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公开(公告)号：US08236972B2
公开(公告)日：2012-08-07
申请号：US12181921
申请日：2008-07-29
IPC分类号： C07D307/42 , C07D307/48 , C07D307/50 , C07D307/54
CPC分类号： C07D307/06 , C07D307/36 , C07D307/54
摘要： The instant invention involves a process for enhancing molecular mass of biomass reactants. The process comprises first forming a substituted or unsubstituted furfural from a biomass. The substituted or unsubstituted furfural is then reacted with an activated methylene compound in the presence of a catalyst and, if desired, a solvent to form a Knoevenagel product. The product may then be hydrogenated to products containing an alcohol, ether, aldehyde, or ketone functional groups or to an olefinic or aliphatic species wherein as much as all of the oxygen and/or nitrogen has been removed.
摘要翻译： 本发明涉及增强生物反应物分子量的方法。 该方法包括首先从生物质形成取代或未取代的糠醛。 然后将取代或未取代的糠醛与活化的亚甲基化合物在催化剂存在下反应，如果需要，则与溶剂反应形成Knoevenagel产物。 然后可以将产物氢化成含有醇，醚，醛或酮官能团的产物或其中除去所有氧和/或氮的烯烃或脂族物质。
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公开(公告)号：US20100029926A1
公开(公告)日：2010-02-04
申请号：US12181921
申请日：2008-07-29
IPC分类号： C08B1/00
CPC分类号： C07D307/06 , C07D307/36 , C07D307/54
摘要： The instant invention involves a process for enhancing molecular mass of biomass reactants. The process comprises first forming a substituted or unsubstituted furfural from a biomass. The substituted or unsubstituted furfural is then reacted with an activated methylene compound in the presence of a catalyst and, if desired, a solvent to form a Knoevenagel product. The product may then be hydrogenated to products containing an alcohol, ether, aldehyde, or ketone functional groups or to an olefinic or aliphatic species wherein as much as all of the oxygen and/or nitrogen has been removed.
摘要翻译： 本发明涉及增强生物反应物分子量的方法。 该方法包括首先从生物质形成取代或未取代的糠醛。 然后将取代或未取代的糠醛与活化的亚甲基化合物在催化剂存在下反应，如果需要，则与溶剂反应形成Knoevenagel产物。 然后可以将产物氢化成含有醇，醚，醛或酮官能团的产物或其中除去所有氧和/或氮的烯烃或脂族物质。
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公开(公告)号：US09636665B2
公开(公告)日：2017-05-02
申请号：US13883686
申请日：2011-12-01
IPC分类号： C07C27/06 , B01J27/236 , B01J23/00 , B01J23/28 , C07C29/153
CPC分类号： B01J27/236 , B01J23/007 , B01J23/28 , C07C27/06 , C07C29/153 , C07C31/08 , C07C31/10
摘要： Catalyst compositions for production of higher alcohols comprise a hydrotalcite or hydrotalcite-like support impregnated with molybdenum and an alkali metal. When the compositions are used to convert syngas, selectivity to higher (C2+) alcohols is increased in comparison to conversions accomplished over many other catalyst systems.
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4.发明申请公开(公告)号：US20130245137A1
公开(公告)日：2013-09-19
申请号：US13883681
申请日：2011-12-01
IPC分类号： C07C29/153
CPC分类号： C07C29/153 , B01J21/185 , B01J23/007 , B01J23/28 , B82Y30/00 , C07C31/08 , C07C31/10
摘要： Catalyst compositions comprising molybdenum, sulfur and an alkali metal ion supported on a nanofibrous, mesoporous carbon molecular sieve are useful for converting syngas to higher alcohols. The compositions are produced via impregnation and may enhance selectivity to ethanol in particular.
摘要翻译： 包含钼，硫和负载在纳米纤维介孔碳分子筛上的碱金属离子的催化剂组合物可用于将合成气转化为高级醇。 通过浸渍制备组合物，特别是可以增强对乙醇的选择性。
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5.发明授权公开(公告)号：US08999876B2
公开(公告)日：2015-04-07
申请号：US13883681
申请日：2011-12-01
IPC分类号： B01J21/18 , B01J23/00 , B01J27/02 , B01J27/051 , C01B31/08 , C07C27/00 , C07C27/06 , D01F9/12 , C07C29/153 , B01J23/28 , B82Y30/00
CPC分类号： C07C29/153 , B01J21/185 , B01J23/007 , B01J23/28 , B82Y30/00 , C07C31/08 , C07C31/10
摘要： Catalyst compositions comprising molybdenum, sulfur and an alkali metal ion supported on a nanofibrous, mesoporous carbon molecular sieve are useful for converting syngas to higher alcohols. The compositions are produced via impregnation and may enhance selectivity to ethanol in particular.
摘要翻译： 包含钼，硫和负载在纳米纤维介孔碳分子筛上的碱金属离子的催化剂组合物可用于将合成气转化为高级醇。 通过浸渍制备组合物，特别是可以增强对乙醇的选择性。
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公开(公告)号：US20130245328A1
公开(公告)日：2013-09-19
申请号：US13883686
申请日：2011-12-01
IPC分类号： B01J27/236 , C07C29/153
CPC分类号： B01J27/236 , B01J23/007 , B01J23/28 , C07C27/06 , C07C29/153 , C07C31/08 , C07C31/10
摘要： Catalyst compositions for production of higher alcohols comprise a hydrotalcite or hydrotalcite-like support impregnated with molybdenum and an alkali metal. When the compositions are used to convert syngas, selectivity to higher (C2+) alcohols is increased in comparison to conversions accomplished over many other catalyst systems.
摘要翻译： 用于生产高级醇的催化剂组合物包含浸渍有钼和碱金属的水滑石或水滑石样载体。 当使用组合物来转化合成气时，与在许多其它催化剂体系上完成的转化率相比，对较高（C2 +）醇的选择性增加。
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公开(公告)号：US07972587B2
公开(公告)日：2011-07-05
申请号：US11849526
申请日：2007-09-04
IPC分类号： C01B3/26
CPC分类号： C01B3/22 , B01J23/42 , C01B3/323 , C01B2203/0227 , C01B2203/0266 , C01B2203/0283 , C01B2203/107 , C01B2203/1082 , C01B2203/1211 , Y02P20/52
摘要： Briefly described, methods of generating (H2) from a biomass and the like, are disclosed.
摘要翻译： 简要描述了从生物质等产生（H2）的方法。
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