.1 and R.sup.2 may be the same or different and each represents a hydrocarbon group having 1 to 4 carbon atoms; and n is an integer ranging from 0 to 2. The propylsilane compounds may be prepared by, for instance, reacting 1-allyl-2-oxopyrrolidine with a hydrogen silane such as trimethoxysilane or trichlorosilane in the presence of a platinum catalyst or further optionally reacting the resulting 3-(2-oxo-1-pyrrolidinyl)-propyl halogenosilane (in the case where a halogenosilane is used) with an alcohol such as methanol. These propylsilane compounds are effective as anti-clouding agent for treating the surface of a variety of substrate.

公开(公告)号：US4895966A

公开(公告)日：1990-01-23

申请号：US387923

申请日：1989-08-01

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08F30/08

CPC分类号： C07F7/0852 ,  C07F7/0818 ,  C07F7/182 ,  C08F30/08

摘要： The organosilane compound of the invention is represented by the general formulaCIFC.dbd.CF--O--(R.sup.1 --O--).sub.m --(--R.sup.2 --).sub.n --CHR.sup.3 --CH.sub.2 --SiR.sub.3,in which, for example, each R.sup.1 is an ethylene group, R.sup.2 is a methylene group, R.sup.3 is a hydrogen atom, each R is an alkyl or alkoxy group, the subscript m is zero, 1, 2 or 3 and the subscript n is zero or 1. The terminal group of CIFC.dbd.CF--O-- has copolymerizability with conventional fluorine-containing polymerizable unsaturated compounds, e.g., tetrafluoroethylene, so that it is useful as a modifying agent of fluorine-containing polymers. A synthetic method for the compound is disclosed.

摘要翻译： 本发明的有机硅烷化合物由通式CIFC = CF-O-（R1-O-）m - （ - R2-）n-CHR3-CH2-SiR3表示，其中，例如，每个R 1是乙烯 基团，R 2是亚甲基，R 3是氢原子，每个R是烷基或烷氧基，下标m是0,1,2或3，下标n是0或1.CFCFC的末端基团= CF -O-与常规含氟可聚合不饱和化合物（例如四氟乙烯）具有共聚性，因此其可用作含氟聚合物的改性剂。 公开了该化合物的合成方法。

公开(公告)号：US5455360A

公开(公告)日：1995-10-03

申请号：US107886

申请日：1993-08-18

申请人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

发明人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Katsuya Takemura

IPC分类号： C08G77/26 ,  B05D1/18 ,  C07F7/12 ,  C07F7/18 ,  C08G77/28 ,  C08J5/18 ,  C09K3/16 ,  H01B1/12 ,  C07F7/10 ,  C07D207/323

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1868

摘要： Disclosed are a conductive pyrrole derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a monomer used for forming the conductive pyrrole derivative monomolecular film and method of manufacturing the same. The invention relates to a monomolecular ultrathin film comprising 1-pyrrolyl groups and silicon groups. The monomer used for forming the film is provided by reacting .omega.-(1-pyrrolyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted monomer, thus chemically bonding a monomolecular film to a substrate surface. Furthermore, a polypyrrole derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.

摘要翻译： 公开了共价键合到基材表面的导电吡咯衍生物单分子膜及其制备方法，以及用于形成导电吡咯衍生物单分子膜的单体及其制造方法。 本发明涉及包含1-吡咯基和硅基团的单分子超薄膜。 用于形成膜的单体是通过使ω-（1-吡咯基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷的四个氢原子中的三个被卤素或烷氧基取代， 的过渡金属催化剂。 将基材浸渍并保持在上述单体的非水溶液中，从而将单分子膜化学键合到基材表面。 此外，通过单分子膜的电解或催化聚合形成聚吡咯衍生物超薄膜。

公开(公告)号：US5116973A

公开(公告)日：1992-05-26

申请号：US564093

申请日：1990-08-08

申请人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

发明人： Tohru Kubota ,  Toshinobu Ishihara ,  Mikio Endo

IPC分类号： C03C17/30 ,  C07B61/00 ,  C07F7/18 ,  C09D5/00

CPC分类号： C07F7/182

摘要： A silane compound having the following formula, wherein R.sup.1 and R.sup.2 are each monovalent hydrocarbon radicals having 1 to 4 carbon atoms and n is an integer of 0, 1 or 2: ##STR1## which is manufactured by reacting 1-allyl-.epsilon.-caprolactam of the following formula: ##STR2## with a hydrogen silane of the following formula:HSiR.sup.1.sub.n (OR.sup.2).sub.3-nin the presence of a platinum-containing catalyst. The silane compound is useful as a surface treatment agent for imparting a moisture-repelling property to the surface of various materials.

公开(公告)号：US5000881A

公开(公告)日：1991-03-19

申请号：US366003

申请日：1989-06-14

申请人： Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota

发明人： Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota

IPC分类号： C07F7/08 ,  C07F7/18 ,  C08F30/08

CPC分类号： C07F7/184 ,  C07F7/0818 ,  C07F7/182 ,  C07F7/1836 ,  C08F30/08

摘要： A novel organosilane compound having polymerizability is disclosed which is a vinyl .omega.-triorganosilyl n-undecanoate of the formula CH.sub.2 .dbd.CH--O--CO--(--CH.sub.2 --).sub.10 --SiR.sub.3, in which R is an alkyl group having 1 to 4 carbon atoms, alkoxy group having 1 to 4 carbon atoms or trialkyl siloxy group of which the alkyl group has 1 to 4 carbon atoms. This compound can be prepared by the hydrosilylation reaction between a triorganosilane of the formula HSiR.sub.3 and vinyl 10-undecenoate of the formulaCH.sub.2 .dbd.CH--O--CO--(--CH.sub.2 --).sub.8 --CH.dbd.CH.sub.2in the presence of a platinum catalyst. The compound is polymerizable to give not only a homopolymer of the compound alone but also a copolymer with other comonomers such as vinyl chloride, chloro trifluoroethylene, methyl methacrylate and the like.

摘要翻译： 公开了一种具有聚合性的新颖的有机硅烷化合物，它是式CH 2 = CH-O-CO - （ - CH 2））10-SiR 3的乙烯基ω-三有机甲硅烷基正十一酸酯，其中R是具有1-4个碳原子的烷基 原子，具有1至4个碳原子的烷氧基或其烷基具有1至4个碳原子的三烷基甲硅烷氧基。 在铂催化剂存在下，该化合物可以通过式HSiR 3的三有机硅烷与式CH 2 = CH-O-CO - （ - CH 2）8 -CH = CH 2的10-十一碳烯酸乙烯酯的氢化硅烷化反应来制备。 该化合物是可聚合的，不仅可以单独使用化合物的均聚物，而且可以与其它共聚单体如氯乙烯，氯三氟乙烯，甲基丙烯酸甲酯等共聚。

公开(公告)号：US4957607A

公开(公告)日：1990-09-18

申请号：US380350

申请日：1989-07-17

申请人： Mikio Endo ,  Minoru Takamizawa ,  Toshinobu Ishihara ,  Tohru Kubota ,  Toshio Shinohara

发明人： Mikio Endo ,  Minoru Takamizawa ,  Toshinobu Ishihara ,  Tohru Kubota ,  Toshio Shinohara

IPC分类号： C07F7/12 ,  C07B61/00 ,  C07F7/08 ,  C07F7/14 ,  C07F7/18

CPC分类号： C07F7/0801 ,  C07F7/14 ,  C07F7/1876

摘要： Cycloalkyl silane compounds such as cyclohexyl methyl dichlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mixture of cyclohexene and methyl dichlorosilane with admixture of a catalytic amount of a platinum catalyst, which is an alcohol complex of chloroplatinic acid, is irradiated at a temperature of 70.degree. C. with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher. Unexpectedly, the efficiency of the reaction can be greatly increased when the platinum catalyst is prepared by heating a solution of chloroplatinic acid in 2-ethylhexyl alcohol at 50.degree. to 80.degree. C. for at least 4 hours.

公开(公告)号：US5461166A

公开(公告)日：1995-10-24

申请号：US384594

申请日：1995-02-03

申请人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Kazuyuki Asakura

发明人： Norihisa Mino ,  Kazufumi Ogawa ,  Toshinobu Ishihara ,  Mikio Endo ,  Tohru Kubota ,  Kazuyuki Asakura

IPC分类号： C07B61/00 ,  B01J23/42 ,  B05D1/18 ,  C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C09K3/00 ,  G03F7/075 ,  C07D333/02 ,  C08G77/08 ,  C08F28/06

CPC分类号： B82Y30/00 ,  B05D1/185 ,  B82Y10/00 ,  B82Y40/00 ,  C07F7/12 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1868

摘要： Disclosed are a conductive thienyl derivative monomolecular film covalently bonded to a substrate surface and method of manufacturing the same, and a silicon compound comprising 3-thienyl groups (thiophene derivative) used for forming the conductive monomolecular film and a method of manufacturing the same. A monomolecular ultrathin film comprising 3-thienyl groups and silicon groups is formed in the invention. The silicon compound used for forming the film is provided by reacting .omega.-(3-thienyl)-1-alkene compound to a monosilane derivative compound, in which three out of four hydrogen atoms of monosilane are replaced with halogen or alkoxy groups, in the presence of a transition metal catalyst. A substrate is dipped and held in a nonaqueous solution of the above-noted compound, thus chemically bonding the monomolecular film to the substrate surface. Furthermore, a thienyl derivative ultrathin film is formed by the electrolytic or catalytic polymerization of the monomolecular film.

摘要翻译： 公开了共价结合到基板表面的导电噻吩基衍生物单分子膜及其制造方法，以及包含用于形成导电性单分子膜的3-噻吩基（噻吩衍生物）的硅化合物及其制造方法。 在本发明中形成包含3-噻吩基和硅基团的单分子超薄膜。 用于形成膜的硅化合物是通过使ω-（3-噻吩基）-1-烯烃化合物与甲硅烷衍生物化合物反应而得到的，其中甲硅烷中四分之三的氢原子被卤素或烷氧基取代， 过渡金属催化剂的存在。 将基材浸渍并保持在上述化合物的非水溶液中，从而将单分子膜化学键合到基材表面。 此外，通过单分子膜的电解或催化聚合形成噻吩衍生物超薄膜。