公开(公告)号：US5340499A

公开(公告)日：1994-08-23

申请号：US927858

申请日：1992-08-11

申请人： Toivo Karna ,  Jukka Laakso ,  Timo Niemi ,  Heikki Ruohonen ,  Esko Savolainen ,  Helge Lindstrom ,  Esa Virtanen ,  Olli Ikkala ,  Alejandro Andreatta

发明人： Toivo Karna ,  Jukka Laakso ,  Timo Niemi ,  Heikki Ruohonen ,  Esko Savolainen ,  Helge Lindstrom ,  Esa Virtanen ,  Olli Ikkala ,  Alejandro Andreatta

IPC分类号： C08K3/22 ,  C08L79/02 ,  C08L101/00 ,  H01B1/12 ,  H01B1/00

CPC分类号： H01B1/128 ,  C08K3/22 ,  C08L101/00 ,  C08L79/02 ,  Y10S264/17 ,  Y10S264/26 ,  Y10S428/922 ,  Y10T428/29 ,  Y10T428/31504

摘要： Compositions and methods are described that relate to the use of reaction products of metal compounds and protonic acids for plasticizing and neutralizing acidic, protonated compositions comprising substituted and unsubstituted polyanilines and co-polymers and or mixtures thereof; and for reducing the percolation threshold for conductivity in blends with insulating bulk polymers.

摘要翻译： 描述了涉及金属化合物和质子酸的反应产物用于增塑和中和包含取代和未取代的聚苯胺和共聚物及其混合物的酸性质子化组合物的组合物和方法; 并且用于减少与绝缘本体聚合物的共混物中的电导率的渗透阈值。

公开(公告)号：US5531932A

公开(公告)日：1996-07-02

申请号：US234870

申请日：1994-04-28

申请人： Toivo Karna ,  Jukka Laakso ,  Timo Niemi ,  Heikki Ruohonen ,  Esko Savolainen ,  Helge Lindstrom ,  Esa Virtanen ,  Olli Ikkala

发明人： Toivo Karna ,  Jukka Laakso ,  Timo Niemi ,  Heikki Ruohonen ,  Esko Savolainen ,  Helge Lindstrom ,  Esa Virtanen ,  Olli Ikkala

IPC分类号： C08K3/22 ,  C08L79/02 ,  C08L101/00 ,  H01B1/12 ,  H01B1/00

CPC分类号： H01B1/128 ,  C08K3/22 ,  C08L101/00 ,  C08L79/02 ,  Y10S264/17 ,  Y10S264/26 ,  Y10S428/922 ,  Y10T428/29 ,  Y10T428/31504

摘要： Compositions and methods are described that relate to the use of reaction products of metal compounds and protonic acids for plasticizing and neutralizing acidic, protonated compositions comprising substituted and unsubstituted polyanilines and co-polymers and or mixtures thereof; and for reducing the percolation threshold for conductivity in blends with insulating bulk polymers.

摘要翻译： 描述了涉及金属化合物和质子酸的反应产物用于增塑和中和包含取代和未取代的聚苯胺和共聚物及其混合物的酸性质子化组合物的组合物和方法; 并且用于减少与绝缘本体聚合物的共混物中的电导率的渗透阈值。

公开(公告)号：US5585040A

公开(公告)日：1996-12-17

申请号：US476913

申请日：1995-06-07

申请人： Pauli Kirmanen ,  Esko Savolainen ,  Esa Virtanen ,  Toivo Karna ,  Jukka Laakso ,  Heikki Ruohonen ,  Kimmo Vakiparta ,  Olli Ikkala ,  Hannele Jarvinen

发明人： Pauli Kirmanen ,  Esko Savolainen ,  Esa Virtanen ,  Toivo Karna ,  Jukka Laakso ,  Heikki Ruohonen ,  Kimmo Vakiparta ,  Olli Ikkala ,  Hannele Jarvinen

IPC分类号： C08G73/00 ,  C08G73/02 ,  C08L79/00 ,  C08L79/08 ,  H01B1/12 ,  H01B1/00 ,  H01B1/04

CPC分类号： C08G73/0266 ,  H01B1/128

摘要： The invention relates to a conductive polymer complex which contains a polyaniline or derivative thereof doped with a protonic acid. By the method according to the invention, a conductive polymer is obtained having substantially reduced acidity, sufficiently high conductivity level, and which is suitable, for example, for being melt processed in conventional plastics processing apparatus. The acidity of the conductive polymer can be reduced by having the conductive polymer contain both a metal compound and an additionally neutralizing compound. The obtained conductive polymer material, having a pH value of approximately 3-8, can be mixed with an insulating polymer to produce a conductive plastics mixture. The invention also relates to a method of preparing a conductive polymer that is more processable by incorporating therein a plasticizing agent selected from the group consisting of water, a C.sub.1 -C.sub.3 alcohol, and mixtures thereof.

公开(公告)号：US5346649A

公开(公告)日：1994-09-13

申请号：US988902

申请日：1992-12-04

申请人： Toivo Karna ,  Jukka Laakso ,  Kalle Levon ,  Esko Savolainen

发明人： Toivo Karna ,  Jukka Laakso ,  Kalle Levon ,  Esko Savolainen

IPC分类号： C08G73/02 ,  C08K5/42 ,  C08L25/04 ,  C08L79/00 ,  C08L79/02 ,  H01B1/12 ,  H01B1/00

CPC分类号： H01B1/128 ,  C08G73/0266 ,  C08K5/42 ,  C08L79/02 ,  C08L25/04

摘要： An electrically conducting plastic material is produced by blending a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof. A reaction product or blend of a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof can be brought to an easy-to-handle or directly melt-processable form through a heat-treatment process carried out at approx. +40.degree. to +250.degree. C. The obtained plastic material is advantageously further improved by blending the heat-treated reaction product or blend with a thermoplastic polymer and then melt-processing the mixed blend. The properties of the resulting compound material exhibit complete compatibility of the heat-treated reaction product or blend with the thermoplastic polymer.

摘要翻译： 通过将聚苯胺或其衍生物与有机磺酸或其衍生物共混来制造导电塑料材料。 聚苯胺或其衍生物与有机磺酸或其衍生物的反应产物或共混物可以通过在约3℃下进行的热处理过程使其易于处理或直接熔融加工形式。 + 40℃至+ 250℃。通过将热处理的反应产物或共混物与热塑性聚合物共混，然后熔融加工该混合共混物，所得塑料材料有利地进一步改进。 所得复合材料的性质表现出热处理反应产物或共混物与热塑性聚合物的完全相容性。

公开(公告)号：US5928565A

公开(公告)日：1999-07-27

申请号：US611004

申请日：1996-03-05

申请人： Toivo Karna ,  Jukka Laakso ,  Kalle Levon ,  Esko Savolainen

发明人： Toivo Karna ,  Jukka Laakso ,  Kalle Levon ,  Esko Savolainen

IPC分类号： C08G73/02 ,  C08K5/42 ,  C08L25/04 ,  C08L79/00 ,  C08L79/02 ,  H01B1/12 ,  H01B1/00 ,  H01B1/20

CPC分类号： H01B1/128 ,  C08G73/0266 ,  C08K5/42 ,  C08L79/02 ,  C08L25/04

摘要： An electrically conducting plastic material is produced by blending a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof. A reaction product or blend of a polyaniline or a derivative thereon with an organic sulfonic acid or a derivative thereof can be brought to an easy-to-handle or directly melt-processable form through a heat-treatment process carried out at approx. +40.degree. to +250.degree. C. The obtained plastic material is advantageously further improved by blending the heat-treated reaction product or blend with a thermoplastic polymer and then melt-processing the mixed blend. The properties of the resulting compound material exhibit complete compatibility of the heat-treated reaction product or blend with the thermoplastic polymer.

摘要翻译： 通过将聚苯胺或其衍生物与有机磺酸或其衍生物共混来制造导电塑料材料。 聚苯胺或其衍生物与有机磺酸或其衍生物的反应产物或共混物可以通过在大约1小时进行的热处理过程使其易于处理或直接熔融加工形式。 + 40℃至+ 250℃。通过将热处理的反应产物或共混物与热塑性聚合物共混，然后熔融加工该混合共混物，所得塑料材料有利地进一步改进。 所得复合材料的性质表现出热处理反应产物或共混物与热塑性聚合物的完全相容性。

公开(公告)号：US4989837A

公开(公告)日：1991-02-05

申请号：US364781

申请日：1989-06-09

申请人： Toivo Karna ,  Ahti Kemppi ,  Esko Savolainen ,  Kalevi Lind ,  Niilo Jaasko ,  Olli Walden

发明人： Toivo Karna ,  Ahti Kemppi ,  Esko Savolainen ,  Kalevi Lind ,  Niilo Jaasko ,  Olli Walden

IPC分类号： H01M2/02 ,  H01M6/48 ,  H01M10/04

CPC分类号： H01M2/0242 ,  H01M10/0413 ,  H01M6/48

摘要： The present invention concerns a procedure for producing an envelope structure for a storage battery having a housing, a cover, and partitions separating cells therein. The battery in particular comprises one or several cells enclosed within the housing, with each cell containing electrolyte and monopolar plates and/or bipolar plates separated from one another by separator plates, and being coated with positive and/or negative active mass, in addition to the requisite electrical connectors interconnecting the cells and/or plates. The envelope structure of the storage battery is produced by casting with electrically-insulating an electrolyte-impermeable material, using in the casting the cells of the storage battery at an inner mold, and separately-constructed mold structure as an outer mold. Wall thickness of the housing of the storage battery is defined with the aid of a spacer structure remaining inside the cast.

公开(公告)号：US4973533A

公开(公告)日：1990-11-27

申请号：US364798

申请日：1989-06-09

申请人： Jukka-Pekka Nieminen ,  Asko Maisti ,  Toivo Karna ,  Ahti Kemppi ,  Esko Savolainen ,  Niilo Jaasko

发明人： Jukka-Pekka Nieminen ,  Asko Maisti ,  Toivo Karna ,  Ahti Kemppi ,  Esko Savolainen ,  Niilo Jaasko

IPC分类号： H01M2/02 ,  H01M6/48 ,  H01M10/04

CPC分类号： H01M10/0413 ,  H01M2/0242 ,  H01M6/48

摘要： The present invention concerns a gas vault structure for a storage battery having one or several cells enclosed in a housing, each cell containing electrolyte and monopolar plates and/or bipolar plates separated from one another by separator plates and coated with positive and/or negative mass, along with requisite electrical connectors interconnecting cells and/or plates. The gas vault structure is arranged to serve as an inner core for producing a gas space during casting of the housing of the storage battery, and/or of the cover, and/or of the partitions separating the cells.

公开(公告)号：US5279769A

公开(公告)日：1994-01-18

申请号：US777396

申请日：1991-12-02

申请人： Timo Kokkonen ,  Toivo Karna ,  Jukka Laakso ,  Per Nyholm ,  Jan-Erik sterholm ,  Henrik Stubb

发明人： Timo Kokkonen ,  Toivo Karna ,  Jukka Laakso ,  Per Nyholm ,  Jan-Erik sterholm ,  Henrik Stubb

IPC分类号： C08J3/20 ,  C08L65/00 ,  C08L101/00 ,  H01B1/12 ,  H01B13/00

CPC分类号： H01B1/127 ,  C08L65/00

摘要： The invention relates to a method for preparing a conductive polymer product by doping a conductor polymer. The conductor polymer or a mixture of the conductor polymer and a matrix polymer is in a molten state brought into contact with a doping agent, whereafter the mixture is treated into a product.

摘要翻译： 本发明涉及通过掺杂导体聚合物制备导电聚合物产品的方法。 导体聚合物或导体聚合物和基质聚合物的混合物处于与掺杂剂接触的熔融状态，之后将混合物处理成产物。

公开(公告)号：US5037671A

公开(公告)日：1991-08-06

申请号：US421273

申请日：1989-10-13

申请人： Toivo Karna ,  Frey Fredenberg ,  Timo Niemi ,  Matti Luukka ,  Jukka-Pekka Nieminen

发明人： Toivo Karna ,  Frey Fredenberg ,  Timo Niemi ,  Matti Luukka ,  Jukka-Pekka Nieminen

IPC分类号： H01M4/20

CPC分类号： H01M4/20

摘要： In a method for manufacturing storage plates, plate frames (5) of storage batteries are material-coated by active material supply means which is provided with at least one rotating material application wheel. The wheel includes a dispensing element (14) with which the active material is dispensed to a conveyor belt or equivalent means which travels under the supply means (10) and conveys plate frames (5). The material application wheel/wheels (11,1a) of the supply means (10) is/are rotated at such a high speed that the material application wheel/wheels (11,1a) dispenses/dispense the active material (1) from the dispensing element (14) to the mobile conveyor belt (20) under the effect of centrifugal force. The invention also concerns a means for manufacturing storage batteries.

公开(公告)号：US5012175A

公开(公告)日：1991-04-30

申请号：US421275

申请日：1989-10-13

申请人： Toivo Karna ,  Kalevi Lind

发明人： Toivo Karna ,  Kalevi Lind

IPC分类号： H01M2/36 ,  H01M4/22

CPC分类号： H01M4/22 ,  H01M2/36

摘要： Apparatus for acid-filling and forming of storage batteries has a frame which is arranged to hole several storage batteries (30) simultaneously. In the frame a duct system (18-25) is in direct contact with the cells (35) of each storage battery (30) fixed in the frame. The duct system supplies acid simultaneously into each storage battery (30) and a circuit (13) simultaneously supplies charging current to the terminals of each storage battery with the electrical interconnection between the terminals of each battery (30) and the circuit (13) being made by installing the respective battery (30) within the frame.