公开(公告)号：US20060128933A1

公开(公告)日：2006-06-15

申请号：US10525452

申请日：2003-08-27

申请人： Toru Morita ,  Hitoshi Yamazaki ,  Jinichiro Kato ,  Teruhiko Matsuo

发明人： Toru Morita ,  Hitoshi Yamazaki ,  Jinichiro Kato ,  Teruhiko Matsuo

IPC分类号： C08G16/00

CPC分类号： D01F6/30 ,  B60C9/0042

摘要： Polyketone fibers comprising, on the basis of the entire repeating units, 95% by mole of a repeating unit of the formula (1) shown below, and showing a minimum value (Amin(F)) of a UV absorbance of 0.5 or less in a wavelength region of 210 to 240 nm. —CH2CH2—CO—  (1)

摘要翻译： 基于整个重复单元，包含以下所示的式（1）的重复单元为95摩尔％，表示最小值（A min min（F））的聚酮纤维 在210〜240nm的波长范围内的紫外吸光度为0.5以下。 <？in-line-formula description =“In-line Formulas”end =“lead”？> CH 2 2 CH 2 2 -CO-（1）<βin -line-formula description =“内联公式”end =“tail”？>

公开(公告)号：US07459516B2

公开(公告)日：2008-12-02

申请号：US10525452

申请日：2003-08-27

申请人： Toru Morita ,  Hitoshi Yamazaki ,  Jinichiro Kato ,  Teruhiko Matsuo

发明人： Toru Morita ,  Hitoshi Yamazaki ,  Jinichiro Kato ,  Teruhiko Matsuo

IPC分类号： C08G16/00 ,  B60C9/00 ,  D01F6/28 ,  D01F6/30

CPC分类号： D01F6/30 ,  B60C9/0042

摘要： Polyketone fibers comprising, on the basis of the entire repeating units, 95% by mole of a repeating unit of the formula (1) shown below, and showing a minimum value (Amin(F)) of a UV absorbance of 0.5 or less in a wavelength region of 210 to 240 nm. —CH2CH2—CO—   (1)

摘要翻译： 基于整个重复单元，包含以下所示的式（1）的重复单元为95摩尔％，并且显示UV吸光度的最小值（Amin（F））为0.5以下的聚酮纤维， 波长区域为210〜240nm。 <？in-line-formula description =“In-line Formulas”end =“lead”？> - CH2CH2-CO-（1）<？in-line-formula description =“In-line Formulas”end =“tail” ？>

公开(公告)号：US20050104030A1

公开(公告)日：2005-05-19

申请号：US10507840

申请日：2003-03-14

申请人： Jinichiro Kato ,  Satoru Yoshida ,  Teruhiko Matsuo

发明人： Jinichiro Kato ,  Satoru Yoshida ,  Teruhiko Matsuo

IPC分类号： C08G63/183 ,  C08G63/80 ,  D01F6/62 ,  C02F5/10

CPC分类号： C08G63/80 ,  C08G63/183 ,  D01F6/62 ,  Y10T428/29 ,  Y10T428/2913

摘要： Poly(trimethylene terephthalate) composition particles comprising 80% by weight or more of trimethylene terephthalate units based on the entire repeating units, having an intrinsic viscosity from 0.8 to 2 dl/g, and satisfying the following conditions (a) to (c): (a) the composition particles have a particle size of 3 mm or less and a weight of less than 1 mg/particle; (b) the composition particles have a terminal carboxyl group content of 25 meq/kg or less; and (c) the composition particles have a cyclic dimer content of 1.5% by weight or less.

摘要翻译： 包含80重量％以上的基于全部重复单元的对苯二甲酸丙二醇酯单元，特性粘度为0.8〜2d / g，并满足以下条件（a）〜（c）的聚 （a）组合物颗粒的粒径为3mm以下，重量小于1mg /粒子; （b）组合物颗粒的末端羧基含量为25meq / kg以下; 和（c）组合物颗粒的环状二聚体含量为1.5重量％以下。

公开(公告)号：US06423407B1

公开(公告)日：2002-07-23

申请号：US09807543

申请日：2001-04-13

申请人： Takao Abe ,  Jinichiro Kato ,  Teruhiko Matsuo

发明人： Takao Abe ,  Jinichiro Kato ,  Teruhiko Matsuo

IPC分类号： D01F600

CPC分类号： D01F6/62 ,  Y10T428/2913 ,  Y10T428/2969

摘要： A polytrimethylene terephthalate fiber composed of a polytrimethylene terephthalate (PTT) comprising not less than 95 mole % of a polytrimethylene terephthalate repeating unit and having an intrinsic viscosity of from 0.7 to 1.3, wherein the fiber satisfies the following features: (1) a degree of crystalline orientation of from 88% to 95%, (2) a peak value of dynamic loss tangent (tan &dgr;) max of from 0.10 to 0.15, (3) a peak temperature Tmax (°C.) of dynamic loss tangent 102 to 116° C., (4) an elongation at break of from 36 to 50%, (5) a peak value of thermal stress being between 0.25 and 0.38 g/d, (6) a fiber to fiber dynamic frictional coefficient of from 0.30 to 0.50; and the PTT fiber having an excellent processability can be obtained through a drawing process in which the undrawn yarn can be stably drawn. The PTT fiber can be produced by melt-spinning PTT having an intrinsic viscosity of 0.7-1.3 at a withdrawal speed of 2,000 m/min or less to obtain a undrawn yarn, and then drawing and heat-treating the undrawn yarn by means of draw-twister.

摘要翻译： 由聚对苯二甲酸丙二醇酯重复单元不少于95摩尔％，特性粘度为0.7〜1.3的聚对苯二甲酸丙二醇酯（PTT）构成的聚对苯二甲酸丙二醇酯纤维，其特征在于：（1） 晶体取向为88％至95％，（2）动态损耗角正切（tanδ）max的峰值为0.10至0.15，（3）动态损耗角正切值102至116的峰值温度Tmax（°C） （4）断裂伸长率为36〜50％，（5）热应力的峰值在0.25〜0.38g / d之间，（6）纤维与纤维的动摩擦系数为0.30〜 0.50; 通过可以稳定地拉伸未拉伸丝的拉伸工艺，可以获得具有优异加工性的PTT纤维。PTT纤维可以通过以2000m的提取速度熔融纺丝特性粘度为0.7-1.3的PTT来制备 /分钟以下，得到未拉伸丝，然后通过拉丝机拉伸和热处理未拉伸丝。

公开(公告)号：US07332561B2

公开(公告)日：2008-02-19

申请号：US10507840

申请日：2003-03-14

申请人： Jinichiro Kato ,  Satoru Yoshida ,  Teruhiko Matsuo

发明人： Jinichiro Kato ,  Satoru Yoshida ,  Teruhiko Matsuo

IPC分类号： C08G63/00 ,  C08G63/80 ,  C08G63/183 ,  C02F5/10

CPC分类号： C08G63/80 ,  C08G63/183 ,  D01F6/62 ,  Y10T428/29 ,  Y10T428/2913

摘要： Poly(trimethylene terephthalate) composition particles comprising 80% by weight or more of trimethylene terephthalate units based on the entire repeating units, having an intrinsic viscosity from 0.8 to 2 dl/g, and satisfying the following conditions (a) to (c): (a) the composition particles have a particle size of 3 mm or less and a weight of less than 1 mg/particle; (b) the composition particles have a terminal carboxyl group content of 25 meq/kg or less; and (c) the composition particles have a cyclic dimer content of 1.5% by weight or less.

摘要翻译： 包含80重量％以上的基于全部重复单元的对苯二甲酸丙二醇酯单元，特性粘度为0.8〜2d / g，并满足以下条件（a）〜（c）的聚 （a）组合物颗粒的粒径为3mm以下，重量小于1mg /粒子; （b）组合物颗粒的末端羧基含量为25meq / kg以下; 和（c）组合物颗粒的环状二聚体含量为1.5重量％以下。

公开(公告)号：US06740400B2

公开(公告)日：2004-05-25

申请号：US10066712

申请日：2002-02-06

申请人： Jinichiro Kato ,  Yoichiro Azuma ,  Katsuhiro Fujimoto ,  Teruhiko Matsuo

发明人： Jinichiro Kato ,  Yoichiro Azuma ,  Katsuhiro Fujimoto ,  Teruhiko Matsuo

IPC分类号： D02G300

CPC分类号： D01F6/62 ,  C08G63/183 ,  C08G63/672 ,  C08G63/80 ,  Y10T428/2913

摘要： A poly(trimethylene terephthalate) comprising 80% by weight or more of trimethylene terephthalate units based on the entire repeating units, having an intrinsic viscosity of from 0.4 to 1.5 dl/g, and satisfying the following formula (1) [—OH]/([—OH]+[—COOH]+[—CH2CH═CH2])×100≧40  (1) wherein [—OH], [—COOH] and [—CH2CH═CH2] represent a terminal hydroxyl group content, a terminal carboxyl group content and a terminal allyl group content of the poly(trimethylene terephthalate), respectively. The poly(trimethylene terephthalate) can be produced by reacting terephthalic acid and/or its lower alcohol ester is reacted with 1,3-propanediol to form 1,3-propanediol ester of terephthalic acid and/or its oligomer, and then polycondensation reaction of the reactant is conducted at temperature of from 235 to 270° C. while the above formula (1) is being satisfied to give the above poly(trimethylene terephthalate).

摘要翻译： 基于全部重复单元的80重量％以上的对苯二甲酸丙二醇酯单元，特性粘度为0.4〜1.5dl / g，满足下式（1）的聚（对苯二甲酸丙二醇酯），其中[-OH] ，[-COOH]和[-CH 2 CH = CH 2]分别表示聚（对苯二甲酸丙二醇酯）的末端羟基含量，末端羧基含量和末端烯丙基含量。 聚对苯二甲酸丙二醇酯可以通过使对苯二甲酸和/或其低级醇酯与1,3-丙二醇反应形成对苯二甲酸和/或其低聚物的1,3-丙二醇酯，然后进行缩聚反应 反应物在235〜270℃的温度下进行，同时满足上述式（1），得到上述聚（对苯二甲酸丙二醇酯）。

公开(公告)号：US06949210B2

公开(公告)日：2005-09-27

申请号：US10388483

申请日：2003-03-17

申请人： Tadashi Koyanagi ,  Takao Abe ,  Teruhiko Matsuo ,  Yousei Mitsumori

发明人： Tadashi Koyanagi ,  Takao Abe ,  Teruhiko Matsuo ,  Yousei Mitsumori

IPC分类号： B27B17/00 ,  D01D5/30 ,  D01F8/14 ,  D06M13/02 ,  D06M13/224 ,  D06M15/53 ,  B29C47/88 ,  D01D5/32 ,  D01D5/34

CPC分类号： D01F8/14 ,  Y10T428/2913 ,  Y10T428/2924 ,  Y10T428/2929 ,  Y10T428/2931 ,  Y10T428/2964 ,  Y10T428/2969

摘要： The present invention provides a polytrimethylene terephthalate composite fiber characterized in that the composite fiber is a plurality of single filament which comprises two kinds of polyester components laminated to each other in a side-by-side manner or an eccentric sheath-core manner, at least one polyester component is polytrimethylene terephthalate and the composite fiber satisfies the following conditions: the content of trimethylene terephthalate cyclic dimer in polytrimethylene terephthalate is 2.5 wt % or less, the fiber-fiber dynamic friction coefficient is from 0.2 to 0.4, the degree of intermingling is from 2 to 60 point/m and/or the number of twists is from 2 to 60 T/m and the fiber size fluctuation U % is 1.5% or less.

摘要翻译： 本发明提供一种聚对苯二甲酸丙二醇酯复合纤维，其特征在于复合纤维是多个单丝，其包含两种聚酯组分，其中两种聚酯组分彼此并排地叠合或者以离心皮芯方式叠层 一种聚酯组分是聚对苯二甲酸丙二酯，复合纤维满​​足以下条件：聚对苯二甲酸丙二醇酯中对苯二甲酸环丙二酯的含量为2.5重量％以下，纤维动态摩擦系数为0.2〜0.4，混合度为 2〜60点/ m和/或捻数为2〜60T / m，纤维尺寸变动U％为1.5％以下。

公开(公告)号：US06673444B2

公开(公告)日：2004-01-06

申请号：US10239416

申请日：2002-09-24

申请人： Yasunori Yuuki ,  Teruhiko Matsuo ,  Tadashi Koyanagi

发明人： Yasunori Yuuki ,  Teruhiko Matsuo ,  Tadashi Koyanagi

IPC分类号： D01F600

CPC分类号： D01F6/62 ,  Y10T428/2913 ,  Y10T428/2969

摘要： The present invention provides a polytrimethylene terephthalate monofilament yarn excellent in softness, bending recovery or durability against a long term use. The inventive polytrimethylene terephthalate monofilament yarn is constituted by trimethylene terephthalate composed of 90 mol % or more of trymethylene terephthalate repeating units and 10 mol % or less of other ester repeating units, wherein the yarn has a single-fiber size of 50 dtex or more, an intrinsic viscosity in a range from 0.8 to 1.3 dl/g, and a boiling water shrinkage of 2% or less.

摘要翻译： 本发明提供了对长期使用的柔软性，弯曲恢复性或耐久性优异的聚对苯二甲酸丙二醇酯单丝纱。 本发明的聚对苯二甲酸丙二醇酯单丝由由对苯二甲酸对苯二甲酸酯重复单元的90摩尔％以上的其他酯重复单元的10摩尔％以下组成的对苯二甲酸丙二醇酯构成，其中，单丝纤维尺寸为50分特以上， 特性粘度为0.8〜1.3dl / g，沸水收缩率为2％以下。

公开(公告)号：US06555220B1

公开(公告)日：2003-04-29

申请号：US10060362

申请日：2002-02-01

申请人： Tadashi Koyanagi ,  Takao Abe ,  Teruhiko Matsuo ,  Yousei Mitsumori

发明人： Tadashi Koyanagi ,  Takao Abe ,  Teruhiko Matsuo ,  Yousei Mitsumori

IPC分类号： D01F600

CPC分类号： D01F8/14 ,  Y10T428/2913 ,  Y10T428/2924 ,  Y10T428/2929 ,  Y10T428/2931 ,  Y10T428/2964 ,  Y10T428/2969

摘要： The present invention provides a polytrimethylene terephthalate composite fiber characterized in that the composite fiber is a plurality of single filament which comprises two kinds of polyester components laminated to each other in a side-by-side manner or an eccentric sheath-core manner, at least one polyester component is polytrimethylene terephthalate and the composite fiber satisfies the following conditions: the content of trimethylene terephthalate cyclic dimer in polytrimethylene terephthalate is 2.5 wt % or less, the fiber-fiber dynamic friction coefficient is from 0.2 to 0.4, the degree of intermingling is from 2 to 60 point/m and/or the number of twists is from 2 to 60 T/m and the fiber size fluctuation U% is 1.5% or less.

摘要翻译： 本发明提供一种聚对苯二甲酸丙二醇酯复合纤维，其特征在于复合纤维是多个单丝，其包含两种聚酯组分，其中两种聚酯组分彼此并排地叠合或者以离心皮芯方式叠层 一种聚酯组分是聚对苯二甲酸丙二酯，复合纤维满​​足以下条件：聚对苯二甲酸丙二醇酯中对苯二甲酸环丙二酯的含量为2.5重量％以下，纤维动态摩擦系数为0.2〜0.4，混合度为 2〜60点/ m和/或捻数为2〜60T / m，纤维尺寸变动U％为1.5％以下。

公开(公告)号：US06495254B1

公开(公告)日：2002-12-17

申请号：US09913645

申请日：2001-08-17

申请人： Takao Abe ,  Youichiro Azuma ,  Teruhiko Matsuo

发明人： Takao Abe ,  Youichiro Azuma ,  Teruhiko Matsuo

IPC分类号： D01F600

CPC分类号： D01F6/62 ,  Y10T428/2913 ,  Y10T428/2969

摘要： According to the present invention, polytrimethylene terephthalate fiber is provided, which is high in toughness, uniform in fiber size and excellent in dyeing uniformity, whereby it is extremely suitable for a clothing use. Polytrimethylene terephthalate fiber according to the present invention can be produced by a two-step method consisting of a low speed spinning process and a drawing process, wherein the winding condition of undrawn fiber, the atmospheric condition under which the undrawn fiber is retained and the time for retaining the undrawn fiber are set to a specific range so that the shrinkage of undrawn fiber with time and the transformation of the undrawn package caused thereby are minimized. Thus, the unwinding tension of the undrawn fiber is maintained constant whereby the drawing is favorably carried out to result in a high quality polytrimethylene terephthalate fiber.

摘要翻译： 根据本发明，提供了聚对苯二甲酸丙二醇酯纤维，其韧性高，纤维尺寸均匀，染色均匀性优异，因此非常适用于服装用途。本发明的聚对苯二甲酸丙二醇酯纤维可以通过 由低速纺丝工艺和拉伸工艺组成的两步​​法，其中未拉伸纤维的卷绕条件，保持未拉伸纤维的大气条件和保持未拉伸纤维的时间设定在特定范围内 未拉伸纤维随时间的收缩和由此引起的未拉伸包装的变形最小化。 因此，未拉伸纤维的退绕张力保持恒定，从而有利地进行拉伸以获得高质量的聚对苯二甲酸丙二醇酯纤维。