公开(公告)号：US07090925B2

公开(公告)日：2006-08-15

申请号：US10807326

申请日：2004-03-24

申请人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

发明人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

IPC分类号： B32B27/00 ,  C08G73/10

CPC分类号： C08J5/18 ,  C08G73/10 ,  C08G73/18 ,  C08J2379/04 ,  C08L79/04 ,  Y10T428/1023 ,  Y10T428/24917 ,  Y10T428/31504 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A material for dielectric films is a polymerizable composition containing an adamantanepolycarboxylic acid represented by following Formula (1):wherein X is a hydrogen atom, a carboxyl group or a hydrocarbon group; and Y1, Y2, Y3 and Y4 are the same as or different from one another and are each a single bond or a bivalent aromatic cyclic group; an aromatic polyamine represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R1 and R2 are each a substituent bound to Ring Z, are the same as or different from each other and are each an amino group, a mono-substituted amino group, a hydroxyl group or a mercapto group; and a solvent other than ketones and aldehydes, in which the adamantanepolycarboxylic acid and aromatic polyamine are dissolved in the solvent

摘要翻译： 介电膜用材料是含有下述式（1）表示的金刚烷多元羧酸的聚合性组合物：其中X为氢原子，羧基或烃基; 和Y 1，Y 2，Y 3和Y 4相同或不同，并且 各自为单键或二价芳族环基; 由下式（2）表示的芳族多胺：其中环Z是单环或多环芳环; R 1和R 2各自为与环Z结合的取代基，彼此相同或不同，并且各自为氨基，单取代的氨基 基，羟基或巯基; 和除酮和醛之外的溶剂，其中金刚烷多羧酸和芳族多胺溶解在溶剂中

公开(公告)号：US07186454B2

公开(公告)日：2007-03-06

申请号：US10807426

申请日：2004-03-24

申请人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

发明人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

IPC分类号： B32B27/00 ,  C08G73/10

CPC分类号： C08J5/18 ,  C08G73/10 ,  C08G73/18 ,  C08J2379/04 ,  C08L79/04 ,  Y10T428/24917 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A material for dielectric films is a polymerizable composition containing an organic solvent, and an adamantanepolycarboxylic acid derivative represented by following Formula (1): wherein X is hydrogen atom, a hydrocarbon group or R4; R1, R2, R3 and R4 and are each independently a protected or unprotected carboxyl group, etc.; and Y1, Y2, Y3 and Y4 are each independently a single bond or a bivalent aromatic cyclic group; and an aromatic polyamine derivative represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R5, R6, R7 and R8 are each a substituent bound to Ring Z and are each independently a protected or unprotected amino group, etc., dissolved in the organic solvent.

摘要翻译： 电介质膜用材料是含有有机溶剂的聚合性组合物和下述式（1）表示的金刚烷多羧酸衍生物：其中X为氢原子，烃基或R 4; R 1，R 2，R 3和R 4，并且各自独立地是保护的或未被保护的羧基， 等等。; 且Y 1，Y 2，Y 3和Y 4各自独立地为单键或二价芳基 环状基团 和由下式（2）表示的芳族多胺衍生物：其中环Z是单环或多环芳环; R 5，R 6，R 7和R 8各自为与环Z结合的取代基，并且分别为 各自独立地是被溶解在有机溶剂中的被保护或未保护的氨基等。

公开(公告)号：US20060241275A1

公开(公告)日：2006-10-26

申请号：US11475022

申请日：2006-06-27

申请人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

发明人： Shinya Nagano ,  Jiichiro Hashimoto ,  Kiyoharu Tsutsumi ,  Yoshinori Funaki

IPC分类号： C08G8/02

CPC分类号： C08J5/18 ,  C08G73/10 ,  C08G73/18 ,  C08J2379/04 ,  C08L79/04 ,  Y10T428/1023 ,  Y10T428/24917 ,  Y10T428/31504 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A material for dielectric films is a polymerizable composition containing an adamantanepolycarboxylic acid represented by following Formula (1): wherein X is a hydrogen atom, a carboxyl group or a hydrocarbon group; and Y1, Y2, Y3 and Y4 are the same as or different from one another and are each a single bond or a bivalent aromatic cyclic group; an aromatic polyamine represented by following Formula (2): wherein Ring Z is a monocyclic or polycyclic aromatic ring; and R1 and R2 are each a substituent bound to Ring Z, are the same as or different from each other and are each an amino group, a mono-substituted amino group, a hydroxyl group or a mercapto group; and a solvent other than ketones and aldehydes, in which the adamantanepolycarboxylic acid and aromatic polyamine are dissolved in the solvent.

摘要翻译： 介电膜用材料是含有下述式（1）表示的金刚烷多元羧酸的聚合性组合物：其中X为氢原子，羧基或烃基; 和Y 1，Y 2，Y 3和Y 4相同或不同，并且 各自为单键或二价芳族环基; 由下式（2）表示的芳族多胺：其中环Z是单环或多环芳环; R 1和R 2各自为与环Z结合的取代基，彼此相同或不同，并且各自为氨基，单取代的氨基 基，羟基或巯基; 和除酮和醛之外的溶剂，其中金刚烷多羧酸和芳族多胺溶解在溶剂中。

公开(公告)号：US07102027B2

公开(公告)日：2006-09-05

申请号：US10807284

申请日：2004-03-24

申请人： Shinya Nagano ,  Jiichiro Hashimoto

发明人： Shinya Nagano ,  Jiichiro Hashimoto

IPC分类号： C07C69/753 ,  C07C61/15 ,  C07C233/58 ,  C07D307/20 ,  C07F7/18 ,  C07D403/14

CPC分类号： C07C51/60 ,  Y02P20/55 ,  C07C61/135

摘要： An adamantanetricarboxylic acid derivative is represented by following Formula (1): wherein X is a hydrogen atom or a hydrocarbon group; and R1, R2 and R3 may be the same as or different from one another and are each a carboxyl group which may be protected by a protecting group, or a carbonyl halide group, wherein at least one of R1, R2 and R3 is a carboxyl group which is protected by a protecting group, or a carbonyl halide group.

摘要翻译： 金刚烷三羧酸衍生物由下式（1）表示：其中X是氢原子或烃基; R 1，R 2，R 3和R 3可以彼此相同或不同，并且各自为可被保护的羧基 保护基或羰基卤基，其中R 1，R 2和R 3中的至少一个是羧基，其中R 1，R 2，R 3和R 3中的至少一个是羧基， 被保护基团或羰基卤基团保护。

公开(公告)号：US20060264667A1

公开(公告)日：2006-11-23

申请号：US11492888

申请日：2006-07-26

申请人： Shinya Nagano ,  Jiichiro Hashimoto

发明人： Shinya Nagano ,  Jiichiro Hashimoto

IPC分类号： C07C61/12

CPC分类号： C07C51/60 ,  Y02P20/55 ,  C07C61/135

摘要： An adamantanetricarboxylic acid derivative is presented by following Formula (1): wherein X is a hydrogen atom or a hydrocarbon group; and R1, R2 and R3 may be the same as or different from one another and are each a carboxyl group which may be protected by a protecting group, or a carbonyl halide group, wherein at least one of R1, R2 and R3 is a carboxyl group which is protected by a protecting group, or a carbonyl halide group.

摘要翻译： 金刚烷三羧酸衍生物由下式（1）表示：其中X为氢原子或烃基; R 1，R 2，R 3和R 3可以彼此相同或不同，并且各自为可被保护的羧基 保护基或羰基卤基，其中R 1，R 2和R 3中的至少一个是羧基，其中R 1，R 2，R 3和R 3中的至少一个是羧基， 被保护基团或羰基卤基团保护。

公开(公告)号：US20070032556A1

公开(公告)日：2007-02-08

申请号：US10577313

申请日：2004-10-20

申请人： Shinya Nagano ,  Jiichiro Hashimoto

发明人： Shinya Nagano ,  Jiichiro Hashimoto

IPC分类号： A61K31/135

CPC分类号： C07C251/20 ,  C07C251/08 ,  C07C251/18 ,  C07C2601/14

摘要： Aromatic polyamine derivatives of this invention are represented by following Formula (1): wherein Ring Z represents a monocyclic or polycyclic aromatic ring; Ra, Rb, Rc, and Rd are each a substituent bonded to Ring Z, where Ra and Rb are the same as or different from each other and each represent a protected or unprotected amino group, and Rc and Rd are the same as or different from each other and each represent a protected or unprotected amino group, a protected or unprotected hydroxy group, or a protected or unprotected mercapto group, and wherein at least one of Ra, Rb, Rc, and Rd represents an amino group protected by an alkylidene group.

摘要翻译： 本发明的芳族多胺衍生物由下式（1）表示：其中环Z表示单环或多环芳环; R a，R b，R c，R d和R d各自是键合到环Z的取代基，其中 R a和R b彼此相同或不同，并且各自表示被保护或未被保护的氨基，R和C和R 各自表示保护的或未被保护的氨基，被保护的或未被保护的羟基，或被保护或未被保护的巯基，并且其中至少一个R' 其中，R a，R b，R c和R d表示被亚烷基保护的氨基。

公开(公告)号：US07368615B2

公开(公告)日：2008-05-06

申请号：US11242779

申请日：2005-10-05

申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

IPC分类号： C07C13/00

CPC分类号： C07C51/313 ,  B01J31/006 ,  B01J31/0209 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2531/845 ,  C07C29/50 ,  C07C45/33 ,  C07C45/39 ,  C07C51/265 ,  C07C201/02 ,  C07C201/08 ,  C07C2601/14 ,  C07D209/48 ,  C07C49/403 ,  C07C49/04 ,  C07C63/06 ,  C07C55/12 ,  C07C55/14 ,  C07C203/08 ,  C07C205/05 ,  C07C31/125 ,  C07C35/08

摘要： A catalyst includes a cyclic imide compound having an N-substituted cyclic imide skeleton represented by following Formula (I): wherein X is an oxygen atom or a hydroxyl group, and having a solubility parameter of less than or equal to 26 [(MPa)1/2] as determined by Fedors method. The catalyst may further comprise a metallic compound. By allowing (A) a compound capable of forming a radical to react with (B) a radical scavenging compound in the presence of the catalyst, an addition or substitution reaction product between the compound (A) and the compound (B) or a derivative thereof can be obtained.

摘要翻译： 催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的环状酰亚胺化合物：其中X是氧原子或羟基，溶解度参数小于或等于26 [（MPa） 通过Fedors方法测定的 ^{1/2。 催化剂还可以包含金属化合物。 通过使（A）能够形成自由基的化合物与（B）自由基清除化合物在催化剂存在下反应的化合物（A）和化合物（B）之间的加成或取代反应产物或衍生物 可以得到。}

公开(公告)号：US06998491B2

公开(公告)日：2006-02-14

申请号：US10092554

申请日：2002-03-08

申请人： Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

发明人： Yasutaka Ishii ,  Tatsuya Nakano ,  Shinya Nagano ,  Naoto Okuyama

IPC分类号： C07D207/00 ,  B07J31/02

CPC分类号： C07C51/313 ,  B01J31/006 ,  B01J31/0209 ,  B01J31/0247 ,  B01J31/0271 ,  B01J31/2208 ,  B01J2231/70 ,  B01J2531/845 ,  C07C29/50 ,  C07C45/33 ,  C07C45/39 ,  C07C51/265 ,  C07C201/02 ,  C07C201/08 ,  C07C2601/14 ,  C07D209/48 ,  C07C49/403 ,  C07C49/04 ,  C07C63/06 ,  C07C55/12 ,  C07C55/14 ,  C07C203/08 ,  C07C205/05 ,  C07C31/125 ,  C07C35/08

摘要： A catalyst includes a cyclic imide compound having an N-substituted cyclic imide skeleton represented by following Formula (I): wherein X is an oxygen atom or a hydroxyl group, and having a solubility parameter of less than or equal to 26 [(MPa)1/2] as determined by Fedors method. The catalyst may further comprise a metallic compound. By allowing (A) a compound capable of forming a radical to react with (B) a radical scavenging compound in the presence of the catalyst, an addition or substitution reaction product between the compound (A) and the compound (B) or a derivative thereof can be obtained.

摘要翻译： 催化剂包括具有由下式（I）表示的N-取代的环状酰亚胺骨架的环状酰亚胺化合物：<化学式id =“CHEM-US-00001”num =“000

公开(公告)号：US06670499B1

公开(公告)日：2003-12-30

申请号：US09869858

申请日：2001-07-06

申请人： Keizo Inoue ,  Shinya Nagano

发明人： Keizo Inoue ,  Shinya Nagano

IPC分类号： C07C6974

CPC分类号： A61K6/0023 ,  A61K6/0017 ,  A61K6/083 ,  C07C69/753 ,  C07C271/34 ,  C07C2603/74 ,  C08F22/105 ,  C08L33/00

摘要： Adamantane derivatives in which two (meth)acryloyloxyalkyl groups are bonded with an adamantane ring through ester groups, adamantane derivatives in which two adamantane rings are bonded through an alkylene group and two urethane bonds, which two adamantane rings each have a (meth)acryloyloxy group bonded thereto directly or through a coupling group, and adamantane derivatives each having a structure in which a group containing an adamantane ring hangs on the alkylene group of an alkylene glycol di(meth)acrylate. The compounds are useful as dental materials intermediates therefor, and as intermediates for optical materials such as lenses.

摘要翻译： 其中两个（甲基）丙烯酰氧基烷基通过酯基与金刚烷环键合的金刚烷衍生物，其中两个金刚烷环通过亚烷基和两个氨基甲酸酯键结合的金刚烷衍生物，这两个金刚烷环各自具有（甲基）丙烯酰氧基 以及金刚烷衍生物各自具有其中含有金刚烷环的基团悬挂在亚烷基二醇二（甲基）丙烯酸酯的亚烷基上的结构。 这些化合物可用作牙科材料的中间体，以及作为光学材料如透镜的中间体。

公开(公告)号：US06515165B1

公开(公告)日：2003-02-04

申请号：US09889882

申请日：2001-07-24

申请人： Keizo Inoue ,  Shinya Nagano ,  Tomohide Ina

发明人： Keizo Inoue ,  Shinya Nagano ,  Tomohide Ina

IPC分类号： C07C6974

CPC分类号： G03F7/0045 ,  C07C67/14 ,  C07C67/48 ,  C07C69/753 ,  C07C2602/42 ,  C07C2603/74

摘要： In a process of the present invention for producing a bridged cyclic polycarboxylic acid t-butyl ester, a bridged cyclic polycarboxylic halide of following Formula (1): (wherein ring Z is a bridged cyclic carbon ring; X is a halogen atom; and m denotes an integer of 2 or more, where ring Z may have a substituent) is allowed to react with t-butyl alcohol or its alkali metal salt to thereby yield an ester of following Formula (2): (wherein tBu is a t-butyl group; and ring Z and m have the same meanings as defined above.) This process can commercially efficiently produce a bridged cyclic polycarboxylic acid t-butyl ester. The compound of Formula (1) can be prepared by allowing a bridged cyclic polycarboxylic acid of following Formula (3): (wherein ring Z is a bridged cyclic carbon ring; and m denotes an integer of 2 or more, where ring Z may have a substituent) to react with a halogenating agent.

摘要翻译： 在本发明的制备桥联环状多元羧酸叔丁酯的方法中，具有下式（1）的桥连环状多羧酸卤化物（其中环Z是桥连环碳环; X是卤素原子; m 表示2以上的整数，其中环Z可以具有取代基）与叔丁醇或其碱金属盐反应，从而得到下式（2）的酯:(其中tBu是叔丁基 基团;且环Z和m具有与上述相同的含义。）该方法可商业上有效地制备桥连环状多元羧酸叔丁酯。 式（1）的化合物可以通过使下述式（3）的桥连环状多元羧酸（其中环Z为桥连环状碳环; m表示2以上的整数，其中环Z可以具有 取代基）与卤化剂反应。