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1.发明申请RADICAL-POLYMERIZABLE RESIN, RADICAL-POLYMERIZABLE RESIN COMPOSITION, AND CURED MATERIAL THEREOF 有权光学聚合树脂，光聚合树脂组合物及其固化材料公开(公告)号：US20130030078A1
公开(公告)日：2013-01-31
申请号：US13642363
申请日：2011-03-28
IPC分类号： C08G63/66
CPC分类号： C08F299/026 , C08F290/144 , C08G65/14 , C08G65/18 , C08G65/22 , C08F222/10
摘要： Provided is a radical-polymerizable resin capable of giving a cured material which is satisfactorily flexible, can relax stress upon usage as an adhesive, and does not cause disadvantages such as separation at the adhesive interface or breakage of an adherend, which stress occurs between the adhesive and the adherend upon heating or cooling and is caused by difference in coefficient of thermal expansion between them.The radical-polymerizable resin is obtained through cationic polymerization of a compound represented by any of following Formulae (1a) and (1b) and a compound represented by any of following Formulae (2a), (2b), (2c), (2d), (2e), and (2f). The radical-polymerizable resin is liquid at 0° C. and has a weight-average molecular weight of 500 or more. Symbols in the formulae are as defined in the description.
摘要翻译： 提供一种能够赋予令人满意的柔软性的固化物的自由基聚合性树脂，可以在作为粘合剂使用时放松应力，并且不会引起诸如粘合界面处的分离或被粘物的断裂等缺点， 粘合剂和被粘物在加热或冷却时是由它们之间的热膨胀系数的差异引起的。 可通过下述通式（1a）和（1b）中任一项所示的化合物的阳离子聚合和由下式（2a），（2b），（2c），（2d） ，（2e）和（2f）。 可自由基聚合的树脂在0℃下为液体，重均分子量为500以上。 式中的符号如说明书中所定义。
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2.发明授权Cationically polymerizable resin, cationically polymerizable resin composition, and cured products thereof 有权阳离子聚合性树脂，阳离子聚合性树脂组合物及其固化物公开(公告)号：US08981040B2
公开(公告)日：2015-03-17
申请号：US13578561
申请日：2011-01-24
IPC分类号： C08F220/32 , C08G65/18 , C08G65/22 , C08F220/28
CPC分类号： C08G65/18 , C08F220/32 , C08F2220/282 , C08G65/22
摘要： Provided is a cationically polymerizable resin which is rapidly cured upon irradiation with light and forms a cured product excellent in flexibility and thermal stability. The cationically polymerizable resin is obtained through radical polymerization of an oxetane-ring-containing (meth)acryloyl compound represented by following Formula (1) alone or in combination with another radically polymerizable compound. In the formula, R1 represents hydrogen atom or methyl group; R2 represents hydrogen atom or an alkyl group; and “A” represents a linear or branched chain alkylene group having 2 to 20 carbon atoms.
摘要翻译： 提供一种阳离子聚合性树脂，其在照射光时迅速固化，形成柔软性和热稳定性优异的固化物。 阳离子聚合性树脂通过单独或与其它自由基聚合性化合物的单独或下述式（1）表示的含氧杂环丁烷的（甲基）丙烯酰基化合物自由基聚合而得到。 在该式中，R 1表示氢原子或甲基; R2表示氢原子或烷基; “A”表示碳原子数2〜20的直链或支链亚烷基。
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3.发明申请公开(公告)号：US20120077946A1
公开(公告)日：2012-03-29
申请号：US13376082
申请日：2010-05-20
IPC分类号： C08F224/00 , C08G63/66
CPC分类号： C08G59/3209 , C08G65/18 , C08G65/22
摘要： Disclosed is a cationically polymerizable resin composition which includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-containing vinyl ether compound (B); and an oligomer or polymer (C) having a molecular weight of 500 or more, being liquid at 0° C., and containing at least one of structures represented by following Formulae (1a) to (1f), wherein Rx represents hydrogen atom or methyl group; R1 to R3 each independently represent a hydrocarbon group having 1 to 5 carbon atoms; “a” is an integer of from 0 to 5; and “b” is 1 or 2. This cationically polymerizable resin composition has a low viscosity, is easy to work, cures extremely rapidly upon irradiation with light, and can give a cured object excellent in flexibility, thermal stability, and bendability after heat treatment.
摘要翻译： 公开了包含含氧杂环丁烷的乙烯基醚化合物（A）和/或含脂环式环氧基的乙烯基醚化合物（B）的阳离子聚合性树脂组合物。 以及分子量为500以上的低分子或聚合物（C），在0℃下为液体，并含有下述式（1a）〜（1f）表示的结构中的至少一种，其中，Rx表示氢原子或 甲基; R 1〜R 3各自独立地表示碳原子数1〜5的烃基。 “a”是0至5的整数; 该“b”为1或2.该阳离子聚合性树脂组合物的粘度低，易于加工，照射后能够极快地固化，能够得到热处理后的柔软性，热稳定性和弯曲性优异的固化物 。
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4.发明授权Radical-polymerizable resin, radical-polymerizable resin composition, and cured material thereof 有权可自由基聚合树脂，自由基聚合性树脂组合物及其固化物公开(公告)号：US08735462B2
公开(公告)日：2014-05-27
申请号：US13642363
申请日：2011-03-28
IPC分类号： C07D303/40 , C08F2/46 , C08G61/04
CPC分类号： C08F299/026 , C08F290/144 , C08G65/14 , C08G65/18 , C08G65/22 , C08F222/10
摘要： Provided is a radical-polymerizable resin capable of giving a cured material which is satisfactorily flexible, can relax stress upon usage as an adhesive, and does not cause disadvantages such as separation at the adhesive interface or breakage of an adherend, which stress occurs between the adhesive and the adherend upon heating or cooling and is caused by difference in coefficient of thermal expansion between them.The radical-polymerizable resin is obtained through cationic polymerization of a compound represented by any of following Formulae (1a) and (1b) and a compound represented by any of following Formulae (2a), (2b), (2c), (2d), (2e), and (2f). The radical-polymerizable resin is liquid at 0 ° C. and has a weight-average molecular weight of 500 or more. Symbols in the formulae are as defined in the description.
摘要翻译： 提供一种能够赋予令人满意的柔软性的固化物的自由基聚合性树脂，可以在作为粘合剂使用时放松应力，并且不会引起诸如粘合界面处的分离或被粘物的断裂等缺点， 粘合剂和被粘物在加热或冷却时是由它们之间的热膨胀系数的差异引起的。 可通过下述通式（1a）和（1b）中任一项所示的化合物的阳离子聚合和由下式（2a），（2b），（2c），（2d） ，（2e）和（2f）。 可自由基聚合的树脂在0℃下为液体，重均分子量为500以上。 式中的符号如说明书中所定义。
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5.发明申请RADICAL POLYMERIZABLE RESIN, RADICAL POLYMERIZABLE RESIN COMPOSITION, AND CURED PRODUCT THEREOF 审中-公开自由基聚合树脂，光聚合树脂组合物及其固化产品公开(公告)号：US20130035465A1
公开(公告)日：2013-02-07
申请号：US13641354
申请日：2011-04-08
IPC分类号： C07D305/06 , C08G63/66 , C08F124/00
CPC分类号： C08F2/44 , C08F220/30 , C08F220/32 , C08F265/06 , C08F283/105 , C08G65/18 , C08G65/22
摘要： Provided is a radically polymerizable resin which has a low viscosity, has excellent workability, and is rapidly cured upon application of heat and/or light to form a cured product having excellent flexibility and thermal stability. The radically polymerizable resin composition is obtained by cationic polymerization of an oxetane-ring-containing (meth)acrylic ester compound represented by following Formula (1) alone or in combination with another cationically polymerizable compound. In Formula (1), R1 represents hydrogen atom or methyl group; R2 represents hydrogen atom or an alkyl group; and “A” represents a linear or branched chain alkylene group having 4 to 20 carbon atoms.
摘要翻译： 提供一种具有低粘度，加工性优异的自由基聚合性树脂，并且在施加热和/或光时迅速固化以形成具有优异的柔性和热稳定性的固化产物。 可自由基聚合的树脂组合物通过单独或与另一种阳离子聚合性化合物的组合使由下述式（1）表示的含氧杂环丁烷的（甲基）丙烯酸酯化合物阳离子聚合而得到。 在式（1）中，R 1表示氢原子或甲基; R2表示氢原子或烷基; A表示碳原子数为4〜20的直链或支链亚烷基。
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6.发明授权Cationically polymerizable resin composition and cured object obtained therefrom 有权阳离子聚合性树脂组合物和由其获得的固化物公开(公告)号：US08975349B2
公开(公告)日：2015-03-10
申请号：US13376082
申请日：2010-05-20
IPC分类号： C08F224/00 , C08G63/66 , C08G59/32 , C08G65/18 , C08G65/22
CPC分类号： C08G59/3209 , C08G65/18 , C08G65/22
摘要： Disclosed is a cationically polymerizable resin composition which includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-containing vinyl ether compound (B); and an oligomer or polymer (C) having a molecular weight of 500 or more, being liquid at 0° C., and containing at least one of structures represented by following Formulae (1a) to (1f), wherein Rx represents hydrogen atom or methyl group; R1 to R3 each independently represent a hydrocarbon group having 1 to 5 carbon atoms; “a” is an integer of from 0 to 5; and “b” is 1 or 2. This cationically polymerizable resin composition has a low viscosity, is easy to work, cures extremely rapidly upon irradiation with light, and can give a cured object excellent in flexibility, thermal stability, and bendability after heat treatment.
摘要翻译： 公开了包含含氧杂环丁烷的乙烯基醚化合物（A）和/或含脂环式环氧基的乙烯基醚化合物（B）的阳离子聚合性树脂组合物。 以及分子量为500以上的低分子或聚合物（C），在0℃下为液体，并含有下述式（1a）〜（1f）表示的结构中的至少一种，其中，Rx表示氢原子或 甲基; R 1〜R 3各自独立地表示碳原子数1〜5的烃基。 “a”是0至5的整数; 该“b”为1或2.该阳离子聚合性树脂组合物的粘度低，易于加工，照射后能够极快地固化，能够得到热处理后的柔软性，热稳定性和弯曲性优异的固化物 。
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7.发明申请CATIONICALLY POLYMERIZABLE RESIN, CATIONICALLY POLYMERIZABLE RESIN COMPOSITION, AND CURED PRODUCTS THEREOF 有权阳离子聚合树脂，阳离子聚合树脂组合物及其固化产品公开(公告)号：US20120309930A1
公开(公告)日：2012-12-06
申请号：US13578561
申请日：2011-01-24
IPC分类号： C07D305/06 , C08G65/00
CPC分类号： C08G65/18 , C08F220/32 , C08F2220/282 , C08G65/22
摘要： Provided is a cationically polymerizable resin which is rapidly cured upon irradiation with light and forms a cured product excellent in flexibility and thermal stability. The cationically polymerizable resin is obtained through radical polymerization of an oxetane-ring-containing (meth)acryloyl compound represented by following Formula (1) alone or in combination with another radically polymerizable compound. In the formula, R1 represents hydrogen atom or methyl group; R2 represents hydrogen atom or an alkyl group; and “A” represents a linear or branched chain alkylene group having 2 to 20 carbon atoms.
摘要翻译： 提供一种阳离子聚合性树脂，其在照射光时迅速固化，形成柔软性和热稳定性优异的固化物。 阳离子聚合性树脂通过单独或与其它自由基聚合性化合物的单独或下述式（1）表示的含氧杂环丁烷的（甲基）丙烯酰基化合物自由基聚合而得到。 在该式中，R 1表示氢原子或甲基; R2表示氢原子或烷基; A表示碳原子数2〜20的直链或支链亚烷基。
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8.发明申请APPARATUS FOR PRODUCING OPTICAL FIBER, METHOD FOR PRODUCING OPTICAL FIBER, AND OPTICAL FIBER PRODUCED BY METHOD 审中-公开用于生产光纤的设备，用于生产光纤的方法和通过方法产生的光纤公开(公告)号：US20130315553A1
公开(公告)日：2013-11-28
申请号：US13983242
申请日：2012-01-27
申请人： Masaki Takebe , Tomoaki Mahiko , Yoshinori Funaki , Shinji Syuto , Hitomi Omae
发明人： Masaki Takebe , Tomoaki Mahiko , Yoshinori Funaki , Shinji Syuto , Hitomi Omae
CPC分类号： B29D11/00663 , B29C35/0805 , B29C35/10 , B29C2035/0827 , B29C2035/0838 , C08F2/48 , G02B6/00 , G02B6/02033
摘要： An apparatus produces an optical fiber by applying light to a photocurable composition and thereby curing the composition. The apparatus includes a nozzle for discharging the photocurable composition; a light irradiator for applying light to the fibrous photocurable composition discharged from the nozzle; and a controller that controls a light irradiation intensity at the nozzle orifice to 0.2 mW/cm2 or less. The nozzle is preferably a double-tube nozzle having an outer tube; and an inner tube arranged inside the outer tube.
摘要翻译： 一种装置通过将光照射到可光固化的组合物上并由此固化该组合物而产生光纤。 该装置包括用于排出可光固化组合物的喷嘴; 用于对从喷嘴排出的纤维状光固化性组合物施加光的光照射器; 以及将喷嘴孔处的光照射强度控制在0.2mW / cm 2以下的控制器。 喷嘴优选为具有外管的双管喷嘴; 以及布置在外管内的内管。
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公开(公告)号：US07105268B2
公开(公告)日：2006-09-12
申请号：US10239051
申请日：2001-12-11
IPC分类号： G03F7/039 , G03F7/26 , C08F20/28 , C07D311/94 , C07D313/20
CPC分类号： G03F7/0395 , G03F7/0397 , Y10S430/109
摘要： A polymeric compound for photoresist of the invention includes at least one monomer unit represented by following Formula (I): wherein R1, R2, R3, R4 and R5 are the same or different and are each a hydrogen atom or a methyl group; m, p and q each denote an integer of from 0 to 2; and n denotes 0 or 1, where the hydroxyl group and carbonyloxy group extending from a principle chain in the formula are independently combined with either of two carbon atoms on the far-left portion of the rings. By using the polymeric compound for photoresist as a base of a photoresist, the resulting photoresist exhibits well-rounded adhesion to substrates and resistance to etching.
摘要翻译： 本发明的光刻胶用高分子化合物包括至少一种由下式（I）表示的单体单元：其中R 1，R 2，R 3， R 4，R 4和R 5相同或不同，各自为氢原子或甲基; m，p和q分别表示0〜2的整数。 并且n表示0或1，其中从式中的主链延伸的羟基和羰氧基独立地与环的最左部分的两个碳原子中的任一个结合。 通过使用光致抗蚀剂的高分子化合物作为光致抗蚀剂的基底，所得到的光致抗蚀剂表现出对基底的良好的圆形粘附性和耐蚀刻性。
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公开(公告)号：US07090925B2
公开(公告)日：2006-08-15
申请号：US10807326
申请日：2004-03-24
CPC分类号： C08J5/18 , C08G73/10 , C08G73/18 , C08J2379/04 , C08L79/04 , Y10T428/1023 , Y10T428/24917 , Y10T428/31504 , Y10T428/31681 , Y10T428/31721
摘要： A material for dielectric films is a polymerizable composition containing an adamantanepolycarboxylic acid represented by following Formula (1):wherein X is a hydrogen atom, a carboxyl group or a hydrocarbon group; and Y1, Y2, Y3 and Y4 are the same as or different from one another and are each a single bond or a bivalent aromatic cyclic group; an aromatic polyamine represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R1 and R2 are each a substituent bound to Ring Z, are the same as or different from each other and are each an amino group, a mono-substituted amino group, a hydroxyl group or a mercapto group; and a solvent other than ketones and aldehydes, in which the adamantanepolycarboxylic acid and aromatic polyamine are dissolved in the solvent
摘要翻译： 介电膜用材料是含有下述式（1）表示的金刚烷多元羧酸的聚合性组合物：其中X为氢原子，羧基或烃基; 和Y 1，Y 2，Y 3和Y 4相同或不同，并且 各自为单键或二价芳族环基; 由下式（2）表示的芳族多胺：其中环Z是单环或多环芳环; R 1和R 2各自为与环Z结合的取代基，彼此相同或不同，并且各自为氨基，单取代的氨基 基，羟基或巯基; 和除酮和醛之外的溶剂，其中金刚烷多羧酸和芳族多胺溶解在溶剂中
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