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    Non-aqueous electrolyte secondary battery
    2.
    发明授权
    Non-aqueous electrolyte secondary battery 有权
    非水电解质二次电池

    公开(公告)号：US06265111B1

    公开(公告)日：2001-07-24

    申请号：US09598206

    申请日：2000-06-21

    申请人： Yasuhiko Bito ,  Toshitada Sato ,  Hiromu Matsuda ,  Yoshinori Toyoguchi ,  Yasushi Nakagiri ,  Hideharu Takezawa

    发明人： Yasuhiko Bito ,  Toshitada Sato ,  Hiromu Matsuda ,  Yoshinori Toyoguchi ,  Yasushi Nakagiri ,  Hideharu Takezawa

    IPC分类号： H01M458

    CPC分类号： H01M4/13 ,  H01M4/362 ,  H01M4/366 ,  H01M4/38 ,  H01M4/382 ,  H01M4/40 ,  H01M4/405 ,  H01M10/052

    摘要： A non-aqueous electrolyte secondary battery having an improved negative electrode is disclosed. The negative electrode comprises alloy particles having a composition represented by the formula: LixM1aM2  (1) wherein M1 represents at least one element selected from the element group m1 consisting of Ti, Zr, V, Sr, Ba, Y, La, Cr, Mo, W, Mn, Co, Ir, Ni, Cu and Fe, M2 represents at least one element selected from the element group m2 consisting of Mg, Ca, Al, In, Si, Sn, Pb, Sb and Bi, M1 and M2 represent different elements each other, and wherein 0≦x≦10, 0.1≦a≦10, with the proviso that 2≦a≦10 when M1 is composed only of Fe, and having at least two phases which are different in composition each other.

    摘要翻译： 公开了一种具有改进的负极的非水电解质二次电池。 负极包括具有下式表示的组成的合金粒子：其中，M1表示选自由Ti，Zr，V，Sr，Ba，Y，La，Cr，Mo，W，Mn组成的元素组m 1中的至少一种元素 ，Co，Ir，Ni，Cu和Fe中的至少一种元素，M2表示选自由Mg，Ca，Al，In，Si，Sn，Pb，Sb和Bi组成的元素组m2中的至少一种元素，M1和M2各自表示不同的元素 另外，并且其中0≤x≤10,0.1≤a≤10，条件是当M1仅由Fe构成且具有至少两个不同组成的相时，2 <= a <= 10 彼此。

    Non-aqueous electrolyte secondary battery and method for manufacturing the same
    3.
    发明授权
    Non-aqueous electrolyte secondary battery and method for manufacturing the same 有权
    非水电解质二次电池及其制造方法

    公开(公告)号：US06733927B1

    公开(公告)日：2004-05-11

    申请号：US09762220

    申请日：2001-03-23

    申请人： Hideharu Takezawa ,  Yasuhiko Bito ,  Hiromu Matsuda ,  Yoshinori Toyoguchi

    发明人： Hideharu Takezawa ,  Yasuhiko Bito ,  Hiromu Matsuda ,  Yoshinori Toyoguchi

    IPC分类号： H01M614

    CPC分类号： H01M10/052 ,  H01M4/131 ,  H01M4/133 ,  H01M4/134 ,  H01M4/1391 ,  H01M4/1393 ,  H01M4/1395 ,  H01M4/62 ,  H01M10/0567 ,  Y10T29/49115

    摘要： In a non-aqueous electrolyte secondary battery, the reaction between the non-aqueous electrolyte and the electrode is suppressed to reduce a decrease in the discharge capacity with the charge/discharge cycle progress and the deterioration of battery characteristics during high-temperature storage. At least one of a chargeable and dischargeable positive electrode, a non-aqueous electrolyte containing a lithium salt, and a chargeable and dischargeable negative electrode in a non-aqueous electrolyte secondary battery contains at least one selected from the group consisting of a phosphate having three aliphatic hydrocarbon groups having 7 to 12 carbon atoms, a phosphate having two aliphatic hydrocarbon groups having 1 to 12 carbon atoms or an aromatic hydrocarbon group, and a phosphate having an aliphatic hydrocarbon group having 1 to 12 carbon atoms or an aromatic hydrocarbon group.

    摘要翻译： 在非水电解质二次电池中，抑制非水电解质和电极之间的反应，以便在高温保存期间充放电循环进行和电池特性的劣化来减小放电容量的降低。 在非水电解质二次电池中，可充电和放电的正电极，含有锂盐的非水电解质和可充电和可放电的负极中的至少一种包含选自三价磷酸盐中的至少一种 碳原子数为7〜12的脂肪族烃基，碳原子数1〜12的2个脂肪族烃基或芳香族烃基的磷酸酯，碳原子数为1〜12的脂肪族烃基或芳香族烃基的磷酸酯。

    Negative electrode for non-aqueous electrolyte rechargeable batteries
    4.
    发明授权
    Negative electrode for non-aqueous electrolyte rechargeable batteries 有权
    用于非水电解质可充电电池的负电极

    公开(公告)号：US06558841B1

    公开(公告)日：2003-05-06

    申请号：US09649581

    申请日：2000-08-29

    申请人： Yasushi Nakagiri ,  Toshitada Sato ,  Hideharu Takezawa ,  Hiromu Matsuda

    发明人： Yasushi Nakagiri ,  Toshitada Sato ,  Hideharu Takezawa ,  Hiromu Matsuda

    IPC分类号： H01M436

    CPC分类号： H01M4/134 ,  H01M4/387 ,  H01M4/624 ,  H01M4/625 ,  H01M10/052 ,  H01M2004/027 ,  Y02T10/7011

    摘要： The purpose of the present invention is to provide a negative electrode for non-aqueous electrolyte rechargeable batteries of which the capacity is high and of which the decrease of the discharging capacity through the cycles is low by improving the electron conductivity of the surfaces of the active material particle for the negative electrode. In order to achieve this purpose, an active material in the form of a composite particle comprising,a phase that can store a lithium ion and includes at least Sn and a phase that cannot store a lithium ion and an electronically conductive material coating part of or the entire surfaces of the above described particle, is used for the negative electrode in the present invention.

    摘要翻译： 本发明的目的是提供一种容量高的非水电解质可再充电电池的负极，其中通过提高活性物质的表面的电子传导性，通过循环的放电容量的降低较低 负极材料颗粒。 为了达到这个目的，可以使用复合颗粒形式的活性材料，该活性材料包括：可以存储锂离子并且至少包含Sn的相和不能存储锂离子的相以及电子导电材料涂覆部分或 上述颗粒的整个表面用于本发明中的负极。

    Charger for lithium secondary battery and electronic apparatus including charger
    5.
    发明授权
    Charger for lithium secondary battery and electronic apparatus including charger 有权
    锂二次电池充电器及包括充电器在内的电子设备

    公开(公告)号：US07248023B2

    公开(公告)日：2007-07-24

    申请号：US11108746

    申请日：2005-04-19

    申请人： Hideharu Takezawa ,  Masaaki Kuranuki ,  Yasuhiko Bito

    发明人： Hideharu Takezawa ,  Masaaki Kuranuki ,  Yasuhiko Bito

    IPC分类号： H02J7/04 ,  H02J7/16

    CPC分类号： H02J7/0088 ,  B60L3/0046 ,  B60L11/1862 ,  B60L11/1872 ,  H02J7/045 ,  Y02T10/7011 ,  Y02T10/7044 ,  Y02T10/705

    摘要： A charger for a secondary battery including a positive electrode, a negative electrode including lithium-containing silicon represented by the composition formula LixSi, and an electrolyte. This charger includes: (1) a voltage detector that detects voltage of the secondary battery that is being charged; and (2) a charge controller that calculates the value x in LixSi included in the secondary battery from an output of the voltage detector and stops the charging of the secondary battery when the calculated value x reaches a predetermined threshold value. The charge controller has at least one settable threshold value including a first threshold value, and the first threshold value is 2.33 or less. The use of this charger makes it possible to charge the secondary battery such that it has a high capacity, or a higher capacity if necessary, without accelerating the deterioration of cycle life.

    摘要翻译： 一种用于二次电池的充电器，包括正极，由组成式Li x Si表示的含锂硅的负极和电解质。 该充电器包括：（1）检测正在充电的二次电池的电压的电压检测器; 和（2）计费控制器，从电压检测器的输出计算二次电池中包含的Li x x Si中的值x，并且当计算值x到达时停止二次电池的充电 预定阈值。 充电控制器具有包括第一阈值的至少一个可设置的阈值，并且第一阈值为2.33或更小。 使用该充电器可以对二次电池进行充电，使其具有高容量，或者如果需要，可以更高容量，而不会加速循环寿命的恶化。

    Charger for lithium secondary battery and electronic apparatus including charger
    6.
    发明申请
    Charger for lithium secondary battery and electronic apparatus including charger 有权
    锂二次电池充电器及包括充电器在内的电子设备

    公开(公告)号：US20050237029A1

    公开(公告)日：2005-10-27

    申请号：US11108746

    申请日：2005-04-19

    申请人： Hideharu Takezawa ,  Masaaki Kuranuki ,  Yasuhiko Bito

    发明人： Hideharu Takezawa ,  Masaaki Kuranuki ,  Yasuhiko Bito

    IPC分类号： H02J7/00 ,  H02J7/04

    CPC分类号： H02J7/0088 ,  B60L3/0046 ,  B60L11/1862 ,  B60L11/1872 ,  H02J7/045 ,  Y02T10/7011 ,  Y02T10/7044 ,  Y02T10/705

    摘要： A charger for a secondary battery including a positive electrode, a negative electrode including lithium-containing silicon represented by the composition formula LixSi, and an electrolyte. This charger includes: (1) a voltage detector that detects voltage of the secondary battery that is being charged; and (2) a charge controller that calculates the value x in LixSi included in the secondary battery from an output of the voltage detector and stops the charging of the secondary battery when the calculated value x reaches a predetermined threshold value. The charge controller has at least one settable threshold value including a first threshold value, and the first threshold value is 2.33 or less. The use of this charger makes it possible to charge the secondary battery such that it has a high capacity, or a higher capacity if necessary, without accelerating the deterioration of cycle life.

    摘要翻译： 一种用于二次电池的充电器，包括正极，由组成式Li x Si表示的含锂硅的负极和电解质。 该充电器包括：（1）检测正在充电的二次电池的电压的电压检测器; 和（2）计费控制器，从电压检测器的输出计算二次电池中包含的Li x x Si中的值x，并且当计算值x到达时停止二次电池的充电 预定阈值。 充电控制器具有包括第一阈值的至少一个可设置的阈值，并且第一阈值为2.33或更小。 使用该充电器可以对二次电池进行充电，使其具有高容量，或者如果需要，可以更高容量，而不会加速循环寿命的恶化。

    Non-aqueous electrolyte secondary battery and method for producing the same
    10.
    发明申请
    Non-aqueous electrolyte secondary battery and method for producing the same 有权
    非水电解质二次电池及其制造方法

    公开(公告)号：US20070204457A1

    公开(公告)日：2007-09-06

    申请号：US11600103

    申请日：2006-11-16

    申请人： Toshitada Sato ,  Hideharu Takezawa ,  Syoichi Imashiku ,  Kazuyoshi Honda

    发明人： Toshitada Sato ,  Hideharu Takezawa ,  Syoichi Imashiku ,  Kazuyoshi Honda

    IPC分类号： H01M10/04

    CPC分类号： H01M10/058 ,  H01M4/13 ,  H01M4/485 ,  H01M10/0525 ,  H01M2004/027 ,  Y10T29/49108 ,  Y10T29/49112 ,  Y10T29/49115

    摘要： A non-aqueous electrolyte secondary battery having both high capacity and long-life is provided by solving the problem of the large irreversible capacity of a negative electrode active material. The non-aqueous electrolyte secondary battery is produced by a method including the steps of: reacting lithium with a negative electrode active material by bringing a metal film that is composed mainly of lithium into contact with a surface of a negative electrode active material layer; and thereafter combining the negative electrode with a positive electrode to form an electrode assembly. The metal film composed mainly of lithium is preferably formed on a carrier that does not chemically react with lithium, and the metal film on the carrier is preferably brought into contact with the negative electrode active material layer while heating and applying a pressure thereto.

    摘要翻译： 通过解决负极活性物质的不可逆容量大的问题，提供了高容量，长寿命的非水电解质二次电池。 非水电解质二次电池是通过以下方法制造的：通过使主要由锂组成的金属膜与负极活性物质层的表面接触而使锂与负极活性物质反应; 然后将负极与正极组合以形成电极组件。 主要由锂组成的金属膜优选形成在不与锂发生化学反应的载体上，并且载体上的金属膜优选在加热并施加压力的同时与负极活性物质层接触。