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公开(公告)号：US06841127B2
公开(公告)日：2005-01-11
申请号：US10187406
申请日：2002-06-28
申请人： Trevor G. Frank , Keith A. Hall , William H. Chandler, Jr. , Thomas Boussie , Thomas J. Crevier , Leonid Matsiev , Christopher Goh
发明人： Trevor G. Frank , Keith A. Hall , William H. Chandler, Jr. , Thomas Boussie , Thomas J. Crevier , Leonid Matsiev , Christopher Goh
IPC分类号： G01N31/16 , B01J19/00 , C08F4/00 , G01N21/78 , G01N25/72 , G01N31/10 , G01N35/00 , G01N35/02 , G01N33/48 , G01N15/06 , G01N21/00 , G01N31/00 , G01N33/00
CPC分类号： G01N31/10 , B01J19/0046 , G01N25/72 , G01N35/025 , G01N2035/00188 , Y10T436/10 , Y10T436/11 , Y10T436/110833 , Y10T436/113332 , Y10T436/114165 , Y10T436/25
摘要： An apparatus for in-situ injection of one or more chemical components into a reaction chamber is disclosed. The apparatus includes a reaction chamber for receiving one or more libraries, each of the libraries comprising two or more samples. The reaction chamber is configured to form a sealed enclosure. The apparatus further includes an injection manifold supporting injectors for in-situ injection of one or more chemical components onto respective samples of the one or more libraries in the pressurized sealed reaction chamber.
摘要翻译： 公开了一种用于将一种或多种化学成分原位注入反应室的装置。 该装置包括用于接收一个或多个库的反应室，每个库包括两个或更多个样品。 反应室被配置成形成密封的外壳。 该装置还包括支撑注射器的注射歧管，用于将一个或多个化学组分原位注射到加压密封反应室中的一个或多个文库的相应样品上。
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公开(公告)号：US06838052B2
公开(公告)日：2005-01-04
申请号：US09895945
申请日：2001-06-29
申请人： Trevor G. Frank , Keith A. Hall , William H. Chandler, Jr. , Thomas Boussie , Thomas J. Crevier , Leonid F. Matsiev
发明人： Trevor G. Frank , Keith A. Hall , William H. Chandler, Jr. , Thomas Boussie , Thomas J. Crevier , Leonid F. Matsiev
IPC分类号： G01N31/16 , B01J19/00 , C08F4/00 , G01N21/78 , G01N25/72 , G01N31/10 , G01N35/00 , G01N35/02 , G01N33/48 , G01N15/06 , G01N21/00 , G01N31/00 , G01N33/00
CPC分类号： G01N31/10 , B01J19/0046 , G01N25/72 , G01N35/025 , G01N2035/00188 , Y10T436/10 , Y10T436/11 , Y10T436/110833 , Y10T436/113332 , Y10T436/114165 , Y10T436/25
摘要： An apparatus for in-situ injection of one or more chemical components into a reaction chamber, comprising a reaction chamber for receiving one or more libraries including two or more samples; an injection module in fluid communication with the reaction chamber for permitting in-situ injection of one or more chemical components into the reaction chamber; and a selectively movable transport assembly supported by at least a portion of the reaction chamber for transporting the one or more libraries to the injection module.
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公开(公告)号：US06900321B2
公开(公告)日：2005-05-31
申请号：US09992630
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C07B61/00 , C07D213/38 , C07D213/61 , C07D213/68 , C07D213/74 , C07F7/00 , C07F9/58 , C08F4/64 , C08F4/642 , C08F4/643 , C08F4/646 , C08F4/659 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , B01J31/00
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridylamine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有吡啶胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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公开(公告)号：US07087690B2
公开(公告)日：2006-08-08
申请号：US10720380
申请日：2003-11-25
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. Lapointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. Lapointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
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公开(公告)号：US06750345B2
公开(公告)日：2004-06-15
申请号：US09992789
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C07F700
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有吡啶基 - 胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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公开(公告)号：US07018949B2
公开(公告)日：2006-03-28
申请号：US10748216
申请日：2003-12-31
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
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7.发明授权Methods of polymerizing ethylene and styrene copolymers with substituted pyridyl amine catalysts and catalysts therefor 失效用取代的吡啶胺催化剂和其催化剂聚合乙烯和苯乙烯共聚物的方法公开(公告)号：US06706829B2
公开(公告)日：2004-03-16
申请号：US09992148
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C08F444
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有吡啶基 - 胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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8.发明授权Methods of copolymerizing ethylene and isobutylene and polymers made thereby 失效共聚乙烯和异丁烯的方法以及由此制备的聚合物公开(公告)号：US06828397B2
公开(公告)日：2004-12-07
申请号：US09992760
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C08F444
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
摘要翻译： 公开了新配体，组合物，金属 - 配体络合物和具有吡啶基 - 胺配体的阵列，其催化单体聚合成聚合物。 这些具有铪金属中心的这些催化剂中的某些具有高性能特征，包括较高的共聚单体引入到乙烯/烯烃共聚物中，其中这种烯烃是例如1-辛烯，异丁烯或苯乙烯。 某些催化剂在各种聚合条件下在溶液过程中将丙烯聚合成高分子量全同立构聚丙烯是特别有效的。
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公开(公告)号：US06713577B2
公开(公告)日：2004-03-30
申请号：US09992385
申请日：2001-11-06
申请人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
发明人： Thomas R. Boussie , Gary M. Diamond , Christopher Goh , Keith A. Hall , Anne M. LaPointe , Margarete K. Leclerc , Cheryl Lund , Vince Murphy
IPC分类号： C08F444
CPC分类号： C07D213/74 , B01J2219/00722 , C07B2200/11 , C07D213/38 , C07D213/61 , C07D213/68 , C07F7/00 , C07F7/003 , C07F9/58 , C08F4/65908 , C08F4/65912 , C08F10/00 , C08F110/06 , C08F210/02 , C08F210/16 , C40B40/14 , C08F4/659 , C08F4/65904 , C08F2500/15 , C08F2500/02 , C08F210/10 , C08F212/08 , C08F210/14 , C08F4/64144 , C08F4/64113 , C08F4/64044
摘要： New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene/olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.
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公开(公告)号：US20080269443A1
公开(公告)日：2008-10-30
申请号：US12215626
申请日：2008-06-27
申请人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Mathew C. Kuchta , Tom Boussie , John F. Walzer , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
发明人： David H. McConville , Lily Ackerman , Robert T. Li , Xiaohong Bei , Mathew C. Kuchta , Tom Boussie , John F. Walzer , Gary Diamond , Francis C. Rix , Keith A. Hall , Anne LaPointe , James Longmire , Vince Murphy , Pu Sun , Dawn Verdugo , Susan Schofer , Eric Dias
IPC分类号： C08K5/56
CPC分类号： C07C2/32 , B01J31/1815 , B01J31/2208 , B01J2231/20 , B01J2531/62 , C07C2531/22 , C08F10/00 , C07C11/02 , C08F4/69146 , C08F4/69275 , C08F4/69103 , C08F4/69172
摘要： The present invention provides a method of producing oligomers of olefins, comprising reacting olefins with a catalyst under oligomerization conditions. The catalyst can be the product of the combination of a chromium compound and a heteroaryl-amine compound. In particular embodiments, the catalyst compound can be used to trimerize or tetramerize ethylene to 1-hexene, 1-octene, or mixtures of 1-hexene and 1-octene.
摘要翻译： 本发明提供一种生产烯烃低聚物的方法，包括在低聚条件下使烯烃与催化剂反应。 催化剂可以是铬化合物和杂芳基 - 胺化合物的组合的产物。 在具体实施方案中，催化剂化合物可用于将乙烯三聚或四聚为1-己烯，1-辛烯或1-己烯和1-辛烯的混合物。
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