Cationic electrodeposition coating composition and coated article therewith
    1.
    发明申请
    Cationic electrodeposition coating composition and coated article therewith 审中-公开
    阳离子电沉积涂料组合物及其涂覆制品

    公开(公告)号:US20070029200A1

    公开(公告)日:2007-02-08

    申请号:US11498727

    申请日:2006-08-04

    IPC分类号: C25B7/00 C25D13/00

    CPC分类号: C25D13/02 C25D13/10 C25D13/12

    摘要: The present invention relates to a cationic electrodeposition coating composition comprising silica particles having pore volume of 0.44 to 1.8 ml/g and average particle size of no more than 10 μm, the composition showing square root of diffusion coefficient (√Tc) of no less than 2.5 upon diffusing a solution onto a coating film therewith; a cationic electrodeposition coating composition comprising silica particles having pore volume of 0.44 to 1.8 ml/g and average particle size of no more than 10 μm, wherein the composition shows minimum deposition pH of 11.90 to 12.00 during electrodeposition coating, and film resistance of 1,000 to 1,500 kΩ·cm2 at film thickness of 15 μm and applied voltage of 240 V; and an article coated with such cationic electrodeposition coating composition. Therefore, the present invention can also provide a coating film formed with the cationic electrodeposition coating composition which can ensure higher corrosion resistance and higher throwing power in addition to other excellent coating properties, even if the resulting coating has extremely thin film thickness (e.g., about 7 μm).

    摘要翻译: 本发明涉及一种阳离子电沉积涂料组合物,其包含孔体积为0.44〜1.8ml / g,平均粒径为10μm以下的二氧化硅粒子,扩散系数平方根(√Tc)的组成不小于 将溶液扩散到其上的涂膜上; 包含孔体积为0.44〜1.8ml / g,平均粒径为10μm以下的二氧化硅粒子的阳离子电沉积涂料组合物,其中组合物在电沉积涂布期间显示最小沉积pH为11.90至12.00,膜电阻为1000〜 薄膜厚度为15μm,施加电压为240V时为1500kOgg·cm 2·2; 和涂有这种阳离子电沉积涂料组合物的制品。 因此,本发明还可以提供一种形成有阳离子电沉积涂料组合物的涂膜,除了其它优异的涂料性能外,还可以确保更高的耐腐蚀性和更高的抛光力,即使所得到的涂层具有非常薄的膜厚度(例如约 7个妈妈)。

    Method for forming multi-layered coating film and coated product
    2.
    发明申请
    Method for forming multi-layered coating film and coated product 审中-公开
    多层涂膜和涂层产品的形成方法

    公开(公告)号:US20070077437A1

    公开(公告)日:2007-04-05

    申请号:US11521380

    申请日:2006-09-15

    IPC分类号: B32B27/40

    摘要: The invention relates to a method for forming a multilayered coating film having a bright feel specific to a metallic coating film and a fineness of a luster color pigment with controlling the miscibility between each coating film when final coatings comprising an intermediate coating composition, a base coating composition and a clear coating composition are applied in this order by a wet-on-wet method to form coating films. The method for forming a multi-layered coating film comprises a step of applying an intermediate coating composition, a base coating composition and a clear coating composition in this order on a substrate formed with an electrodeposition coating film, and a step of baking and curing the applied three layers simultaneously, wherein the base coating composition contains crosslinking polymer microparticles and a nonaqueous dispersion resin.

    摘要翻译: 本发明涉及一种形成具有对金属涂膜的光泽特性的多层涂膜和光泽颜料的细度的方法,当控制包含中间涂料组合物的最终涂层时,控制每个涂膜之间的混溶性,底涂层 组合物和透明涂料组合物按此顺序通过湿法湿式方法施加以形成涂膜。 形成多层涂膜的方法包括在形成有电沉积涂膜的基材上依次涂布中间涂料组合物,底涂层组合物和透明涂料组合物的步骤,以及烘烤和固化 同时施加三层,其中基底涂料组合物含有交联聚合物微粒和非水分散体树脂。

    Method for forming coated film and intermediate coating material
    3.
    发明授权
    Method for forming coated film and intermediate coating material 有权
    涂膜和中间涂层材料的形成方法

    公开(公告)号:US06863929B2

    公开(公告)日:2005-03-08

    申请号:US10347270

    申请日:2003-01-21

    摘要: A method for forming a coated film comprising the steps of sequentially applying an intermediate coating material, a base coating material and a clear coating material on a substrate on which an electrodeposition coated film has been formed; and simultaneously curing the applied three layers by baking, wherein the intermediate coating material comprises: (a) 40 to 56% by weight of an urethane modified polyester resin, the urethane modified polyester resin being obtainable by polyaddition of: a hydroxyl group containing polyester resin which is obtainable by polycondensation of an acid ingredient including not less than 80% by mole of isophthalic acid with a polyhydric alcohol ingredient, with an aliphatic diisocyanate compound; (b) 10 to 30% by weight of a melamine resin; (c) 15 to 30% by weight of a blocked isocyanate compound; (d) 4 to 15% by weight of a nonaqueous dispersion resin having core-shell structure; and (e) 0.4 to 2 parts by weight of a flake-like pigment. The resulting layered coated film is superior in aesthetic appearance and chipping resistance even formed in the three-coating and one-baking method.

    摘要翻译: 一种形成涂膜的方法,包括以下步骤:在其上形成有电沉积涂膜的基材上顺次涂布中间涂料,基涂料和透明涂料; 同时通过烘烤固化所施加的三层,其中中间涂层材料包括:(a)40至56重量%的氨基甲酸酯改性聚酯树脂,所述聚氨酯改性聚酯树脂可通过以下方式加成获得:含羟基的聚酯树脂 其可以通过使含有不少于80摩尔%的间苯二甲酸与多元醇成分的酸成分与脂肪族二异氰酸酯化合物缩聚而得到; (b)10〜30重量%的三聚氰胺树脂; (c)15〜30重量%的封端异氰酸酯化合物; (d)4〜15重量%的具有核 - 壳结构的非水分散体树脂; 和(e)0.4〜2重量份的片状颜料。 所得到的层状涂膜在三层涂布和一次烘烤方法中甚至形成的美观性和耐崩裂性优异。

    Surface treatment method of metal material
    4.
    发明授权
    Surface treatment method of metal material 有权
    金属材料表面处理方法

    公开(公告)号:US08506728B2

    公开(公告)日:2013-08-13

    申请号:US12839034

    申请日:2010-07-19

    IPC分类号: C23C22/05

    摘要: In a process which is before a treatment process of forming a chemical conversion, TiO2 fine particles as an electron releasing-related substance (electron releasing substance) are attached onto a surface of a vehicle body. Then, a chemical conversion treatment is applied to the vehicle body having the TiO2 fine particles attached thereto. Thereby, an energy band gap of a finally-formed chemical conversion film can be smaller than that of a chemical conversion film formed by using only a chemical conversion treatment agent. Accordingly, the number of electrons (free electrons) which can be supplied onto the surface of a chemical conversion film can be increased during a voltage application in an electrodeposition coating process, and reducing reaction at a cathode can be promoted.

    摘要翻译: 在化学转化处理过程之前的过程中,作为电子释放相关物质(电子释放物质)的TiO 2微粒附着在车体的表面。 然后,对附着有TiO 2微粒的车身施加化学转化处理。 因此,最终形成的化学转化膜的能带隙可以小于仅使用化学转化处理剂形成的化学转化膜的能带隙。 因此,在电沉积涂覆工艺中的电压施加期间,可以提高可供给到化学转化膜的表面上的电子数(自由电子数),从而可以促进阴极的还原反应。

    CURED ELECTRODEPOSITION COATING FILM AND PROCESS FOR FORMING A MULTI LAYERED COATING FILM
    5.
    发明申请
    CURED ELECTRODEPOSITION COATING FILM AND PROCESS FOR FORMING A MULTI LAYERED COATING FILM 审中-公开
    固化电沉积膜和形成多层涂膜的方法

    公开(公告)号:US20120027938A1

    公开(公告)日:2012-02-02

    申请号:US13188890

    申请日:2011-07-22

    摘要: The present invention relates to a cured electrodeposition coating film which can be applied on a substrate such as an automobile body.The cured electrodeposition coating film has a dynamic glass transition temperature of 105 to 120° C. and a crosslink density of 1.2×10−3 to 2.0×10−3 mole/cc, and phenol structural part represented with the formula: —C6H4—O— within a range of 0.12 to 0.24 mole in molar number based on a resin solid content of 100 g in the cured electrodeposition coating film. The cured electrodeposition coating film is obtained by conducting electrodeposition coating with a cationic electrodeposition coating composition, and then heating and curing it, wherein the cationic electrodeposition coating composition comprises, cationic epoxy resin (A) having bisphenol A-type structure in its molecule, cationic acrylic resin (B) obtainable by reacting an amino group containing compound with a copolymer obtainable by radical-copolymerization of a hydroxy group containing monomer, a glycidyl group containing monomer and another monomer, blocked isocyanate curing agent (C) which is obtained by blocking a cycloaliphatic isocyanate compound with an oxime compound, and a pigment.

    摘要翻译: 本发明涉及一种固化的电沉积涂膜,其可以应用于诸如汽车车身的基材上。 固化的电沉积涂膜的动态玻璃化转变温度为105〜120℃,交联密度为1.2×10-3〜2.0×10-3摩尔/ cc,酚结构部分为:-C 6 H 4 - O-在固化的电沉积涂膜中的基于树脂固体含量为100g的摩尔数为0.12至0.24摩尔的范围内。 固化的电沉积涂膜通过用阳离子电沉积涂料组合物进行电沉积涂覆,然后加热和固化而得到,其中阳离子电沉积涂料组合物包括其分子中具有双酚A型结构的阳离子环氧树脂(A),阳离子 通过使含氨基化合物与可通过使含羟基的单体,含缩水甘油基的单体和其它单体自由基共聚获得的共聚物反应而获得的丙烯酸树脂(B),通过封闭异氰酸酯固化剂(C) 脂环族异氰酸酯化合物与肟化合物和颜料。