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公开(公告)号：US5585040A
公开(公告)日：1996-12-17
申请号：US476913
申请日：1995-06-07
申请人： Pauli Kirmanen , Esko Savolainen , Esa Virtanen , Toivo Karna , Jukka Laakso , Heikki Ruohonen , Kimmo Vakiparta , Olli Ikkala , Hannele Jarvinen
发明人： Pauli Kirmanen , Esko Savolainen , Esa Virtanen , Toivo Karna , Jukka Laakso , Heikki Ruohonen , Kimmo Vakiparta , Olli Ikkala , Hannele Jarvinen
CPC分类号： C08G73/0266 , H01B1/128
摘要： The invention relates to a conductive polymer complex which contains a polyaniline or derivative thereof doped with a protonic acid. By the method according to the invention, a conductive polymer is obtained having substantially reduced acidity, sufficiently high conductivity level, and which is suitable, for example, for being melt processed in conventional plastics processing apparatus. The acidity of the conductive polymer can be reduced by having the conductive polymer contain both a metal compound and an additionally neutralizing compound. The obtained conductive polymer material, having a pH value of approximately 3-8, can be mixed with an insulating polymer to produce a conductive plastics mixture. The invention also relates to a method of preparing a conductive polymer that is more processable by incorporating therein a plasticizing agent selected from the group consisting of water, a C.sub.1 -C.sub.3 alcohol, and mixtures thereof.
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2.发明授权
公开(公告)号：US5531932A
公开(公告)日：1996-07-02
申请号：US234870
申请日：1994-04-28
申请人： Toivo Karna , Jukka Laakso , Timo Niemi , Heikki Ruohonen , Esko Savolainen , Helge Lindstrom , Esa Virtanen , Olli Ikkala
发明人： Toivo Karna , Jukka Laakso , Timo Niemi , Heikki Ruohonen , Esko Savolainen , Helge Lindstrom , Esa Virtanen , Olli Ikkala
IPC分类号： C08K3/22 , C08L79/02 , C08L101/00 , H01B1/12 , H01B1/00
CPC分类号： H01B1/128 , C08K3/22 , C08L101/00 , C08L79/02 , Y10S264/17 , Y10S264/26 , Y10S428/922 , Y10T428/29 , Y10T428/31504
摘要： Compositions and methods are described that relate to the use of reaction products of metal compounds and protonic acids for plasticizing and neutralizing acidic, protonated compositions comprising substituted and unsubstituted polyanilines and co-polymers and or mixtures thereof; and for reducing the percolation threshold for conductivity in blends with insulating bulk polymers.
摘要翻译： 描述了涉及金属化合物和质子酸的反应产物用于增塑和中和包含取代和未取代的聚苯胺和共聚物及其混合物的酸性质子化组合物的组合物和方法; 并且用于减少与绝缘本体聚合物的共混物中的电导率的渗透阈值。
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公开(公告)号：US5585038A
公开(公告)日：1996-12-17
申请号：US253904
申请日：1994-06-03
申请人： Pauli Kirmanen , Esko Savolainen , Esa Virtanen , Toivo K arn a , Jukka Laakso , Heikki Ruohonen , Kimmo V akiparta , Olli Ikkala , Hannele J arvinen
发明人： Pauli Kirmanen , Esko Savolainen , Esa Virtanen , Toivo K arn a , Jukka Laakso , Heikki Ruohonen , Kimmo V akiparta , Olli Ikkala , Hannele J arvinen
CPC分类号： C08G73/0266 , H01B1/128
摘要： The invention relates to a conductive polymer complex which contains a polyaniline or derivative thereof doped with a protonic acid. By the method according to the invention, a conductive polymer is obtained having substantially reduced acidity, sufficiently high conductivity level, and which is suitable, for example, for being melt processed in conventional plastics processing apparatus. The acidity of the conductive polymer can be reduced by having the conductive polymer contain both a metal compound and an additionally neutralizing compound. The obtained conductive polymer material, having a pH value of approximately 3-8, can be mixed with an insulating polymer to produce a conductive plastics mixture. The invention also relates to a method of preparing a conductive polymer that is more processable by incorporating therein a plasticizing agent selected from the group consisting of water, a C.sub.1 -C.sub.3 alcohol, and mixtures thereof.
摘要翻译： 本发明涉及含有掺杂有质子酸的聚苯胺或其衍生物的导电聚合物络合物。 通过根据本发明的方法，获得了具有显着降低的酸度，足够高的导电率的导电聚合物，并且其适用于例如在常规塑料加工设备中熔融加工。 通过使导电聚合物含有金属化合物和另外的中和化合物，可以降低导电聚合物的酸度。 获得的pH值约为3-8的导电聚合物材料可与绝缘聚合物混合以制备导电塑料混合物。 本发明还涉及一种制备导电聚合物的方法，该导电聚合物通过在其中加入选自水，C1-C3醇及其混合物的增塑剂更加可加工。
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公开(公告)号：US5340499A
公开(公告)日：1994-08-23
申请号：US927858
申请日：1992-08-11
申请人： Toivo Karna , Jukka Laakso , Timo Niemi , Heikki Ruohonen , Esko Savolainen , Helge Lindstrom , Esa Virtanen , Olli Ikkala , Alejandro Andreatta
发明人： Toivo Karna , Jukka Laakso , Timo Niemi , Heikki Ruohonen , Esko Savolainen , Helge Lindstrom , Esa Virtanen , Olli Ikkala , Alejandro Andreatta
IPC分类号： C08K3/22 , C08L79/02 , C08L101/00 , H01B1/12 , H01B1/00
CPC分类号： H01B1/128 , C08K3/22 , C08L101/00 , C08L79/02 , Y10S264/17 , Y10S264/26 , Y10S428/922 , Y10T428/29 , Y10T428/31504
摘要： Compositions and methods are described that relate to the use of reaction products of metal compounds and protonic acids for plasticizing and neutralizing acidic, protonated compositions comprising substituted and unsubstituted polyanilines and co-polymers and or mixtures thereof; and for reducing the percolation threshold for conductivity in blends with insulating bulk polymers.
摘要翻译： 描述了涉及金属化合物和质子酸的反应产物用于增塑和中和包含取代和未取代的聚苯胺和共聚物及其混合物的酸性质子化组合物的组合物和方法; 并且用于减少与绝缘本体聚合物的共混物中的电导率的渗透阈值。
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公开(公告)号：US5346649A
公开(公告)日：1994-09-13
申请号：US988902
申请日：1992-12-04
申请人： Toivo Karna , Jukka Laakso , Kalle Levon , Esko Savolainen
发明人： Toivo Karna , Jukka Laakso , Kalle Levon , Esko Savolainen
CPC分类号： H01B1/128 , C08G73/0266 , C08K5/42 , C08L79/02 , C08L25/04
摘要： An electrically conducting plastic material is produced by blending a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof. A reaction product or blend of a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof can be brought to an easy-to-handle or directly melt-processable form through a heat-treatment process carried out at approx. +40.degree. to +250.degree. C. The obtained plastic material is advantageously further improved by blending the heat-treated reaction product or blend with a thermoplastic polymer and then melt-processing the mixed blend. The properties of the resulting compound material exhibit complete compatibility of the heat-treated reaction product or blend with the thermoplastic polymer.
摘要翻译： 通过将聚苯胺或其衍生物与有机磺酸或其衍生物共混来制造导电塑料材料。 聚苯胺或其衍生物与有机磺酸或其衍生物的反应产物或共混物可以通过在约3℃下进行的热处理过程使其易于处理或直接熔融加工形式。 + 40℃至+ 250℃。通过将热处理的反应产物或共混物与热塑性聚合物共混，然后熔融加工该混合共混物，所得塑料材料有利地进一步改进。 所得复合材料的性质表现出热处理反应产物或共混物与热塑性聚合物的完全相容性。
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公开(公告)号：US5928565A
公开(公告)日：1999-07-27
申请号：US611004
申请日：1996-03-05
申请人： Toivo Karna , Jukka Laakso , Kalle Levon , Esko Savolainen
发明人： Toivo Karna , Jukka Laakso , Kalle Levon , Esko Savolainen
CPC分类号： H01B1/128 , C08G73/0266 , C08K5/42 , C08L79/02 , C08L25/04
摘要： An electrically conducting plastic material is produced by blending a polyaniline or a derivative thereof with an organic sulfonic acid or a derivative thereof. A reaction product or blend of a polyaniline or a derivative thereon with an organic sulfonic acid or a derivative thereof can be brought to an easy-to-handle or directly melt-processable form through a heat-treatment process carried out at approx. +40.degree. to +250.degree. C. The obtained plastic material is advantageously further improved by blending the heat-treated reaction product or blend with a thermoplastic polymer and then melt-processing the mixed blend. The properties of the resulting compound material exhibit complete compatibility of the heat-treated reaction product or blend with the thermoplastic polymer.
摘要翻译： 通过将聚苯胺或其衍生物与有机磺酸或其衍生物共混来制造导电塑料材料。 聚苯胺或其衍生物与有机磺酸或其衍生物的反应产物或共混物可以通过在大约1小时进行的热处理过程使其易于处理或直接熔融加工形式。 + 40℃至+ 250℃。通过将热处理的反应产物或共混物与热塑性聚合物共混，然后熔融加工该混合共混物，所得塑料材料有利地进一步改进。 所得复合材料的性质表现出热处理反应产物或共混物与热塑性聚合物的完全相容性。
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公开(公告)号：US5436317A
公开(公告)日：1995-07-25
申请号：US168189
申请日：1993-12-17
申请人： Hannele Jarvinen , Jukka Laakso , Irma Auvinen , Eija Silvasti
发明人： Hannele Jarvinen , Jukka Laakso , Irma Auvinen , Eija Silvasti
CPC分类号： C08G73/0266 , H01B1/128
摘要： A method for preparing a polyaniline having a desired molar mass. Control of the molar mass of the polyaniline is achieved in connection with an aniline polymerization reaction, by feeding aniline and an oxidizing agent participating in the polymerization reaction gradually into a polymerization vessel. By varying the feeding speeds of the aniline and the oxidizing agent, polyanilines having different molar masses are obtained.
摘要翻译： 一种制备具有所需摩尔质量的聚苯胺的方法。 通过将参与聚合反应的苯胺和氧化剂逐渐加入到聚合容器中，与苯胺聚合反应相关地控制聚苯胺的摩尔质量。 通过改变苯胺和氧化剂的进料速度，得到具有不同摩尔质量的聚苯胺。
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8.发明授权Electrically conducting thermoset polymer compositions with hydroxy containing protonic acid dopant 失效具有羟基的质子酸掺杂剂的导电热固性聚合物组合物
公开(公告)号：US5662833A
公开(公告)日：1997-09-02
申请号：US562245
申请日：1995-11-22
摘要： The present invention relates to electrically conducting thermoset compositions and methods for preparing them. In the compositions according to the invention, the conducting component is a polyaniline protonated with a protonic acid containing at least one hydroxyl group. The thermoset matrix can be, for instance, a phenol-formaldehyde resin, a melamine-formaldehyde resin, or a polyester resin.
摘要翻译： 本发明涉及导电热固性组合物及其制备方法。 在根据本发明的组合物中，导电组分是用含有至少一个羟基的质子酸质子化的聚苯胺。 热固性基质可以是例如酚醛树脂，三聚氰胺 - 甲醛树脂或聚酯树脂。
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公开(公告)号：US5279769A
公开(公告)日：1994-01-18
申请号：US777396
申请日：1991-12-02
申请人： Timo Kokkonen , Toivo Karna , Jukka Laakso , Per Nyholm , Jan-Erik sterholm , Henrik Stubb
发明人： Timo Kokkonen , Toivo Karna , Jukka Laakso , Per Nyholm , Jan-Erik sterholm , Henrik Stubb
IPC分类号： C08J3/20 , C08L65/00 , C08L101/00 , H01B1/12 , H01B13/00
摘要： The invention relates to a method for preparing a conductive polymer product by doping a conductor polymer. The conductor polymer or a mixture of the conductor polymer and a matrix polymer is in a molten state brought into contact with a doping agent, whereafter the mixture is treated into a product.
摘要翻译： 本发明涉及通过掺杂导体聚合物制备导电聚合物产品的方法。 导体聚合物或导体聚合物和基质聚合物的混合物处于与掺杂剂接触的熔融状态，之后将混合物处理成产物。
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公开(公告)号：US5219492A
公开(公告)日：1993-06-15
申请号：US898286
申请日：1992-07-09
CPC分类号： H01B1/128 , C08G61/126 , H01M4/60
摘要： The invention relates to a conductive polymer composite wherein the internally conductive polymer component consists of a polymer of a 3-substituted thiophene, the polymer being doped with a suitable electron acceptor or electron emitter compound. The polymer composite is prepared by processing in molten state by various methods such as extrusion molding, injection molding, compression molding, or sheet blowing, together with a suitable polymer matrix, to form a homogenous composite.
摘要翻译： 本发明涉及一种导电聚合物复合材料，其中内部导电聚合物组分由3-取代噻吩的聚合物组成，该聚合物掺杂有合适的电子受体或电子发射体化合物。 聚合物复合材料通过与各种方法如挤出成型，注射成型，压缩成型或片材吹制以及合适的聚合物基质一起在熔融状态下加工制备，以形成均匀的复合材料。
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